Dislocation constriction and cross-slip in Al and Ag: an ab initio study

A novel model based on the Peierls framework of dislocations is developed. The new theory can deal with a dislocation spreading at more than one slip planes. As an example, we study dislocation cross-slip and constriction process of two fcc metals, Al and Ag. The energetic parameters entering the model are determined from ab initio calculations. We find that the screw dislocation in Al can cross-slip spontaneously in contrast with that in Ag, which splits into partials and cannot cross-slip without first being constricted. The dislocation response to an external stress is examined in detail. We determine dislocation constriction energy and critical stress for cross-slip, and from the latter, we estimate the cross-slip energy barrier for the straight screw dislocations

Self-similar slip pulses during rate-and-state earthquake nucleation

For a wide range of conditions, earthquake nucleation zones on rate- and state-dependent faults that obey either of the popular state evolution laws expand as they accelerate. Under the “slip” evolution law, which experiments show to be the more relevant law for nucleation, this expansion takes the form of a unidirectional slip pulse. In numerical simulations these pulses often tend to approach, with varying degrees of robustness, one of a few styles of self-similar behavior. Here we obtain an approximate self-similar solution that accurately describes slip pulses growing into regions initially sliding at steady state. In this solution the length scale over which slip speeds are significant continually decreases, being inversely proportional to the logarithm of the maximum slip speed V_(max), while the total slip remains constant. This slip is close to D_c(1−a/b)^(−1), where D_c is the characteristic slip scale for state evolution and a and b are the parameters that determine the sensitivity of the frictional strength to changes in slip rate and state. The pulse has a “distance to instability” as well as a “time to instability,” with the remaining propagation distance being proportional to (1−a/b)^(−2) [ln(V_(max)Θ_(bg)/D_c)]^(−1), where Θ_(bg) is the background state into which the pulse propagates. This solution provides a reasonable estimate of the total slip for pulses growing into regions that depart modestly from steady state

Surface roughness and interfacial slip boundary condition for quartz crystal microbalances

The response of a quartz crystal microbalance (QCM) is considered using a wave equation for the substrate and the Navier-Stokes equations for a finite liquid layer under a slip boundary condition. It is shown that when the slip length to shear wave penetration depth is small, the first order effect of slip is only present in the frequency response. Importantly, in this approximation the frequency response satisfies an additivity relation with a net response equal to a Kanazawa liquid term plus an additional Sauerbrey "rigid" liquid mass. For the slip length to result in an enhanced frequency decrease compared to a no-slip boundary condition, it is shown that the slip length must be negative so that the slip plane is located on the liquid side of the interface. It is argued that the physical application of such a negative slip length could be to the liquid phase response of a QCM with a completely wetted rough surface. Effectively, the model recovers the starting assumption of additivity used in the trapped mass model for the liquid phase response of a QCM having a rough surface. When applying the slip boundary condition to the rough surface problem, slip is not at a molecular level, but is a formal hydrodynamic boundary condition which relates the response of the QCM to that expected from a QCM with a smooth surface. Finally, possible interpretations of the results in terms of acoustic reflectivity are developed and the potential limitations of the additivity result should vapour trapping occur are discussed

Slip behavior in liquid films on surfaces of patterned wettability: Comparison between continuum and molecular dynamics simulations

We investigate the behavior of the slip length in Newtonian liquids subject to planar shear bounded by substrates with mixed boundary conditions. The upper wall, consisting of a homogenous surface of finite or vanishing slip, moves at a constant speed parallel to a lower stationary wall, whose surface is patterned with an array of stripes representing alternating regions of no-shear and finite or no-slip. Velocity fields and effective slip lengths are computed both from molecular dynamics (MD) simulations and solution of the Stokes equation for flow configurations either parallel or perpendicular to the stripes. Excellent agreement between the hydrodynamic and MD results is obtained when the normalized width of the slip regions, $a/\sigma \gtrsim {\cal O}(10)$, where $\sigma$ is the (fluid) molecular diameter characterizing the Lennard-Jones interaction. In this regime, the effective slip length increases monotonically with $a/\sigma$ to a saturation value. For $a/\sigma \lesssim {\cal O}(10)$ and transverse flow configurations, the non-uniform interaction potential at the lower wall constitutes a rough surface whose molecular scale corrugations strongly reduce the effective slip length below the hydrodynamic results. The translational symmetry for longitudinal flow eliminates the influence of molecular scale roughness; however, the reduced molecular ordering above the wetting regions of finite slip for small values of $a/\sigma$ increases the value of the effective slip length far above the hydrodynamic predictions. The strong inverse correlation between the effective slip length and the liquid structure factor representative of the first fluid layer near the patterned wall illustrates the influence of molecular ordering effects on slip in non-inertial flows.Comment: 12 pages, 10 figures Web reference added for animations: http://www.egr.msu.edu/~priezjev/bubble/bubble.htm

Power-Law Slip Profile of the Moving Contact Line in Two-Phase Immiscible Flows

Large scale molecular dynamics (MD) simulations on two-phase immiscible flows show that associated with the moving contact line, there is a very large $1/x$ partial-slip region where $x$ denotes the distance from the contact line. This power-law partial-slip region is verified in large-scale adaptive continuum simulations based on a local, continuum hydrodynamic formulation, which has proved successful in reproducing MD results at the nanoscale. Both MD and continuum simulations indicate the existence of a universal slip profile in the Stokes-flow regime, well described by $v^{slip}(x)/V_w=1/(1+{x}/{al_s})$, where $v^{slip}$ is the slip velocity, $V_w$ the speed of moving wall, $l_s$ the slip length, and $a$ is a numerical constant. Implications for the contact-line dissipation are discussed.Comment: 13 pages, 3 figure

Wall slip and flow of concentrated hard-sphere colloidal suspensions

We present a comprehensive study of the slip and flow of concentrated colloidal suspensions using cone-plate rheometry and simultaneous confocal imaging. In the colloidal glass regime, for smooth, non-stick walls, the solid nature of the suspension causes a transition in the rheology from Herschel-Bulkley (HB) bulk flow behavior at large stress to a Bingham-like slip behavior at low stress, which is suppressed for sufficient colloid-wall attraction or colloid-scale wall roughness. Visualization shows how the slip-shear transition depends on gap size and the boundary conditions at both walls and that partial slip persist well above the yield stress. A phenomenological model, incorporating the Bingham slip law and HB bulk flow, fully accounts for the behavior. Microscopically, the Bingham law is related to a thin (sub-colloidal) lubrication layer at the wall, giving rise to a characteristic dependence of slip parameters on particle size and concentration. We relate this to the suspension's osmotic pressure and yield stress and also analyze the influence of van der Waals interaction. For the largest concentrations, we observe non-uniform flow around the yield stress, in line with recent work on bulk shear-banding of concentrated pastes. We also describe residual slip in concentrated liquid suspensions, where the vanishing yield stress causes coexistence of (weak) slip and bulk shear flow for all measured rates

Analysis of the potential mechanisms of rockbursts

Sudden slip on geological faults or other discontinuities in rock may be preceded by an initial phase of "slow" fault creep. A simple plane strain model of a suddenly loaded fault is analysed to illustrate the possible transition from stable slip behaviour to accelerated, unstable slip. The model assumes that a peaked shear load is applied suddenly to the fault region. The rate of slip movement is assumed to be proportional to the difference between the applied shear stress and the cohesive and frictional slip resistance. It is found that the evolutionary fault movement can be described succinctly by a non-linear ordinary differential equation describing the activated length of the sliding fault as a function of time. The differential equation is found to depend on a single, dimensionless parameter whose value determines whether the fault slip decays monotonically or accelerates in an unstable manner