Steric Effects of Alkyl Ammonium Salts on the Combustion of Exchanged Smectite Clays

Bomb calorimetry was explored as a new method for determining the cation exchange capacity (CEC) of clays. Smectite clays were modified with several alkyl ammonium salts varying in number of carbons and the spatial orientation of the carbons about the central nitrogen atom. The clays used, standards purchased from the Source Clay Repository, have CECs of 44, 80, 88, and 120 meq/100 g. Theoretically, the combustion energy of the organo-clays should be approximately the same for each salt. Any differences in energy would be due to the different structures of the salts and how they are oriented in the interlamellar region of the clay. The number of alkyl ammonium salts that bind to the negatively charged sites in the clay layers would represent the CEC of the clay. The orientation of the organic cation in the interlamellar region was examined using x-ray powder diffraction, which provides the spacing between the clay layers. The combustion energy data collected using bomb calorimetry was used to calculate the CEC of the clay by comparing the energy from the pure salts to determine the number of salt molecules intercalated into the clay. Since the pure salt and the clay have a one-to-one charge ratio, the number of salt molecules will directly represent the number of negatively charged sites on the clay which is the CEC of the clay

Coccolithophore biodiversity controls carbonate export in the Southern Ocean

Southern Ocean waters are projected to undergo profound changes in their physical and chemical properties in the coming decades. Coccolithophore blooms in the Southern Ocean are thought to account for a major fraction of the global marine calcium carbonate (CaCO3) production and export to the deep sea. Therefore, changes in the composition and abundance of Southern Ocean coccolithophore populations are likely to alter the marine carbon cycle, with feedbacks to the rate of global climate change. However, the contribution of coccolithophores to CaCO3 export in the Southern Ocean is uncertain, particularly in the circumpolar subantarctic zone that represents about half of the areal extent of the Southern Ocean and where coccolithophores are most abundant. Here, we present measurements of annual CaCO3 flux and quantitatively partition them amongst coccolithophore species and heterotrophic calcifiers at two sites representative of a large portion of the subantarctic zone. We find that coccolithophores account for a major fraction of the annual CaCO3 export, with the highest contributions in waters with low algal biomass accumulations. Notably, our analysis reveals that although Emiliania huxleyi is an important vector for CaCO3 export to the deep sea, less abundant but larger species account for most of the annual coccolithophore CaCO3 flux. This observation contrasts with the generally accepted notion that high particulate inorganic carbon accumulations during the austral summer in the subantarctic Southern Ocean are mainly caused by E. huxleyi blooms. It appears likely that the climate-induced migration of oceanic fronts will initially result in the poleward expansion of large coccolithophore species increasing CaCO3 production. However, subantarctic coccolithophore populations will eventually diminish as acidification overwhelms those changes. Overall, our analysis emphasizes the need for species-centred studies to improve our ability to project future changes in phytoplankton communities and their influence on marine biogeochemical cycles.info:eu-repo/semantics/publishedVersio

Automatic transcription of Turkish makam music

In this paper we propose an automatic system for transcribing/nmakam music of Turkey. We document the specific/ntraits of this music that deviate from properties that/nwere targeted by transcription tools so far and we compile/na dataset of makam recordings along with aligned microtonal/nground-truth. An existing multi-pitch detection algorithm/nis adapted for transcribing music in 20 cent resolution,/nand the final transcription is centered around the/ntonic frequency of the recording. Evaluation metrics for/ntranscribing microtonal music are utilized and results show/nthat transcription of Turkish makam music in e.g. an interactive/ntranscription software is feasible using the current/nstate-of-the-art.This work is partly supported by the European/nResearch Council under the European Union’s Seventh/nFramework Program, as part of the CompMusic project/n(ERC grant agreement 267583)

Probabilities and Quantum Reality: Are There Correlata?

Any attempt to introduce probabilities into quantum mechanics faces difficulties due to the mathematical structure of Hilbert space, as reflected in Birkhoff and von Neumann's proposal for a quantum logic. The (consistent or decoherent) histories solution is provided by its single framework rule, an approach that includes conventional (Copenhagen) quantum theory as a special case. Mermin's Ithaca interpretation addresses the same problem by defining probabilities which make no reference to a sample space or event algebra (``correlations without correlata''). But this leads to severe conceptual difficulties, which almost inevitably couple quantum theory to unresolved problems of human consciousness. Using histories allows a sharper quantum description than is possible with a density matrix, suggesting that the latter provides an ensemble rather than an irreducible single-system description as claimed by Mermin. The histories approach satisfies the first five of Mermin's desiderata for a good interpretation of quantum mechanics, including Einstein locality, but the Ithaca interpretation seems to have difficulty with the first (independence of observers) and the third (describing individual systems).Comment: Latex 31 pages, 3 figures in text using PSTrick

Radio-quiet and radio-loud pulsars: similar in Gamma-rays but different in X-rays

We present new Chandra and XMM-Newton observations of a sample of eight radio-quiet Gamma-ray pulsars detected by the Fermi Large Area Telescope. For all eight pulsars we identify the X-ray counterpart, based on the X-ray source localization and the best position obtained from Gamma-ray pulsar timing. For PSR J2030+4415 we found evidence for an about 10 arcsec-long pulsar wind nebula. Our new results consolidate the work from Marelli et al. 2011 and confirm that, on average, the Gamma-ray--to--X-ray flux ratios (Fgamma/Fx) of radio-quiet pulsars are higher than for the radio-loud ones. Furthermore, while the Fgamma/Fx distribution features a single peak for the radio-quiet pulsars, the distribution is more dispersed for the radio-loud ones, possibly showing two peaks. We discuss possible implications of these different distributions based on current models for pulsar X-ray emission.Comment: Accepted for publication in The Astrophysical Journal; 12 pages, 3 figures, 2 table

The New Quantum Logic

It is shown how all the major conceptual difficulties of standard (textbook) quantum mechanics, including the two measurement problems and the (supposed) nonlocality that conflicts with special relativity, are resolved in the consistent or decoherent histories interpretation of quantum mechanics by using a modified form of quantum logic to discuss quantum properties (subspaces of the quantum Hilbert space), and treating quantum time development as a stochastic process. The histories approach in turn gives rise to some conceptual difficulties, in particular the correct choice of a framework (probabilistic sample space) or family of histories, and these are discussed. The central issue is that the principle of unicity, the idea that there is a unique single true description of the world, is incompatible with our current understanding of quantum mechanics.Comment: Minor changes and corrections to bring into conformity with published versio

Non-Abelian phases in two-component ν=2/3\nu=2/3 fractional quantum Hall states: Emergence of Fibonacci anyons

Recent theoretical insights into the possibility of non-Abelian phases in $\nu=2/3$ fractional quantum Hall states revived the interest in the numerical phase diagram of the problem. We investigate the effect of various kinds of two-body interlayer couplings on the $(330)$ bilayer state and exactly solve the Hamiltonian for up to $14$ electrons on sphere and torus geometries. We consider interlayer tunneling, short-ranged repulsive/attractive pseudopotential interactions and Coulomb repulsion. We find a 6-fold ground-state degeneracy on the torus when the interlayer hollow-core interaction is dominant. To identify the topological nature of this phase we measure the orbital-cut entanglement spectrum, quasihole counting, topological entanglement entropy, and wave-function overlap. Comparing the numerical results to the theoretical predictions, we interpret this 6-fold ground-state degeneracy phase to be the non-Abelian bilayer Fibonacci state.Comment: 5+5 pages, 3+1 figures, published versio

Preparatory studies of zero-g cloud drop coalescence experiment

Experiments to be performed in a weightless environment in order to study collision and coalescence processes of cloud droplets are described. Rain formation in warm clouds, formation of larger cloud drops, ice and water collision processes, and precipitation in supercooled clouds are among the topics covered