Effect of hydration on conductivity of Ba4La x Ca2-X Nb2O11 + 0.5x (x = 0.5, 1, 1.5, 2) phases

Substitution of Ca by La in initial cubic double perovskite Ba 4(Ca2Nb2)O11[VO]1 allowed obtaining phases with a similar structure with a lower content of structural oxygen vacancies, Ba4(La x Ca2-x Nb 2)O11 + 0.5x [VO]1-0.5x (x = 0.5, 1, 1.5, 2). The impedance technique was used to measure the temperature dependences of conductivity in the atmosphere of dry and humid air. Transport numbers determined using the EMF method in an oxygen-air and water steam concentration cells point to the predominantly hole nature of conductivity in the high-temperature region (T > 600 C) and to predominance of proton conductivity in the low-temperature region. Activation energies of hole and proton conductivity were calculated. Thermogravimetric measurements were carried out under heating from 25 to 1000 C with simultaneous mass-spectrometric determination of evolved H2O and CO2. The properties of the studied Ba4(La x Ca2-x Nb 2)O11 + 0.5x (x = 0.5, 1, 1.5, 2) phases were compared with the earlier studied Ba4-x La x (Ca2Nb 2)O11 + 0.5x phases with similar lanthanum content. © 2013 Pleiades Publishing, Ltd

Comment on the Matrix Element of O11O_{11}

The gluon dipole operator, $O_{11}$, has received much attention recently because it can have a large coefficient in some SUSY extensions of the standard model. We find that the commonly used matrix element of $O_{11}$ of Bertolini, Eeg and Fabbrichesi is in rough (but accidental) numerical agreement with an estimate based on dimensional analysis.Comment: 6 pages, Late

(Biphenyl-2-yl)bromidobis(2-methyltetrahydrofuran-[kappa]O)magnesium(II)

In the title Grignard reagent, [MgBr(C12H9)(C5H10O)2], the Mg centre adopts a distorted tetrahedral MgCO2Br arrangement. The dihedral angle between the two aromatic rings of the biphenyl residue is 44.00 (14)°. Each molecule incorporates one R- and one S-configured 2-methyltetrahydrofuran molecule. Key indicators: single-crystal X-ray study; T = 173 K; mean σ(C–C) = 0.007 Å; R factor = 0.045; wR factor = 0.108; data-to-parameter ratio = 17.4

Human Capital Externalities and Growth

This paper proposes a methodology to estimate externalities in human capital as a response to the evidence of a worldwide divergent development. We estimate supply and demand for human capital in a five-year panel for 60 countries in the period 1980-2000, and found that there are positive externalities in human capital accumulation close to one, implying increasing returns to scale and increasing marginal returns in human capital which eliminates the channel that enables generating conditional convergence.Economic growth, human capital, externalities. Classification JEL:J24, O11, O40, Y40

Consistency of a gauged two-Higgs-doublet model: Scalar sector

We study the theoretical and phenomenological constraints imposed on the scalar sector of the gauged two Higgs doublet model proposed recently as a variant of the popular inert Higgs doublet model of dark matter. The requirements of tree-level vacuum stability and perturbative unitarity in the scalar sector are analyzed in detail. Furthermore, taking into account the constraints from the 125 GeV Higgs boson measurements at the Large Hadron Collider, we map out the allowed ranges for the fundamental parameters of the scalar potential in the model.Comment: 41 pages, 31 figures. V2: Content added to section III.A, references added, content matches version published in PR

Vibrational state dependence of ionic rotational branching ratios in resonance enhanced multiphoton ionization of CH

We show that rapid evolution of a Rydberg orbital with internuclear distance in a resonance enhanced multiphoton ionization (REMPI) process can have a profound influence on the production of molecular ions in alternative rotational states. This is illustrated by calculations of ionic rotational branching ratios for (2+1′) REMPI via the O11 (20.5) branch of the E′ ^2Σ^+(3pσ) Rydberg state of CH. The rotational propensity rule for ionization changes from ΔN=odd (ΔN=N_+−N_i) at lower vibrational excitation, as expected from the ΔN+l=odd selection rule, to ΔN=even at higher vibrational levels. This effect is expected to be quite general and should be most readily observable in diatomic hydrides

Amiloride hydro­chloride methanol disolvate

In the crystal of the title compound [systematic name: 2-(3,5-diamino-6-chloro­pyrazin-2-ylcarbon­yl)guanidinium chloride methanol disolvate], C6H9ClN7O+·Cl-·2CH3OH , the components are connected by N—H ... N, N—H ... Cl, N—H ... O, O—H ... Cl and O—H ... O hydrogen bonds into a three-dimensional network. The dihedral angle between the aromatic ring and the guanidine residue is 6.0 (2)°

Invariant integration over the orthogonal group

I adapt a recently introduced method for integrating over the unitary group (S. Aubert and C.S. Lam, J.Math.Phys. 44, 6112-6131 (2003)) to the orthogonal group. I derive explicit formulas for a number of one, two and three-vector integrals, as well as recursion formulas for more complicated cases.Comment: 13 page

Dipotassium [N,N '-(propane-1,3-diyl)dioxamato-kappa O-4,N,N ',O ']copper(II) trihydrate: redetermination at 100 K

Redetermination of the structure of the title compound, K-2[Cu(C7H6N2O6)]center dot 3H(2)O,at 100 K reveals conformational disorder in the almost planar copper-containing molecular dianions and clarifies the complex hydrogen-bonded network involving the water molecules. The asymmetric unit contains two independent formula units. In one of the [Cu(C7H6N2O6)](2-) dianions, the propyl chain is disordered over two orientiations, with site-occupancy factors of 0.852 (5) and 0.148 (5)