Energy-harvesting materials

It is shown how key features of natural photosynthesis can be emulated in novel materials based on photoactive multichromophore arrays and crystals. A major consideration in the design of such systems is the means of channeling electronic excitation from sites of light absorption to centers where it is stored or released. Storage is often achieved by driving charge separation or, for the longer term, a more complex chemical reaction whilst rapid release is commonly associated with frequency up-converted emission. In each case channeling to the conversion site generally entails a multi-step energy transfer mechanism whose efficiency is determined by the arrangement and electronic properties of the array chromophores or ions, guided in the more complex systems by a spectroscopic gradient that promotes overall directionality. The functional cascade molecules known as photoactive dendrimers are exemplars of this approach. The latest developments involve new mechanisms for concerted excitation transfer in multichromophore systems, leading towards the tailoring and exploitation of optical nonlinearities for high intensity energy pooling applications

Energy harvesting: a review of the interplay between structure and mechanism

The science of energy harvesting has recently undergone radical change, with the advent of new materials exploiting mechanisms fundamentally different from those of traditional solar cells. Utilizing principles that are in many cases acquired from breakthroughs in molecular photobiology, the introduction of a range of new synthetic polymers, multichromophore arrays and nanoparticle-based materials heralds a marked resurgence of interest, a shift of focus and heightened expectations in the science of light-harvesting. The interplay between structure and mechanism significantly impinges upon issues extending from fundamental theory to the principles of energy-harvesting materials design. Understanding and exploiting the principles allows materials to be engineered that can harness absorbed energy with heightened efficiency. Two of the key areas of application are dendrimers and rare-earth doped solids

MIMO-OFDM Based Energy Harvesting Cooperative Communications Using Coalitional Game Algorithm

This document is the Accepted Manuscript version. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.In this paper, we consider the problem of cooperative communication between relays and base station in an advanced MIMO-OFDM framework, under the assumption that the relays are supplied by electric power drawn from energy harvesting (EH) sources. In particular, we focus on the relay selection, with the goal to guarantee the required performance in terms of capacity. In order to maximize the data throughput under the EH constraint, we model the transmission scheme as a non-transferable coalition formation game, with characteristic function based on an approximated capacity expression. Then, we introduce a powerful mathematical tool inherent to coalitional game theory, namely: the Shapley value (Sv) to provide a reliable solution concept to the game. The selected relays will form a virtual dynamically-configuredMIMO network that is able to transmit data to destination using efficient space-time coding techniques. Numerical results, obtained by simulating the EH-powered cooperativeMIMO-OFDMtransmission with Algebraic Space-Time Coding (ASTC), prove that the proposed coalitional game-based relay selection allows to achieve performance very close to that obtained by the same system operated by guaranteed power supply. The proposed methodology is finally compared with some recent related state-of-the-art techniques showing clear advantages in terms of link performance and goodput.Peer reviewe

Optically nonlinear energy transfer in light-harvesting dendrimers

Dendrimeric polymers are the subject of intense research activity geared towards their implementation in nanodevice applications such as energy harvesting systems,organic light-emitting diodes, photosensitizers, low-threshold lasers, and quantum logic elements, etc. A recent development in this area has been the construction of dendrimers specifically designed to exhibit novel forms of optical nonlinearity, exploiting the unique properties of these materials at high levels of photon flux. Starting from a thorough treatment of the underlying theory based on the principles of molecular quantum electrodynamics, it is possible to identify and characterize several optically nonlinear mechanisms for directed energy transfer and energy pooling in multichromophore dendrimers. Such mechanisms fall into two classes: first, those where two-photon absorption by individual donors is followed by transfer of the net energy to an acceptor; second, those where the excitation of two electronically distinct but neighboring donor groups is followed by a collective migration of their energy to a suitable acceptor. Each transfer process is subject to minor dissipative losses. In this paper we describe in detail the balance of factors and the constraints that determines the favored mechanism, which include the excitation statistics, structure of the energy levels, laser coherence factors, chromophore selection rules and architecture, possibilities for the formation of delocalized excitons, spectral overlap, and the overall distribution of donors and acceptors. Furthermore, it transpires that quantum interference between different mechanisms can play an important role. Thus, as the relative importance of each mechanism determines the relevant nanophotonic characteristics, the results reported here afford the means for optimizing highly efficient light-harvesting dendrimer devices

RF-Powered Cognitive Radio Networks: Technical Challenges and Limitations

The increasing demand for spectral and energy efficient communication networks has spurred a great interest in energy harvesting (EH) cognitive radio networks (CRNs). Such a revolutionary technology represents a paradigm shift in the development of wireless networks, as it can simultaneously enable the efficient use of the available spectrum and the exploitation of radio frequency (RF) energy in order to reduce the reliance on traditional energy sources. This is mainly triggered by the recent advancements in microelectronics that puts forward RF energy harvesting as a plausible technique in the near future. On the other hand, it is suggested that the operation of a network relying on harvested energy needs to be redesigned to allow the network to reliably function in the long term. To this end, the aim of this survey paper is to provide a comprehensive overview of the recent development and the challenges regarding the operation of CRNs powered by RF energy. In addition, the potential open issues that might be considered for the future research are also discussed in this paper.Comment: 8 pages, 2 figures, 1 table, Accepted in IEEE Communications Magazin

Resource Allocation in Wireless Networks with RF Energy Harvesting and Transfer

Radio frequency (RF) energy harvesting and transfer techniques have recently become alternative methods to power the next generation of wireless networks. As this emerging technology enables proactive replenishment of wireless devices, it is advantageous in supporting applications with quality-of-service (QoS) requirement. This article focuses on the resource allocation issues in wireless networks with RF energy harvesting capability, referred to as RF energy harvesting networks (RF-EHNs). First, we present an overview of the RF-EHNs, followed by a review of a variety of issues regarding resource allocation. Then, we present a case study of designing in the receiver operation policy, which is of paramount importance in the RF-EHNs. We focus on QoS support and service differentiation, which have not been addressed by previous literatures. Furthermore, we outline some open research directions.Comment: To appear in IEEE Networ

Wireless Powered Cooperative Relaying using NOMA with Imperfect CSI

The impact of imperfect channel state (CSI) information in an energy harvesting (EH) cooperative non-orthogonal multiple access (NOMA) network, consisting of a source, two users, and an EH relay is investigated in this paper. The relay is not equipped with a fixed power source and acts as a wireless powered node to help signal transmission to the users. Closed-form expressions for the outage probability of both users are derived under imperfect CSI for two different power allocation strategies namely fixed and dynamic power allocation. Monte Carlo simulations are used to numerically evaluate the effect of imperfect CSI. These results confirm the theoretical outage analysis and show that NOMA can outperform orthogonal multiple access even with imperfect CSI.Comment: 6 pages, 6 figures, accepted in IEEE GLOBECOM 2018 NOMA Worksho