Low-Power Heterogeneous Graphene Nanoribbon-CMOS Multistate Volatile Memory Circuit

Graphene is an emerging nanomaterial believed to be a potential candidate for post-Si nanoelectronics, due to its exotic properties. Recently, a new graphene nanoribbon crossbar (xGNR) device was proposed which exhibits negative differential resistance (NDR). In this paper, a multi-state memory design is presented that can store multiple bits in a single cell enabled by this xGNR device, called Graphene Nanoribbon Tunneling Random Access Memory (GNTRAM). An approach to increase the number of bits per cell is explored alternative to physical scaling to overcome CMOS SRAM limitations. A comprehensive design for quaternary GNTRAM is presented as a baseline, implemented with a heterogeneous integration between graphene and CMOS. Sources of leakage and approaches to mitigate them are investigated. This design is extensively benchmarked against 16nm CMOS SRAMs and 3T DRAM. The proposed quaternary cell shows up to 2.27x density benefit vs. 16nm CMOS SRAMs and 1.8x vs. 3T DRAM. It has comparable read performance and is power-efficient, up to 1.32x during active period and 818x during stand-by against high performance SRAMs. Multi-state GNTRAM has the potential to realize high-density low-power nanoscale embedded memories. Further improvements may be possible by using graphene more extensively, as graphene transistors become available in future

Scalability of the channel capacity in graphene-enabled wireless communications to the nanoscale

Graphene is a promising material which has been proposed to build graphene plasmonic miniaturized antennas, or graphennas, which show excellent conditions for the propagation of Surface Plasmon Polariton (SPP) waves in the terahertz band. Due to their small size of just a few micrometers, graphennas allow the implementation of wireless communications among nanosystems, leading to a novel paradigm known as Graphene-enabled Wireless Communications (GWC). In this paper, an analytical framework is developed to evaluate how the channel capacity of a GWC system scales as its dimensions shrink. In particular, we study how the unique propagation of SPP waves in graphennas will impact the channel capacity. Next, we further compare these results with respect to the case when metallic antennas are used, in which these plasmonic effects do not appear. In addition, asymptotic expressions for the channel capacity are derived in the limit when the system dimensions tend to zero. In this scenario, necessary conditions to ensure the feasibility of GWC networks are found. Finally, using these conditions, new guidelines are derived to explore the scalability of various parameters, such as transmission range and transmitted power. These results may be helpful for designers of future GWC systems and networks.Peer ReviewedPostprint (author’s final draft

A Double-Voltage-Controlled Effective Thermal Conductivity Model of Graphene for Thermoelectric Cooling

© 1963-2012 IEEE. Graphene provides a new opportunity for thermoelectric study based on its unique heat transfer behavior controllable by a gate voltage. In this paper, an effective thermal conductivity model of graphene for thermoelectric cooling is proposed. The model is based on a double-voltage-control mechanism. According to the law of Fourier heat conduction, an effective thermal conductivity model of the proposed thermoelectric cooling device is derived taking a tunable external voltage into account. Then, a gate voltage is used which can change graphene's thermoelectric characteristics. To verify the correctness and effectiveness of the proposed model, a circuit simulation model using HSPICE is built based on the thermoelectric duality. The simulation results from HSPICE and the calculated results from the mathematic model show good agreements with each other. This paper provides a novel precisely controlling method for thermoelectric cooling

Plasmonic Properties of Nanoparticle and Two Dimensional Material Integrated Structure

Recently, various groups have demonstrated nano-scale engineering of nanostructures for optical to infrared wavelength plasmonic applications. Most fabrication technique processes, especially those using noble metals, requires an adhesion layer. Previously proposed theoretical work to support experimental measurement often neglect the effect of the adhesion layers. The first finding of this work focuses on the impact of the adhesion layer on nanoparticle plasmonic properties. Gold nanodisks with a titanium adhesion layer are investigated by calculating the scattering, absorption, and extinction cross-section with numerical simulations using a finite difference time domain (FDTD) method. I demonstrate that a gold nanodisk with an adhesive layer significantly shifts the plasmon resonance relative to one without adhesion material. In addition, the adhesive layer also introduces stronger damping and decay time. Next, I investigate the plasmonic properties and effects of dielectric environment of black phosphorene (BP), a newly discovered anisotropic 2D material. Results suggest that the surface plasmon properties of a black phosphorene nanoribbon could be exploited to probe the efficiency of edge plasmonic enhanced absorption. Furthermore, the enhanced absorption of periodic BP nanoribbons is affected strongly by high density free carriers in BP nanoribbon geometries from mid-infrared to high infrared regime. Also when adding a thin dielectric shielding layer, such as hexagonal boron nitride, in addition to preserving the edge mode plasmonic nature of BP, it also allows for an unprecedented control of the absorption resonance energy. Finally, I also show monolayer graphene surface plasmon hybridization with hyperbolic phonon polarization local density of state of hyperbolic ferroelectric LiNbO3. The results show that the dispersion mode hybridization process is significantly regulated by a electrostatic gated single graphene and double graphene layer in addition to the ferroelectric layer size. The spontaneous emission (SE) rate the hyperbolic band contribution of LiNbO3 with graphene integrated system elucidated enhancement and inhibit spontaneous emission. Specially, the SE rate between in hybrid system is always smaller than that of the bulk in the hyperbolic band region with higher chemical potential

Transport and Optical Properties of Quantized Low-Dimensional Systems

In this thesis, we present a systematic investigation of the static and dynamic response properties of low-dimensional systems, using a variety of theoretical techniques ranging from time dependent density functional theory to the recursive Green\u27s function method. As typical low-dimensional systems, metal nanostructures can strongly interact with an electric field to support surface plasmons, making their optical properties extremely attractive in both fundamental and applied aspects. We have investigated the energy broadening of surface plasmons in metal structures of reduced dimensionality, where Landau damping is the dominant dissipation channel and presents an intrinsic limitation to plasmonics technology. We show that for every prototype class of systems considered, including nanoshells, coaxial nanotubes, and ultrathin films, Landau damping can be drastically tuned due to energy quantization of the individual electron levels and e-h pairs. Both the generic trend and oscillatory nature of the tunability are in stark contrast with the expectations of the semiclassical surface scattering picture. For a more realistic environment of low-dimensional systems, the effect of a dielectric substrate is considered to mimic the experimental setup. We have studied the dispersion of various plasmon excitations in metal thin films with growth substrates. Our results qualitatively reproduce the experimentally observed plasmon spectra of the Mg/Si systems. The underlying physics for the formation of various absorption peaks can be understood with a simple hybridization concept. Based on this concept, the coexistence of surface and bulk plasmons in experimental observation turns out to be a clear evidence for the existence of multiple-multipole surface plasmons due to the quantum confinement in thin films. To step into more confined worlds, we choose the real two-dimensional material graphene as our representive system, which is a semi-metal with zero band-gap. As the first step, the static electric response of graphene is investigated by exploring its transport properties. We have studied the pseudospin valve effect in bilayer graphene nanoribbons. The pseudospin degree of freedom is associated with the electron density in two layers and can be controlled by external gate electrodes. We find that the conductance of nanoribbons shows different behaviors compared with infinite systems due to the appearance of edge states and quantum confinement. Remarkably, a large on-off ratio can be achieved in nanoribbons with zigzag edges, even when the Fermi energy lies in the bulk energy gap. The influence of possible edge vacancies and interface conditions is also discussed. Finally, we discuss the possibility of using plasmon excitations to detach the graphene from its growth substrate, where the dynamic electric response of the graphene-metal system is expected to play a central role

Emergence of complexity in hierarchically organized chiral particles

The structural complexity of composite biomaterials and biomineralized particles arises from the hierarchical ordering of inorganic building blocks over multiple scales. Although empirical observations of complex nanoassemblies are abundant, the physicochemical mechanisms leading to their geometrical complexity are still puzzling, especially for nonuniformly sized components. We report the self-assembly of hierarchically organized particles (HOPs) from polydisperse gold thiolate nanoplatelets with cysteine surface ligands. Graph theory methods indicate that these HOPs, which feature twisted spikes and other morphologies, display higher complexity than their biological counterparts. Their intricate organization emerges from competing chirality-dependent assembly restrictions that render assembly pathways primarily dependent on nanoparticle symmetry rather than size. These findings and HOP phase diagrams open a pathway to a large family of colloids with complex architectures and unusual chiroptical and chemical properties