Single Photon Counting UV Solar-Blind Detectors Using Silicon and III-Nitride Materials

Ultraviolet (UV) studies in astronomy, cosmology, planetary studies, biological and medical applications often require precision detection of faint objects and in many cases require photon-counting detection. We present an overview of two approaches for achieving photon counting in the UV. The first approach involves UV enhancement of photon-counting silicon detectors, including electron multiplying charge-coupled devices and avalanche photodiodes. The approach used here employs molecular beam epitaxy for delta doping and superlattice doping for surface passivation and high UV quantum efficiency. Additional UV enhancements include antireflection (AR) and solar-blind UV bandpass coatings prepared by atomic layer deposition. Quantum efficiency (QE) measurements show QE > 50% in the 100–300 nm range for detectors with simple AR coatings, and QE ≅ 80% at ~206 nm has been shown when more complex AR coatings are used. The second approach is based on avalanche photodiodes in III-nitride materials with high QE and intrinsic solar blindness

Advances on CMOS image sensors

This paper offers an introduction to the technological advances of image sensors designed using complementary metal–oxide–semiconductor (CMOS) processes along the last decades. We review some of those technological advances and examine potential disruptive growth directions for CMOS image sensors and proposed ways to achieve them. Those advances include breakthroughs on image quality such as resolution, capture speed, light sensitivity and color detection and advances on the computational imaging. The current trend is to push the innovation efforts even further as the market requires higher resolution, higher speed, lower power consumption and, mainly, lower cost sensors. Although CMOS image sensors are currently used in several different applications from consumer to defense to medical diagnosis, product differentiation is becoming both a requirement and a difficult goal for any image sensor manufacturer. The unique properties of CMOS process allows the integration of several signal processing techniques and are driving the impressive advancement of the computational imaging. With this paper, we offer a very comprehensive review of methods, techniques, designs and fabrication of CMOS image sensors that have impacted or might will impact the images sensor applications and markets

Robust broad spectral photodetection (UV-NIR) and ultra high responsivity investigated in nanosheets and nanowires of Bi2Te3 under harsh nano-milling conditions

Due to miniaturization of device dimensions, the next generations photodetector based devices are expected to be fabricated from robust nanostructured materials. Hence there is an utmost requirement of investigating exotic optoelectronic properties of nanodevices fabricated from new novel materials and testing their performances at harsh conditions. The recent advances on 2D layered materials indicate exciting progress on broad spectral photodetection (BSP) but still there is a great demand for fabricating ultra-high performance photodetectors made from single material sensing broad electromagnetic spectrum since the detection range 325 nm to 1550 nm is not covered by the conventional Si or InGaAs photodetectors. Alternatively, Bi2Te3 is a layered material, possesses exciting optoelectronic, thermoelectric, plasmonics properties. Here we report robust photoconductivity measurements on Bi2Te3 nanosheets and nanowires demonstrating BSP from UV to NIR. The nanosheets of Bi2Te3 show the best ultra-high photoresponsivity (~74 A/W at 1550 nm ). Further these nanosheets when transform into nanowires using harsh FIB milling conditions exhibit about one order enhancement in the photoresponsivity without affecting the performance of the device even after 4 months of storage at ambient conditions. An ultra-high photoresponsivity and BSP indicate exciting robust nature of topological insulator based nanodevices for optoelectronic applications.Comment: 14 pages, 6 figure

Low Voltage Low Light Imager and Photodetector

Highly efficient, low energy, low light level imagers and photodetectors are provided. In particular, a novel class of Della-Doped Electron Bombarded Array (DDEBA) photodetectors that will reduce the size, mass, power, complexity, and cost of conventional imaging systems while improving performance by using a thinned imager that is capable of detecting low-energy electrons, has high gain, and is of low noise

Enabling Technologies for Next Generation Ultraviolet Astrophysics, Planetary, and Heliophysics Missions

Our study sought to create a new paradigm in UV instrument design, detector technology, and optics that will form the technological foundation for a new generation of ultraviolet missions. This study brought together scientists and technologists representing the broad community of astrophysicists, planetary and heliophysics physicists, and technologists working in the UV. Next generation UV missions require major advances in UV instrument design, optics and detector technology. UV offers one of the few remaining areas of the electromagnetic spectrum where this is possible, by combining improvements in detector quantum efficiency (5-10x), optical coatings and higher-performance wide-field spectrometers (5-10x), and increasing multiplex advantage (100-1000x). At the same time, budgets for future missions are tightly constrained. Attention has begun to turn to small and moderate class missions to provide new observational capabilities on timescales that maintain scientific vitality. Developments in UV technology offer a comparatively unique opportunity to conceive of small (Explorer) and moderate (Probe, Discovery, New Millennium) class missions that offer breakthrough science. Our study began with the science, reviewing the breakthrough science questions that compel the development of new observational capabilities in the next 10-20 years. We invented a framework for highlighting the objectives of UV measurement capabilities: following the history of baryons from the intergalactic medium to stars and planets. In astrophysics, next generation space UV missions will detect and map faint emission and tomographically map absorption from intergalactic medium baryons that delineate the structure of the Universe, map the circum-galactic medium that is the reservoir of galaxy-building gas, map the warm-hot ISM of our Galaxy, explore star-formation within the Local group and beyond, trace gas in proto-planetary disks and extended atmospheres of exoplanets, and record the transient UV universe. Solar system planetary atmospheric physics and chemistry, aurorae, surface composition and magnetospheric environments and interactions will be revealed using UV spectroscopy. UV spectroscopy may even detect life on an exoplanet. Our study concluded that with UV technology developments within reach over the next 5- 10 years, we can conceive moderate-class missions that will answer many of the compelling science questions driving the field. We reviewed the science measurement requirements for these pioneering new areas and corresponding technology requirements. We reviewed and evaluated the emerging technologies, and developed a figure of merit based on potential science impact, state of readiness, required investment, and potential for highly leveraged progress in a 5-10 year horizon. From this we were able to develop a strategy for technology development. Some of this technology development will be subject to funding calls from federal agencies. A subset form a portfolio of highly promising technologies that are ideal for funding from a KISS Development Program. One of our study’s principal conclusions was that UV detector performance drives every aspect of the scientific capability of future missions, and that two highly flexible detector technologies were at the tipping point for major breakthroughs. These are Gen-2 borosilicate Atomic Layer Deposition (ALD) coated microchannel plate detectors with GaN photocathodes, and ALDantireflection (AR) coated, delta-doped photon-counting CCD detectors. Both offer the potential for QE>50% combined with large formats and pixel counts, low background, and sky-limited photon-counting performance over the 100-300 nm band. Ramped AR coatings for spectroscopic detectors could achieve QE’s as high as 80%! A second conclusion was that UV coatings are on the threshold of a major breakthrough. UV coatings permeate every aspect of telescope and instrument design. Efficient, robust, ultra-thin and highly uniform reflective coatings applied with Atomic Layer Deposition (ALD) offer the possibility of high-performance, wide-field, highly-multiplexed UV spectrometers and a broadband reach covering the scientifically critical 100-120 nm range (home of 50% of all atomic and molecular resonance lines). Our study concluded that UV coating advances made possible by ALD is the principle technology advance that will enable a joint UV-optical general astrophysics and exoEarth imaging flagship mission. A third conclusion was that the revolution in micro- and nano-fabrication technology offers a cornucopia of new possibilities for revolutionary UV technology developments in the near future. An immediate example is the application of new microlithography techniques to patterning UV diffraction gratings that are highly efficient and designed to enable wide-field, high-resolution spectroscopy. These techniques could support the development of new detectors that could discriminate optical and UV photons and potentially energy-resolving detection. Relatively modest investments in technology development over the next 5-10 years could provide advances in detectors, coatings, diffractive elements, and filters that would result in an effective increase in science capability of 100-1000! The study brought together a diverse community, led to many new ideas and collaborations, and brought cohesion and common purpose to UV practitioners. This will have a lasting and positive impact on the future of our field

Optofluidic plasmonic onchip nanosensor array for biodetection

Thesis (Ph.D.)--Boston UniversitySurface plasmon resonance (SPR) sensing has been demonstrated in the past decade to be the gold standard technique for biochemical interaction analysis, and plays an important role in drug discovery and biomedical research. The technique circumvents the need of fluorescence/radioactive tagging or enzymatic detection, enables ultrasensitive remote sensing, and quantitatively monitors bio-interaction in real time. Although SPR has these attractive features that can satisfy most research/clinic requirements, there still exist problems that limit its applications. First, the reflection geometry of the prism coupling scheme adds limitations for high throughput screening application. Additionally, SPR instrumentations are bulky and not suitable for point-of-care settings. Moreover, the SPR sensor is embedded in conventional micro-fluidic cells, in which the sensor performance is limited by inefficient analyte transport. Suspended plasmonic nanohole array (PNA) offers an opportunity to overcome these limitations. A collinear excitation/collection coupling scheme combined with the small footprint of PNA provides unique platform for multiplexing and system minimization. The suspended nanohole structure also offers a unique configuration to integrate nano-photonics with nano-fluidics. This thesis focuses on developing a lab-on-a-chip PNA platform for point-of-care bio-detection. To achieve this, we first demonstrate that the figure-of-merit of our PNA sensor surpasses that of the prism coupled SPR. We also show that the ultrasensitive label-free PNA sensor is able to directly detect intact viruses from biological media at clinically relevant concentrations with little sample preparation. We then present a plasmonic microarray with over one million PNA sensors on a microscope slide for high throughput screening applications. A dual-color filter imaging method is introduced to increase the accuracy, reliability, and signal-to-noise ratio in a highly multiplexed manner. Finally, we present a nanoplasmonic-nanofluidic platform enabling active delivery of analyte to the sensor. Sensor response time is reduced by an order of magnitude compared to the conventional flow scheme. A dynamic range spanning 5 orders of magnitude from 10^3 to 10^7 particles/mL is shown on this platform corresponding to analyte concentration sufficient for clinical applications. The proposed approach opens up opportunities of a lab-on-a-chip bio-detection system for drug screening, disease diagnostic as well as clinic studies

Flexible ultraviolet and ambient light sensor based on nanomaterial network fabricated by using selective and localized wet-chemical reactions

We report ZnO nanowire- and TiO_2 nanotube-based light sensors on flexible polymer substrates fabricated by localized hydrothermal synthesis and liquid phase deposition (LPD). This method realized simple and cost-effective in situ synthesis and integration of one-dimensional ZnO and TiO_2 nanomaterials. The fabricated sensor devices with ZnO nanowires and TiO_2 nanotubes show very high sensitivity and quick response to the ultraviolet (UV) and ambient light, respectively. In addition, our direct synthesis and integration method result in mechanical robustness under external loading such as static and cyclic bending because of the strong bonding between the nanomaterial and the electrode. By controlling the reaction time of the LPD process, the Ti/Zn ratio could be simply modulated and the spectral sensitivity to the light in the UV to visible range could be controlled

Exploration of Miniature Flexible Devices Empowered by Van Der Waals Material

This research mainly focuses on the fabrication of miniature flexible devices empowered by van der Waals materials. Through the extensive experiments contained in this thesis, by exploring the characteristics of van der Waals materials, optimizing the manufacturing process of lithography technology, and characterizing the photoelectric performance of micro devices, this thesis has promoted the development of micro flexible device manufacturing and expanded its applications in the fields of biological detection, medical treatment, and environmental monitoring. We introduced a miniature van der Waals semiconductor empowered vertical color sensor, which saves three times the volume space compared to the traditional planer color sensor and includes multiple optical aberration correction functions as well. Such a small red, green, and blue (RGB) color sensor can be applied in bionic eyes, breaking through the limitations of existing black and white recognition. On this basis, we further explored the stretchability of two-dimensional materials represented by MoS2. We proposed a chemical treatment method combined with gold nanoparticles and (3-mercaptopropyl)trimethoxysilane (MPTMS) to realize the relocation of flexible micro devices. This method improves the adhesion between the material layer and the flexible substrate (PDMS), which significantly increases the flexible device stretchability, and prolongs its service life. Through the above work, this thesis explores the van der Waals materials’ properties, and optimizes the manufacturing process of micro devices, further exerts the advantages of material flexibility, therefore provides more possibilities for the development of smart wearable devices, biomedical detection, and other fields

Single Photon Counting UV Solar-Blind Detectors Using Silicon and III-Nitride Materials

Ultraviolet (UV) studies in astronomy, cosmology, planetary studies, biological and medical applications often require precision detection of faint objects and in many cases require photon-counting detection. We present an overview of two approaches for achieving photon counting in the UV. The first approach involves UV enhancement of photon-counting silicon detectors, including electron multiplying charge-coupled devices and avalanche photodiodes. The approach used here employs molecular beam epitaxy for delta doping and superlattice doping for surface passivation and high UV quantum efficiency. Additional UV enhancements include antireflection (AR) and solar-blind UV bandpass coatings prepared by atomic layer deposition. Quantum efficiency (QE) measurements show QE > 50% in the 100–300 nm range for detectors with simple AR coatings, and QE ≅ 80% at ~206 nm has been shown when more complex AR coatings are used. The second approach is based on avalanche photodiodes in III-nitride materials with high QE and intrinsic solar blindness

NASA Tech Briefs, January 2007

Topics covered include: Flexible Skins Containing Integrated Sensors and Circuitry; Artificial Hair Cells for Sensing Flows; Video Guidance Sensor and Time-of-Flight Rangefinder; Optical Beam-Shear Sensors; Multiple-Agent Air/Ground Autonomous Exploration Systems; A 640 512-Pixel Portable Long-Wavelength Infrared Camera; An Array of Optical Receivers for Deep-Space Communications; Microstrip Antenna Arrays on Multilayer LCP Substrates; Applications for Subvocal Speech; Multiloop Rapid-Rise/Rapid Fall High-Voltage Power Supply; The PICWidget; Fusing Symbolic and Numerical Diagnostic Computations; Probabilistic Reasoning for Robustness in Automated Planning; Short-Term Forecasting of Radiation Belt and Ring Current; JMS Proxy and C/C++ Client SDK; XML Flight/Ground Data Dictionary Management; Cross-Compiler for Modeling Space-Flight Systems; Composite Elastic Skins for Shape-Changing Structures; Glass/Ceramic Composites for Sealing Solid Oxide Fuel Cells; Aligning Optical Fibers by Means of Actuated MEMS Wedges; Manufacturing Large Membrane Mirrors at Low Cost; Double-Vacuum-Bag Process for Making Resin- Matrix Composites; Surface Bacterial-Spore Assay Using Tb3+/DPA Luminescence; Simplified Microarray Technique for Identifying mRNA in Rare Samples; High-Resolution, Wide-Field-of-View Scanning Telescope; Multispectral Imager With Improved Filter Wheel and Optics; Integral Radiator and Storage Tank; Compensation for Phase Anisotropy of a Metal Reflector; Optical Characterization of Molecular Contaminant Films; Integrated Hardware and Software for No-Loss Computing; Decision-Tree Formulation With Order-1 Lateral Execution; GIS Methodology for Planning Planetary-Rover Operations; Optimal Calibration of the Spitzer Space Telescope; Automated Detection of Events of Scientific Interest; Representation-Independent Iteration of Sparse Data Arrays; Mission Operations of the Mars Exploration Rovers; and More About Software for No-Loss Computing