Nonstatistical dynamics on potentials exhibiting reaction path bifurcations and valley-ridge inflection points

We study reaction dynamics on a model potential energy surface exhibiting post-transition state bifurcation in the vicinity of a valley ridge inflection point. We compute fractional yields of products reached after the VRI region is traversed, both with and without dissipation. It is found that apparently minor variations in the potential lead to significant changes in the reaction dynamics. Moreover, when dissipative effects are incorporated, the product ratio depends in a complicated and highly non-monotonic fashion on the dissipation parameter. Dynamics in the vicinity of the VRI point itself play essentially no role in determining the product ratio, except in the highly dissipative regime.Comment: 33 pages, 10 figures, corrected the author name in reference [6

Spectra of "Real-World" Graphs: Beyond the Semi-Circle Law

Many natural and social systems develop complex networks, that are usually modelled as random graphs. The eigenvalue spectrum of these graphs provides information about their structural properties. While the semi-circle law is known to describe the spectral density of uncorrelated random graphs, much less is known about the eigenvalues of real-world graphs, describing such complex systems as the Internet, metabolic pathways, networks of power stations, scientific collaborations or movie actors, which are inherently correlated and usually very sparse. An important limitation in addressing the spectra of these systems is that the numerical determination of the spectra for systems with more than a few thousand nodes is prohibitively time and memory consuming. Making use of recent advances in algorithms for spectral characterization, here we develop new methods to determine the eigenvalues of networks comparable in size to real systems, obtaining several surprising results on the spectra of adjacency matrices corresponding to models of real-world graphs. We find that when the number of links grows as the number of nodes, the spectral density of uncorrelated random graphs does not converge to the semi-circle law. Furthermore, the spectral densities of real-world graphs have specific features depending on the details of the corresponding models. In particular, scale-free graphs develop a triangle-like spectral density with a power law tail, while small-world graphs have a complex spectral density function consisting of several sharp peaks. These and further results indicate that the spectra of correlated graphs represent a practical tool for graph classification and can provide useful insight into the relevant structural properties of real networks.Comment: 14 pages, 9 figures (corrected typos, added references) accepted for Phys. Rev.

State-space Geometry, Statistical Fluctuations and Black Holes in String Theory

We study the state-space geometry of various extremal and nonextremal black holes in string theory. From the notion of the intrinsic geometry, we offer a new perspective of black hole vacuum fluctuations. For a given black hole entropy, we explicate the intrinsic state-space geometric meaning of the statistical fluctuations, local and global stability conditions and long range statistical correlations. We provide a set of physical motivations pertaining to the extremal and nonextremal black holes, \textit{viz.}, the meaning of the chemical geometry and physics of correlation. We illustrate the state-space configurations for general charge extremal black holes. In sequel, we extend our analysis for various possible charge and anticharge nonextremal black holes. From the perspective of statistical fluctuation theory, we offer general remarks, future directions and open issues towards the intrinsic geometric understanding of the vacuum fluctuations and black holes in string theory. Keywords: Intrinsic Geometry; String Theory; Physics of black holes; Classical black holes; Quantum aspects of black holes, evaporation, thermodynamics; Higher-dimensional black holes, black strings, and related objects; Statistical Fluctuation; Flow Instability. PACS: 02.40.Ky; 11.25.-w; 04.70.-s; 04.70.Bw; 04.70.Dy; 04.50.Gh; 5.40.-a; 47.29.KyComment: 28 pages. arXiv admin note: substantial text overlap with arXiv:1102.239

Semiclassical Casimir Energies at Finite Temperature

We study the dependence on the temperature T of Casimir effects for a range of systems, and in particular for a pair of ideal parallel conducting plates, separated by a vacuum. We study the Helmholtz free energy, combining Matsubara's formalism, in which the temperature appears as a periodic Euclidean fourth dimension of circumference 1/T, with the semiclassical periodic orbital approximation of Gutzwiller. By inspecting the known results for the Casimir energy at T=0 for a rectangular parallelepiped, one is led to guess at the expression for the free energy of two ideal parallel conductors without performing any calculation. The result is a new form for the free energy in terms of the lengths of periodic classical paths on a two-dimensional cylinder section. This expression for the free energy is equivalent to others that have been obtained in the literature. Slightly extending the domain of applicability of Gutzwiller's semiclassical periodic orbit approach, we evaluate the free energy at T>0 in terms of periodic classical paths in a four-dimensional cavity that is the tensor product of the original cavity and a circle. The validity of this approach is at present restricted to particular systems. We also discuss the origin of the classical form of the free energy at high temperatures.Comment: 17 pages, no figures, Late

Iron fluorescence from within the innermost stable orbit of black hole accretion disks

The fluorescent iron Ka line is a powerful observational probe of the inner regions of black holes accretion disks. Previous studies have assumed that only material outside the radius of marginal stability can contribute to the observed line emission. Here, we show that fluorescence by material inside the radius of marginal stability, which is in the process of spiralling towards the event horizon, can have a observable influence on the iron line profile and equivalent width. For concreteness, we consider the case of a geometrically thin accretion disk, around a Schwarzschild black hole, in which fluorescence is excited by an X-ray source placed at some height above the disk and on the axis of the disk. Fully relativistic line profiles are presented for various source heights and efficiencies. It is found that the extra line flux generally emerges in the extreme red wing of the iron line, due to the large gravitational redshift experienced by photons from the region within the radius of marginal stability. We apply our models to the variable iron line seen in the ASCA spectrum of the Seyfert nucleus MCG-6-30-15. It is found that the change in the line profile, equivalent width, and continuum normalization, can be well explained as being due to a change in the height of the source above the disk. We discuss the implications of these results for distinguishing rapidly-rotating black holes from slowly rotating holes using iron line diagnostics.Comment: 20 pages, LaTeX. Accepted for publication in Astrophysical Journal. Figures 3 to 7 replaced with corrected versions (previous figures affected by calculational error). Some changes in the best fitting parameter

From Sasaki-Einstein spaces to quivers via BPS geodesics: Lpqr

The AdS/CFT correspondence between Sasaki-Einstein spaces and quiver gauge theories is studied from the perspective of massless BPS geodesics. The recently constructed toric Lpqr geometries are considered: we determine the dual superconformal quivers and the spectrum of BPS mesons. The conformal anomaly is compared with the volumes of the manifolds. The U(1)^2_F x U(1)_R global symmetry quantum numbers of the mesonic operators are successfully matched with the conserved momenta of the geodesics, providing a test of AdS/CFT duality. The correspondence between BPS mesons and geodesics allows to find new precise relations between the two sides of the duality. In particular the parameters that characterize the geometry are mapped directly to the parameters used for a-maximization in the field theory. The analysis simplifies for the special case of the Lpqq models, which are shown to correspond to the known "generalized conifolds". These geometries can break conformal invariance through toric deformations of the complex structure.Comment: 30 pages, 8 figures, LaTeX. v2: One more figure. References added, typos correcte