Ceramics in gas turbine: Powder and process characterization

Some of the intrinsic properties of various forms of Si3N4 and SiC are listed and limitations of such materials' availability are pointed out. The essential features/parameters to characterize a batch of powder are discussed including the standard techniques for such characterization. In process characterization, parameters in sintering, reaction sintering, and hot pressing processes are discussed including the factors responsible for strength limitations in ceramic bodies. Significant improvements in material properties can be achieved by reducing or eliminating the strength limiting factors with consistent powder and process characterization along with process control

X-ray and electron spin resonance on YBa2Cu3O7 prepared by citrate synthesis

YBa2Cu3O7 samples were prepared by a citrate synthesis technique. Powder X-ray diffraction and resistance measurements were performed for sample characterization. This single-phase material has a Tc(R=0) of 91.2 K. Electron spin resonance experiments indicate the presence of 10 to 15% of Cu3+

Development of powder diffraction apparatus for small-angle X-ray scattering measurements

A novel type of X-ray collimation system attached to commercial powder diffractometers makes the structural characterization of nanomaterials possible in a wide size range from <0.1 to 100 nm by combination of the small- and wide-angle X-ray scattering techniques. There is no dead interval in the detection between the small- and wide-angle regimes. This device can be attached to any existing 'θ/θ' powder diffractometer, providing a multi-functional small- and wide-angle X-ray scattering/diffraction (SWAXS) apparatus. After proper alignment and adjustment, the device can be removed and re-attached at any time to switch between normal and SWAXS functions. Copyright © International Union of Crystallography 2013

Effects of Nanosilica Powder from Rice Hull Ash on Seed Germination of Tomato (Lycopersicon esculentum)

open5noNanosilica powders were synthesized from rice hull ash (RHA) and their effects on seed germination of tomato plants were investigated. Synthesized nanosilica powder was subjected to various characterization studies for identification of the size, structure, morphology and elemental composition. Atomic force microscopy (AFM) and transmission electron microscopy (TEM) results showed that the nanoparticles were in agglomerated form with an average diameter of 46.5 nm and 40 nm, respectively. X-ray diffractometry (XRD) indicated that nanosilica powder is amorphous in nature. The nanosilica powder was also characterized as having a purity of 98.33% using EDXRF spectroscopy and having a surface area 172.19 m2 g-1 using the Brunauer-Emmett-Teller (BET) method. The study showed that nanosilica powder significantly improved germination parameters such as germination percentage, germination index, vigor index, mean germination time and average shoot length of tomato but not fresh weight and dry weight. The best results were found at 5gL-1 nanosilica powder. The increase over untreated control seeds was 22% for germination percentage, 47% for germination index, 92% for vigor index and 55% for average shoot length with the addition of 5 gL-1 nanosilica powder. Nanosilica powder-mediated improvement of seed germination in tomato suggests a potential application of nanosilica powder in seed germination of the plant. The study can serve as theoretical basis for further agricultural applications of nanosilica powder.openMaria Morissa Lu, Diana Marie De Silva, Engelbert Peralta, Alvin . Fajardo, Milagros PeraltaMaria Morissa, Lu; DE SILVA, DIANA MARIE; Engelbert, Peralta; Fajardo, Alvin.; Milagros, Peralt

Characterization and flow of food and mineral powders : a thesis presented in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Engineering at Massey University, Manawatū, New Zealand

Powders are important commodities across different industries, such as the food and pharmaceutical industries. In these industries, powders are usually made, mixed, milled, packaged, and stored; these operations require the powders to move and flow under desired conditions and different stress levels. Failure to flow will cause hindrances to production; therefore knowledge of powder flow or flowability is important. There is a constant demand for accurate, reliable, and robust measurement and characterization methods for powder flowability. Powders behave differently under varying conditions; the behaviour of a powder is influenced by particle size distribution, and powder handling and processing conditions. There is to date no one “standard” method to characterize powder flowability; it is common to use a variety of methods and devices to measure flow properties and provide insight into the behaviour and flow characteristics of powders under different conditions. The flow properties of model food and mineral powders were measured and assessed by shear testing, compression via tapping, fluidization, and powder tumbling. Shear testing was done with an annular shear cell following Jenike (1964) and Berry, Bradley and McGregor (2014). Compression via tapping was performed according to a procedure in the dairy industry (Niro, 1978) and the European Pharmacopoeia (Schüssele & Bauer-Brandl, 2003). Fluidization was used to measure powder bed expansion and bed collapse following the powder classification framework provided by Geldart and co-workers (Geldart, 1973; Geldart, Harnby, & Wong, 1984; Geldart & Wong, 1984, 1985). Powder tumbling was performed in a novel Gravitational Displacement Rheometer, GDR, which measured the motion and avalanche activity of powders that moved under their own weight when rotated in a cylinder at different drum speed levels. The flow data from each characterization method were evaluated individually with regards to particle size distribution and then assessed collectively. The findings presented and discussed include the i) demonstration of the dominant influence of surface-volume mean particle diameter on powder flow properties, ii) characterization of flowability based on Jenike’s arbitrary flow divisions, iii) development of new correlations for the estimation of powder cohesion and bulk density at low preconsolidation stresses, iv) demonstration of hopper outlet diameter as a measure of flowability, v) demonstration of the limited utility of Hausner ratio as a flowability index, vi) substantiation of von Neumann ratio as a sensitive and useful indicator for identifying the onset of bubbling in fluidized beds using bed pressure fluctuation data, and vii) demonstration of the utility of standard deviation of the GDR load cell signal as an indicator of powder avalanche activity. These findings provide improved understanding and knowledge of powder flowability; they can be used to assist and facilitate the development of new techniques and solutions relevant to the handling and processing of powders especially in the food and pharmaceutical industries

Influence of calcination conditions on structural and solid‐state kinetic properties of iron oxidic species supported on SBA‐15

Iron oxidic species supported on silica SBA-15 were synthesized with various iron loadings using two different FeIII precursors. The effect of varying powder layer thickness during calcination on structural and solid-state kinetic properties of FexOy/SBA-15 samples was investigated. Calcination was conducted in thin (0.3 cm) or thick (1.3 cm) powder layer. Structural characterization of resulting FexOy/SBA-15 samples was performed by nitrogen physisorption, X-ray diffraction, and DR-UV/Vis spectroscopy. Thick powder layer during calcination induced an increased species size independent of the precursor. However, a significantly more pronounced influence of calcination mode on species size was observed for the FeIII nitrate precursor compared to the FeIII citrate precursor. Temperature-programmed reduction (TPR) experiments revealed distinct differences in reducibility and reduction mechanism dependent on calcination mode. Thick layer calcination of the samples obtained from FeIII nitrate precursor resulted in more pronounced changes in TPR profiles compared to samples obtained from FeIII citrate precursor. TPR traces were analyzed by model-dependent Coats-Redfern method and model-independent Kissinger method. Differences in solid-state kinetic properties of FexOy/SBA-15 samples dependent on powder layer thickness during calcination correlated with differences in iron oxidic species size.TU Berlin, Open-Access-Mittel - 201

Multivariate data analysis to assess dry powder inhalers performance from powder properties

The study aimed at investigating the correlations among the physical and bulk properties of carrier based dry powder inhaler formulations and the performance of the powder inhaler device estimated by in-vitro tests for a specific active pharmaceutical ingredient (API), and at obtaining predictive models for the in-vitro performance. Samples from scale-up process batches having different formulations, process settings and bulk size, were characterized by rheological, density and particle size tests. In vitro performance was evaluated by several parameters obtained by a dosage unit sampling apparatus (DUSA) and a next generation impactor (NGI). Correlations between powder properties and performance propertieswere established using partial least square (PLS) regression analysis. Variable importance in projection (VIP)was used in order to assess the most influential powder characterization variables to estimate the analytical ones. Particle size, density and rate of flowability are significant for modeling the Delivered Dose of the API and the total quantity of powder related to each dose. Powder characterization variables, describing the degree of cohesiveness and the flow properties of powder, are related to the total amount of the active ingredient for different formulations. DUSA test variables were satisfactory predicted on the basis of powder characterization variables, while NGI performance variables were predicted with higher error

One pot solvothermal synthesis of organic acid coated magnetic iron oxide nanoparticles

Indexación: ScieloABSTRACT In this work we present the synthesis and characterization of iron oxide nanoparticles (IONPs), which were structurally and magnetically characterized. The use of iron salts and an organic acid (l-serine or ascorbic acid) as precursors under solvothermal conditions yielded these coated IONPs. The powder X-ray diffraction pattern of FeO-1 and FeO-2 is consistent with hematite (α-Fe2O3) and hematite-maghemite ((α-Fe2O3/γ-Fe2O3) respectively. The TEM analysis permits to estimate an average size of 10 nm for the FeO-1 sample. The magnetic characterization of the samples through the M(H) plots showed a very low coercivity value for both samples, being 53 Oe for FeO-1 and 10 Oe for FeO-2, indicating the very weak ferromagnetic character of the synthesized iron oxide species. Even though both organic acids under solvothermal conditions permit to obtain coated IONPs in one pot reaction, l-serine produces a more narrow-size distribution

Solidification Morphology Analysis of SLM of Cu Powder

The solidification morphology analysis of fine Cu powder melted by a raster scanned energy beam from a focused Nd:YAG laser is presented here. The powder was processed inside of sealed chamber where it was subjected to a high vacuum cycle. The laser fusion process consisted raster scanning a narrow rectangular pattern with a high density of scanning lines, the chamber was purged with inert gas during the process. Up to a 3.3 mm/s laser travel speed and maximum laser power level of 240 W were used to melt a 2 mm thick bed of loose powder. The resulting solidified ingots were separated into categories based on their shape integrity. Metallographic analysis by means of optical microscopy and scanning electron microscopy was performed on the cross section and longitudinal section of the ingots with homogeneous surface and complete shape integrity. Characterization revealed an elongated columnar grain structure with a grain orientation along the direction of the laser travel direction, some degree of porosity was observed too in some of the specimens. It was observed that grains diameter ranged from 10 to 100 µm and contained a two phase eutectic microstructure of copper and it oxides. Oxygen content was accounted from a 5.5 up to 8.1 atomic percent, a small percentage of chlorine was present, too. A 2 to 8 percent variation in the Vickers microhardness values were found between the different specimens when measured along the longitudinal section. These HV values corresponded to approximate 20-25% cold rolled oxygen free copper (80-90 HV). The ingots thus produced suggest that a multilayer structure from Cu powder could be build by the SLM process having sufficiently adequate compositional, microstructure and mechanical properties for functional applications.Mechanical Engineerin