2 research outputs found
Topological characterization of antireflective and hydrophobic rough surfaces: are random process theory and fractal modeling applicable?
The random process theory (RPT) has been widely applied to predict the joint
probability distribution functions (PDFs) of asperity heights and curvatures of
rough surfaces. A check of the predictions of RPT against the actual statistics
of numerically generated random fractal surfaces and of real rough surfaces has
been only partially undertaken. The present experimental and numerical study
provides a deep critical comparison on this matter, providing some insight into
the capabilities and limitations in applying RPT and fractal modeling to
antireflective and hydrophobic rough surfaces, two important types of textured
surfaces. A multi-resolution experimental campaign by using a confocal
profilometer with different lenses is carried out and a comprehensive software
for the statistical description of rough surfaces is developed. It is found
that the topology of the analyzed textured surfaces cannot be fully described
according to RPT and fractal modeling. The following complexities emerge: (i)
the presence of cut-offs or bi-fractality in the power-law power-spectral
density (PSD) functions; (ii) a more pronounced shift of the PSD by changing
resolution as compared to what expected from fractal modeling; (iii) inaccuracy
of the RPT in describing the joint PDFs of asperity heights and curvatures of
textured surfaces; (iv) lack of resolution-invariance of joint PDFs of textured
surfaces in case of special surface treatments, not accounted by fractal
modeling.Comment: 21 pages, 13 figure
Photo-Attachment of Biomolecules for Miniaturization on Wicking Si-Nanowire Platform
We demonstrated the surface functionalization of a highly three-dimensional, superhydrophilic wicking substrate using light to immobilize functional biomolecules for sensor or microarray applications. We showed here that the three-dimensional substrate was compatible with photo-attachment and the performance of functionalization was greatly improved due to both increased surface capacity and reduced substrate reflectivity. In addition, photo-attachment circumvents the problems induced by wicking effect that was typically encountered on superhydrophilic three-dimensional substrates, thus reducing the difficulty of producing miniaturized sites on such substrate. We have investigated various aspects of photo-attachment process on the nanowire substrate, including the role of different buffers, the effect of wavelength as well as how changing probe structure may affect the functionalization process. We demonstrated that substrate fabrication and functionalization can be achieved with processes compatible with microelectronics processes, hence reducing the cost of array fabrication. Such functionalization method coupled with the high capacity surface makes the substrate an ideal candidate for sensor or microarray for sensitive detection of target analytes.National University of Singapore (Graduate School for Integrative Sciences and Engineering scholarship)GLOBALFOUNDRIES Singapore Pte. Ltd.Singapore-MIT Allianc