Plasma Surface Treatment of Powder Materials — Process and Application

Polyolefin particles are hydrophobic, and this prevents their use for various applications. Plasma treatment is an environment-friendly polyolefin hydrophilisation method. We developed an industrial-scale plant for plasma treatment of particles as small as micrometers in diameter. Materials such as PE waxes, UHMWPE and powders for rotomolding production were tested to verify their new surface properties. We achieved significantly increased wettability of the particles, so that they are very easily dispersive in water without agglomeration, and their higher surface energy is retained even after sintering in the case of rotomolding powders

The physical and thermal properties of modified rotational molding grade silane cross-linked polyethylene compound

This study is aimed at investigating the physical and thermal properties of the modified rotational molding grade cross-linked polyethylene compound with respect to process ability. Rotational molding grade High Density Polyethylene (HDPE) was blended at various compositions with HDPE and Low Density Polyethylene (LDPE) using twin screw extruder. The melt index of the blends was studied according to ASTM D 1238. The blended compositions were chemically cross-linked with various amount of silane cross-linking agent using two roll-mill. Water curing was then undertaken at 100°C in water bath for 4 and 8 hours. Gel content was measured according to ASTM D 2765 to determine the degree of cross-linking. For thermal analysis, only samples crosslinked with 2.0 phr silane cross-linking agent were investigated on the Differential Scanning Calorimetry (DSC) according to ASTM D 3417. The thermal stability test of the silane Crosslinkable Polyethylene (XLPE) was performed by Thermogravimetric Analyzer (TGA) according to ASTM D 3850. Results on melt index (MI) indicated that the rotational molding grade HDPE blended with HDPE showed higher MI compared to that with LDPE thus improved process ability. The density of rotational molding grade HDPE with HDPE was slightly increased whereas that blended with LDPE was slightly decreased. Samples blended with HDPE, melting temperature, Tm, barely changed and degree of crystallinity, Xc, decreased with compositions. Samples with LDPE Tm and Xc decreased with compositions thus improved process ability. As the silane concentrations increased, the gel content after curing was also increased but independent of compositions. Longer curing time resulted in higher gel content. Thermal stability of the crosslinked HDPE was higher than the uncross-linked HDPE, thus silane cross-linking help to stabilize the blends

Polyamide Nanocomposites for Selective Laser Sintering

Current polyamide 11 and 12 are lacking in fire retardancy and high strength/high heat resistance characteristics for a plethora of finished parts that are desired and required for performance driven applications. It is anticipated that nanomodification of polyamide 11 and 12 will result in enhanced polymer performance, i.e., fire retardancy, high strength and high heat resistance for polyamide 11 and 12. It is expected that these findings will expand the market opportunities for polyamide 11 and 12 resin manufacturers. The objective of this research is to develop improved polyamide 11 and 12 polymers with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering (SLS) rapid manufacturing (RM). A nanophase was introduced into the polyamide 11 and 12 via twin screw extrusion to provide improved material properties of the polymer blends. Arkema RILSAN® polyamide 11 molding polymer pellets and Degussa VESTAMID® L1670 polyamide 12 were examined with three types of nanoparticles: chemically modified montmorillonite (MMT) organoclays, surface modified nanosilica, and carbon nanofibers (CNFs) to create polyamide 11 and 12 nanocomposites. Wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM) were used to determine the degree of dispersion. Injection molded test specimens were fabricated for physical, thermal, mechanical properties, and flammability tests. Thermal stability of these polyamide 11 and 12 nanocomposites was examined by TGA. Mechanical properties such as tensile, flexural, and elongation at break were measured. Flammability properties were also obtained using the Cone Calorimeter at an external heat flux of 50 kW/m2. TEM micrographs, physical, mechanical, and flammability properties are included in the paper. Polyamide 11 and 12 nanocomposites properties are compared with polyamide 11 and 12 baseline polymers. Based on flammability and mechanical material performance, selective polymers including polyamide 11 nanocomposites and control polyamide 11 were cryogenically ground into fine powders and fabricated into SLS parts.Mechanical Engineerin

Flame Retardant Intumescent Polyamide 11 Nanocomposites – Further Study

The objective of this research is to develop improved polyamide 11 and 12 polymers with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering (SLS) rapid manufacturing (RM). In the present study, a nanophase was introduced into the polyamide 11 and combine with a conventional intumescent flame retardant (FR) additive via twin screw extrusion. Arkema Rilsan® polyamide 11 molding polymer pellets were used with two types of nanoparticles such as: chemically modified montmorillonite (MMT) organoclays and carbon nanofibers (CNFs). Two types of Clariant’s Exolit® OP 1311 and 1312 intumescent FR additives were used to generate a family of FR intumescent polyamide 11 nanocomposites with anticipated synergism.Mechanical Engineerin

Innovative Selective Laser Sintering Rapid Manufacturing using Nanotechnology

The objective of this research is to develop an improved nylon 11 (polyamide 11) polymer with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering (SLS) rapid manufacturing (RM). A nanophase was introduced into nylon 11 via twin screw extrusion to provide improved material properties of the polymer blends. Atofina (now known as Arkema) RILSAN® nylon 11 injection molding polymer pellets was used with three types of nanoparticles: chemically modified montmorillonite (MMT) organoclays, nanosilica, and carbon nanofibers (CNF) to create nylon 11 nanocomposites. Wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM) were used to determine the degree of dispersion. Fifteen nylon 11 nanocomposites and control nylon 11 were fabricated by injection molding. Flammability properties (using a cone calorimeter with a radiant flux of 50 kW/m2 ) and mechanical properties such as tensile strength and modulus, flexural modulus, elongation at break were determined for the nylon 11 nanocomposites and compared with the baseline nylon 11. Based on flammability and mechanical material performance, five polymers including four nylon 11 nanocomposites and a control nylon 11 were cryogenically ground into fine powders for SLS RM. SLS specimens were fabricated for flammability, mechanical, and thermal properties characterization. Nylon 11-CNF nanocomposites exhibited the best overall properties for this study.Mechanical Engineerin

Polyamide from lactams by reactive rotational molding via anionic ring-opening polymerization: Optimization of processing parameters

A reactive rotational molding (RRM) process was developed to obtain a PA6 by activated anionic ring-opening polymerization of epsilon-caprolactam (APA6). Sodium caprolactamate (C10) and caprolactam magnesium bromide (C1) were employed as catalysts, and difunctional hexamethylene-1,6-dicarbamoylcaprolactam (C20) was used as an activator. The kinetics of the anionic polymerization of !-caprolactam into polyamide 6 was monitored through dynamic rheology and differential scanning calorimetry measurements. The effect of the processing parameters, such as the polymerization temperature, different catalyst/activator combinations and concentrations, on the kinetics of polymerization is discussed. A temperature of 150°C was demonstrated to be the most appropriate. It was also found that crystallization may occur during PA6 polymerization and that the combination C1/C20 was well suited as it permitted a suitable induction time. Isoviscosity curves were drawn in order to determine the available processing window for RRM. The properties of the obtained APA6 were compared with those of a conventionally rotomolded PA6. Results pointed at lower cycle times and increased tensile properties at weak deformation

Pengaruh Variasi Waktu Terhadap Cacat dan Ketebalan Produk Plastik pada Proses Rotational Molding

Salah satu proses dalam pembentukan plastik (molding) adalah dengan menggunakan proses rotational molding. Proses ini umumnya digunakan untuk menciptakan produk besar dan berongga. Tingkat efektifitas waktu proses sangat mempengaruhi prosentase cacat dan ketebalan produk hasil pencetakan. Dengan mengoptimalkan waktu proses diharapkan dapat meminimalisir cacat dan menghasilkan ketebalan produk yang baik. Dalam eksperimen proses rotational molding ini melakukan percobaan pembuatan produk berbentuk bola dan terdapat rongga didalamnya dengan bahan baku Polypropylene (pp). Dimensi bola yang direncanakan dengan diameter luar 60 mm, diameter rongga 56 mm dan ketebalan 2 mm. Proses rotational molding menggunakan perbandingan putaran 2:1 dengan kecepatan putaran sumbu utama 20 rpm, sumbu kecil 30 rpm, dan temperature leleh pp 160 ºC. Menggunakan variasi waktu proses yaitu 45 menit, 60 menit, dan 90 menit. Mold yang digunakan terbuat dari bahan baja ST 37, dan pembuatan mold menggunakan proses CNC. Dari hasil analisis waktu proses terhadap prosentase cacat dan ketebalan produk. Bahwa menggunakan variasi waktu proses 60 menit lebih baik dari variasi waktu proses 45 menit dan 90 menit, karena tingkat pemanasan plastik sangatlah berpengaruh terhadap cacat dan ketebalan produk. Jika plastik terlalu cepat dipanaskan akan mengakibatkan butiran plastik tidak mencair dengan sempurna dan tidak melekat pada dinding cetakan, sebaliknya jika plastik terlalu lama dipanaskan akan menyebabkan menurun dan berkurangnya kekuatan impak dari produk tersebut

Intumescent Flame Retardant Polyamide 11 Nanocomposites

Current polyamide 11 and 12 are lacking in fire retardancy and high strength/high heat resistance characteristics for a plethora of fabricated parts that are desired and required for performance driven applications. The introduction of selected nanoparticles such as surface modified montmorillonite (MMT) clay or carbon nanofibers (CNFs), combined with a conventional intumescent flame retardant (FR) additive into the polyamide 11/polyamide 12 (PA11/PA12) by melt processing conditions has resulted in the preparation of a family of intumescent polyamide nanocomposites. These intumescent polyamide 11 and 12 nanocomposites exhibit enhanced polymer performance characteristics, i.e., fire retardancy, high strength and high heat resistance and are expected to expand the market opportunities for polyamide 11 and polyamide 12 polymer manufacturers. The objective of this research is to develop improved polyamide 11 and 12 polymers with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering (SLS) rapid manufacturing (RM). In the present study, a nanophase was introduced into the polyamide 11 and combining it with a conventional intumescent FR additive via twin screw extrusion. Arkema RILSAN® polyamide 11 molding polymer pellets were examined with two types of nanoparticles: chemically modified montmorillonite (MMT) organoclays, and carbon nanofibers (CNFs); and Clairant’s Exolit® OP 1230 intumescent FR additive were used to create a family of FR intumescent polyamide 11 nanocomposites. Transmission electron microscopy (TEM) was used to determine the degree of nanoparticles dispersion. Injection molded specimens were fabricated for physical, thermal, and flammability measurements. Thermal stability of these intumescent polyamide 11 nanocomposites was examined by TGA. Flammability properties were obtained using the Cone Calorimeter at an external heat flux of 35 kW/m 2 and UL 94 Test Method. Heat deflection temperatures (HDT) were also measured. TEM micrographs, physical, thermal, and flammability properties are presented. FR intumescent polyamide 11 nanocomposites properties are compared with polyamide 11 baseline polymer. Based on flammability and mechanical material performance, selective polymers including polyamide 11 nanocomposites and control polyamide 11 will be cryogenically ground into fine powders for SLS RM processing. SLS specimens will be fabricated for thermal, flammability, and mechanical properties characterization.Mechanical Engineerin

SLS Materials Development Method for Rapid Manufacturing

As soon as SFF technology development began to make Rapid Prototyping possible the interest in Rapid Manufacturing (RM) began to grow. The advantages in terms of functional integration, elimination of tooling and fixtures and mass customization make a compelling case for RM, leading some in the field to call it the next industrial revolution. Yet without the materials properties necessary to provide the function and variety currently available from mass production methods, the application of RM will remain limited. Developing new materials for the SLS process, one immediate step toward a larger portfolio of RM materials, is very challenging. The formation of high quality SLS parts relies on appropriate powder characteristics, thermal cycles and sintering behavior. Based on a brief examination of the key factors in SLS processing and a research project to develop a new binder material for Silicon Carbide composites, a systematic materials development method is proposed in this paper. The method provides guidance for introducing new SLS materials, support for educating new SLS users and researchers and direction for several future research projects.Mechanical Engineerin

Otobüslerde Kullanılan Plastik Yakıt Tanklarının Statik Ve Dinamik Analizler Yardımıyla Dayanımının İncelenmesi

Konferans Bildirisi -- Teorik ve Uygulamalı Mekanik Türk Milli Komitesi, 2015Conference Paper -- Theoretical and Applied Mechanical Turkish National Committee, 2015Günümüzde, otobüslerde kullanılmakta olan konvansiyonel metal yakıt tankları yerini plastik yakıt tanklarına bırakmaktadır. Bu makalede, plastik yakıt tanklarının, statik ve dinamik analizlere dayalı, bilgisayar destekli, geliştime-tasarım projesinn bir kısmı sunulmuştur. Öncelikle, plastik malzemenin mekanik özelliklerini bulmaya yönelik kupon testleri gerçekleştirilmiştir. Statik analizlerde yakıt tankına eşdeğer yükler uygulanmıştır. Dinamik analizler ise zamanla değişen yük, yakıt ve tankın atalaet momentleri göz önüne alınmış ve modal transient analiz yöntemi kullanılmıştır. Statik analizlerde, eşdeğer statik yükleme yaklaşımı kullanılmaktadır. Yapılan dinamk analizlerde, akışkan akustik elemanlar kullanılarak modellenmiştir. Yakıt tankı farklı doluluk oranları için incelenerek karşılaştırılmış ve sonuçları bu bildiride paylaşılmıştır.Nowadays, the conventional metal fuel tanks used in buses are being replaced with plastic fuel tanks. In this paper, a part of the project which aims to develop a computer aided methodology for developing/designing of the plastic fuel tanks based on static and dynamic analysis is presented. Coupon tests are first conducted to acquire the mechanical properties of the plastic material. In the static analysis, equivalent static loads are applied to the fuel tanks. In the dynamic analysis, the time varying loading and the inertia of the fluid and fuel tanks are taken into account using modal transient analysis. Fluid which is in the tank is modeled with acoustic approach in dynamic analysis. In this paper, different fullness ratios of the fuel tank are investigated and both results are compared each other