Flowing matter

This open access book, published in the Soft and Biological Matter series, presents an introduction to selected research topics in the broad field of flowing matter, including the dynamics of fluids with a complex internal structure -from nematic fluids to soft glasses- as well as active matter and turbulent phenomena.Flowing matter is a subject at the crossroads between physics, mathematics, chemistry, engineering, biology and earth sciences, and relies on a multidisciplinary approach to describe the emergence of the macroscopic behaviours in a system from the coordinated dynamics of its microscopic constituents.Depending on the microscopic interactions, an assembly of molecules or of mesoscopic particles can flow like a simple Newtonian fluid, deform elastically like a solid or behave in a complex manner. When the internal constituents are active, as for biological entities, one generally observes complex large-scale collective motions. Phenomenology is further complicated by the invariable tendency of fluids to display chaos at the large scales or when stirred strongly enough. This volume presents several research topics that address these phenomena encompassing the traditional micro-, meso-, and macro-scales descriptions, and contributes to our understanding of the fundamentals of flowing matter.This book is the legacy of the COST Action MP1305 “Flowing Matter”

Energy-stable linear schemes for polymer-solvent phase field models

We present new linear energy-stable numerical schemes for numerical simulation of complex polymer-solvent mixtures. The mathematical model proposed by Zhou, Zhang and E (Physical Review E 73, 2006) consists of the Cahn-Hilliard equation which describes dynamics of the interface that separates polymer and solvent and the Oldroyd-B equations for the hydrodynamics of polymeric mixtures. The model is thermodynamically consistent and dissipates free energy. Our main goal in this paper is to derive numerical schemes for the polymer-solvent mixture model that are energy dissipative and efficient in time. To this end we will propose several problem-suited time discretizations yielding linear schemes and discuss their properties

Assembly, Elasticity, And Structure Of Lyotropic Chromonic Liquid Crystals And Disordered Colloids

This dissertation describes experiments which explore the structure and dynamics in two classes of soft materials: lyotropic chromonic liquid crystals and colloidal glasses and super-cooled liquids. The first experiments found that the achiral LCLCs, sunset yellow FCF (SSY) and disodium cromoglycate (DSCG) both exhibit spontaneous mirror symmetry breaking in the nematic phase driven by a giant elastic anisotropy of their twist modulus compared to their splay and bend moduli. Resulting structures of the confined LCLCs display interesting director configurations due to interplay of topologically required defects and twisted director fields. At higher concentrations, the LCLC compounds form columnar phases. We studied the columnar phase confined within spherical drops and discovered and understood configurations of the LC that sometimes led to non-spherical droplet shapes. The second experiments with SSY LCLCs confined in hollow cylinders uncovered director configurations which were driven in large measure by an exotic elastic modulus known as saddle-splay. We measured this saddle-splay modulus in a LCLC for the first time and found it to be more than 50 times greater than the twist elastic modulus. This large relative value of the saddle-splay modulus violates a theoretical result/assumption known as the Ericksen inequality. A third group of experiments on LCLCs explored the drying process of sessile drops containing SSY solutions, including evaporation dynamics, morphology, and deposition patterns. These drops differ from typical, well-studied evaporating colloidal drops primarily due to the LCLC\u27s concentration-dependent isotropic, nematic, and columnar phases. Phase separation occurs during evaporation, creating surface tension gradients and significant density and viscosity variation within the droplet. Thus, the drying multiphase drops exhibit new convective currents, drop morphologies, deposition patterns, as well as a novel ordered crystalline phase. Finally, experiments in colloidal glasses and super-cooled liquids were initiated to probe the relationship between structure and dynamics in their constituent particles. The displacements of individual particles in the colloids can be decomposed into small cage fluctuations and large rearrangements into new cages. We found a correlation between the rate of rearrangement and the local cage structure associated with each particle. Particle trajectories of a two-dimensional binary mixture of soft colloids are captured by video microscopy. We use a machine learning method to calculate particle ``softness\u27\u27, which indicates the likelihood of rearrangement based on many radial structural features for each particle. We measured the residence time between consecutive rearrangements and related probability distribution functions (PDFs). The softness-dependent conditional PDF is well fit by an exponential with decay time decreasing monotonically with increasing softness. Using these data and a simple thermal activation model, we determined activation energies for rearrangements

Global Solutions for Two-Phase Complex Fluids with Quadratic Anchoring in Soft Matter Physics

We study a diffuse interface model describing the complex rheology and the interfacial dynamics during phase separation in a polar liquid-crystalline emulsion. More precisely, the physical systems comprises a two-phase mixture consisting in a polar liquid crystal immersed in a Newtonian fluid. Such composite material is a paradigmatic example of complex fluids arising in Soft Matter which exhibits multiscale interplay. Beyond the Ginzburg-Landau and Frank elastic energies for the concentration and the polarization, the free energy of the system is characterized by a quadratic anchoring term which tunes the orientation of the polarization at the interface. This leads to several quasi-linear nonlinear couplings in the resulting system describing the macroscopic dynamics. In this work, we establish the first mathematical results concerning the global dynamics of two-phase complex fluids with interfacial anchoring mechanism. First, we determine a set of sufficient conditions on the parameters of the system and the initial conditions which guarantee the existence of global weak solutions in two and three dimensions. Secondly, we show that weak solutions are unique and globally regular in the two dimensional case. Finally, we complement our analysis with some numerical simulations to display polarization and interfacial anchoring.Comment: 52 pages, 5 figure

Lattice Boltzmann method for Q-tensor nemato-dynamics in liquid crystal display devices.

Nematic liquid crystals are fluids whose anisometric molecules show long range orientational order but no positional order. The orientational order gives rise to anisotropic properties that have widely been exploited as the basis for liquid crystal display devices. The Ericksen-Leslie director theory has successfully been used to describe many dynamic properties of liquid crystals however there are situations in which a more complete description may be given in terms of the second rank traceless symmetric Q-tensor. The development of a liquid crystal device solver is described. The solver calculates the flow, director and order parameter fields in three-dimensions through the Q-tensor equations of nemato-dynamics. The solver includes elastic, electric, magnetic, thermotropic, flexoelectric, dielectric and surface anchoring effects. Coupled lattice Boltzmann algorithms are used with anisotropic forcing terms included in order to reproduce the governing equations. A Chapman-Enskog analysis demonstrates that the algorithm recovers the target macroscopic equations.The method is successfully validated against analytical results for the effect of temperature, external electric fields, flow alignment and Miesowicz viscosities. Further validation is given against numerical solutions of a one-dimensional model of a liquid crystal display device proposed by Davidson.The switching behaviour of a Zenithal Bistable Display is then investigated. It is shown how flexoelectric properties of nematics produce bistability within this device. Defect creation and annihilation processes are shown during device switching for which it is necessary to use a method with variable order parameter. An approach to determine the flexoelectric coefficients is discussed. Results are presented for the preliminary characterisation and operation of this display that may enable optimisation for use in the display industry

Liquid crystals in micron-scale droplets, shells and fibers

peer reviewedThe extraordinary responsiveness and large diversity of self-assembled structures of liquid crystals are well documented and they have been extensively used in devices like displays. For long, this application route strongly influenced academic research, which frequently focused on the performance of liquid crystals in display-like geometries, typically between flat, rigid substrates of glass or similar solids. Today a new trend is clearly visible, where liquid crystals confined within curved, often soft and flexible, interfaces are in focus. Innovation in microfluidic technology has opened for high-throughput production of liquid crystal droplets or shells with exquisite monodispersity, and modern characterization methods allow detailed analysis of complex director arrangements. The introduction of electrospinning in liquid crystal research has enabled encapsulation in optically transparent polymeric cylinders with very small radius, allowing studies of confinement effects that were not easily accessible before. It also opened the prospect of functionalizing textile fibers with liquid crystals in the core, triggering activities that target wearable devices with true textile form factor for seamless integration in clothing. Together, these developments have brought issues center stage that might previously have been considered esoteric, like the interaction of topological defects on spherical surfaces, saddle-splay curvature-induced spontaneous chiral symmetry breaking, or the non-trivial shape changes of curved liquid crystal elastomers with non-uniform director fields that undergo a phase transition to an isotropic state. The new research thrusts are motivated equally by the intriguing soft matter physics showcased by liquid crystals in these unconventional geometries, and by the many novel application opportunities that arise when we can reproducibly manufacture these systems on a commercial scale. This review attempts to summarize the current understanding of liquid crystals in spherical and cylindrical geometry, the state of the art of producing such samples, as well as the perspectives for innovative applications that have been put forward.R-AGR-0505 - IRP15 - UNIQUE (20150401-20180331) - LAGERWALL Ja