33,121 research outputs found
Excitation and emission spectra of rubidium in rare-gas thin-films
To understand the optical properties of atoms in solid state matrices, the
absorption, excitation and emission spectra of rubidium doped thin-films of
argon, krypton and xenon were investigated in detail. A two-dimensional
spectral analysis extends earlier reports on the excitation and emission
properties of rubidium in rare-gas hosts. We found that the doped crystals of
krypton and xenon exhibit a simple absorption-emission relation, whereas
rubidium in argon showed more complicated spectral structures. Our sample
preparation employed in the present work yielded different results for the Ar
crystal, but our peak positions were consistent with the prediction based on
the linear extrapolation of Xe and Kr data. We also observed a bleaching
behavior in rubidium excitation spectra, which suggests a population transfer
from one to another spectral feature due to hole-burning. The observed optical
response implies that rubidium in rare-gas thin-films is detectable with
extremely high sensitivity, possibly down to a single atom level, in low
concentration samples.Comment: 7 pages, 5 figure
Sympathetic cooling in a mixture of diamagnetic and paramagnetic atoms
We have experimentally realized a hybrid trap for ultracold paramagnetic
rubidium and diamagnetic ytterbium atoms by combining a bichromatic optical
dipole trap for ytterbium with a Ioffe-Pritchard-type magnetic trap for
rubidium. In this hybrid trap, sympathetic cooling of five different ytterbium
isotopes through elastic collisions with rubidium was achieved. A strong
dependence of the interspecies collisional cross section on the mass of the
ytterbium isotope was observed.Comment: 4 pages, 4 figure
Electromagnetically induced transparency and four-wave mixing in a cold atomic ensemble with large optical depth
We report on the delay of optical pulses using electromagnetically induced
transparency in an ensemble of cold atoms with an optical depth exceeding 500.
To identify the regimes in which four-wave mixing impacts on EIT behaviour, we
conduct the experiment in both rubidium 85 and rubidium 87. Comparison with
theory shows excellent agreement in both isotopes. In rubidium 87, negligible
four-wave mixing was observed and we obtained one pulse-width of delay with 50%
efficiency. In rubidium 85, four-wave-mixing contributes to the output. In this
regime we achieve a delay-bandwidth product of 3.7 at 50% efficiency, allowing
temporally multimode delay, which we demonstrate by compressing two pulses into
the memory medium.Comment: 8 pages, 6 figure
Thermal Studies on Rubidium Dinitramide
The present study has been carried out to investigate conflicting reports in the literature on the nature of the thermal decomposition of the energetic oxidant rubidium dinitramide in the liquid state. The techniques employed included DSC, simultaneous TG-DTA, simultaneous TG-mass spectrometry and thermomicroscopy. The measurements were supplemented by quantitative chemical analysis of the reaction products. The results showed that, following fusion at 106 °C, the overall decomposition proceeded in a single exothermic reaction stage forming a mixture of rubidium nitrate and rubidium nitrite in the molar ratio 1.2 : 1
Coherent Dark States of Rubidium 87 in a Buffer Gas using Pulsed Laser Light
The coherent dark resonance between the hyperfine levels F=1, m=0 and F=2,
m=0 of the rubidium ground state has been observed experimentally with the
light of a pulsed mode-locked diode laser operating at the D1 transition
frequency. The resonance occurs whenever the pulse repetition frequency matches
an integer fraction of the rubidium 87 ground state hyperfine splitting of 6.8
GHz. Spectra have been taken by varying the pulse repetition frequency. Using
cells with argon as a buffer gas a linewidth as narrow as 149 Hz was obtained.
The rubidium ground state decoherence cross section 1.1*10^(-18) cm^2 for
collisions with xenon atoms has been measured for the first time with this
method using a pure isotope rubidium vapor cell and xenon as a buffer gas.Comment: 3 pages, 5 figures, 1 misprint correcte
Novel Rubidium Poly-Nitrogen Materials at High Pressure
First-principles crystal structure search is performed to predict novel
rubidium poly-nitrogen materials at high pressure by varying the stoichiometry,
i. e. relative quantities of the constituent rubidium and nitrogen atoms. Three
compounds of high nitrogen content, RbN_{5}, RbN_{2}, and Rb_{4}N_{6}, are
discovered. Rubidium pentazolate (RbN5) becomes thermodynamically stable at
pressures above \unit[30]{GPa}. The charge transfer from Rb to N atoms enables
aromaticity in cyclo-N_{^{_{5}}}^{-} while increasing the ionic bonding in the
crystal. Rubidium pentazolate can be synthesized by compressing rubidium azide
(RbN3) and nitrogen (N2) precursors above \unit[9.42]{GPa}, and its
experimental discovery is aided by calculating the Raman spectrum and
identifying the features attributed to N_{^{_{5}}}^{-} modes. The two other
interesting compounds, RbN2 containing infinitely-long single-bonded nitrogen
chains, and Rb_{4}N_{6} consisting of single-bonded N_{6} hexazine rings,
become thermodynamically stable at pressures exceeding \unit[60]{GPa}. In
addition to the compounds with high nitrogen content, Rb_{3}N_{3}, a new
compound with 1:1 RbN stoichiometry containing bent N_{3} azides is found to
exist at high pressures
Lifetime Measurement of the 6s Level of Rubidium
We present a lifetime measurements of the 6s level of rubidium. We use a
time-correlated single-photon counting technique on two different samples of
rubidium atoms. A vapor cell with variable rubidium density and a sample of
atoms confined and cooled in a magneto-optical trap. The 5P_{1/2} level serves
as the resonant intermediate step for the two step excitation to the 6s level.
We detect the decay of the 6s level through the cascade fluorescence of the
5P_{3/2} level at 780 nm. The two samples have different systematic effects,
but we obtain consistent results that averaged give a lifetime of 45.57 +- 0.17
ns.Comment: 10 pages, 9 figure
Laser Cooling of Dense Rubidium-Noble Gas Mixtures via Collisional Redistribution of Radiation
We describe experiments on the laser cooling of both helium-rubidium and
argon-rubidium gas mixtures by collisional redistribution of radiation.
Frequent alkali-noble gas collisions in the ultradense gas, with typically
200\,bar of noble buffer gas pressure, shift a highly red detuned optical beam
into resonance with a rubidium D-line transition, while spontaneous decay
occurs close to the unshifted atomic resonance frequency. The technique allows
for the laser cooling of macroscopic ensembles of gas atoms. The use of helium
as a buffer gas leads to smaller temperature changes within the gas volume due
to the high thermal conductivity of this buffer gas, as compared to the heavier
argon noble gas, while the heat transfer within the cell is improved.Comment: 8 pages, 6 figure
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