10,909 research outputs found
The Structure of 1-\u3cem\u3etert\u3c/em\u3e-butyl-2,2,3,4,4-pentamethylphosphetane 1-oxide, C\u3csub\u3e12\u3c/sub\u3eH\u3csub\u3e25\u3c/sub\u3eOP
Structure of l-Benzyl-2,2,3,3-tetramethyl-l-phenylphosphetanium Bromide, a Cyelobutane Derivative
In search of space: Fourier spectroscopy, 1950-1970
In the large grey area between science and technology, specialisms emerge with associated specialists. But some specialisms remain ‘peripheral sciences’, never attaining the status of disciplines ensconced in universities, and their specialists do not become recognised professionals. A major social component of such side-lined sciences – one important grouping of techno-scientific workers – is the research-technology community. An important question concerning research-technology is to explain how the grouping survives without specialised disciplinary and professional affiliations. The case discussed illustrates the dynamics of one such community
Dual Fabry-Perot filter for measurement of CO rotational spectra: design and application to the CO spectrum of Venus
We present the design of a harmonic resonant filter that can be used with a Fourier transform spectrometer (FTS) for simultaneous measurement of a series of lines in the CO rotational ladder. To enable studies of both broad CO absorptions in Venus and modestly red-shifted CO emission from external galaxies, relatively broad (approximately 10-30-GHz FWHM) transmission passbands are desirable. Because a single low-finesse Fabry Perot (FP) etalon has insufficient interline rejection, a dual-FP etalon was considered. Such a design provides significantly better interband rejection and somewhat more flattopped transmission spikes. A prototype filter of this type, made of two thin silicon disks spaced by an air gap, has been constructed and used with our FTS at the Caltech Submillimeter Observatory for simultaneous measurement of the four submillimeter CO transitions in the atmosphere of Venus that are accessible from the ground
Galactic cosmic ray induced radiation dose on terrestrial exoplanets
This past decade has seen tremendous advancements in the study of extrasolar
planets. Observations are now made with increasing sophistication from both
ground and space-based instruments, and exoplanets are characterized with
increasing precision. There is a class of particularly interesting exoplanets,
falling in the habitable zone, which is defined as the area around a star where
the planet is capable of supporting liquid water on its surface. Theoretical
calculations also suggest that close-in exoplanets are more likely to have
weaker planetary magnetic fields, especially in case of super earths. Such
exoplanets are subjected to a high flux of Galactic Cosmic Rays (GCRs) due to
their weak magnetic moments. GCRs are energetic particles of astrophysical
origin, which strike the planetary atmosphere and produce secondary particles,
including muons, which are highly penetrating. Some of these particles reach
the planetary surface and contribute to the radiation dose. Along with the
magnetic field, another factor governing the radiation dose is the depth of the
planetary atmosphere. The higher the depth of the planetary atmosphere, the
lower the flux of secondary particles will be on the surface. If the secondary
particles are energetic enough, and their flux is sufficiently high, the
radiation from muons can also impact the sub-surface regions, such as in the
case of Mars. If the radiation dose is too high, the chances of sustaining a
long-term biosphere on the planet are very low. We explore the dependence of
the GCR induced radiation dose on the strength of the planetary magnetic field
and its atmospheric depth, finding that the latter is the decisive factor for
the protection of a planetary biosphere.Comment: Accepted for publication in Astrobiolog
Electrospun polyvinyl alcohol/carbon dioxide modified polyethyleneimine composite nanofiber scaffolds
A novel biocompatible polyvinyl alcohol/carbon dioxide modified polyethyleneimine (PVA/PEI-CO2) composite nanofiber was fabricated by a green and facile protocol, which reduces the cytotoxicity of PEI through the surface modification of the PEI with CO2. The 13C NMR spectrum, elemental analysis, and TGA show that CO2 has been incorporated in the PEI surface resulting in a relatively stable structure. The resulting PVA/PEI-CO2 composite nanofibers have been characterized by attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR), contact angle, and scanning electron microscopy (SEM). The results show that the average diameters of the nanofibers range from 265 ± 53 nm to 423 ± 80 nm. The cytotoxicity of PVA/PEI-CO2 composite nanofibers was assessed by cytotoxicity evaluation using the growth and cell proliferation of normal mice Schwann cells. SEM and the MTT assay demonstrated the promotion of cell growth and proliferation on the PVA/PEI-CO2 composite scaffold. It suggests that PEI-CO2 can have tremendous potential applications in biological material research
A spectroscopic analysis of the chemically peculiar star HD207561
In this paper we present a high-resolution spectroscopic analysis of the
chemically peculiar star HD207561. During a survey programme to search for new
roAp stars in the Northern hemisphere, Joshi et al. (2006) observed significant
photometric variability on two consecutive nights in the year 2000. The
amplitude spectra of the light curves obtained on these two nights showed
oscillations with a frequency of 2.79 mHz [P~6-min]. However, subsequent
follow-up observations could not confirm any rapid variability. In order to
determine the spectroscopic nature of HD207561, high-resolution spectroscopic
and spectro-polarimetric observations were carried out. A reasonable fit of the
calculated Hbeta line profile to the observed one yields the effective
temperature (Teff) and surface gravity (log g) as 7300 K and 3.7 dex,
respectively. The derived projected rotational velocity (vsin i) for HD207561
is 74 km/sec indicative of a relatively fast rotator. The position of HD207561
in the H-R diagram implies that this is slightly evolved from the main-sequence
and located well within the delta-Scuti instability strip. The abundance
analysis indicates the star has slight under-abundances of Ca and Sc and mild
over-abundances of iron-peak elements. The spectro-polarimetric study of
HD207561 shows that the effective magnetic field is within the observational
error of 100 gauss (G). The spectroscopic analysis revealed that the star has
most of the characteristics similar to an Am star, rather than an Ap star, and
that it lies in the delta-Scuti instability strip; hence roAp pulsations are
not expected in HD207561, but low-overtone modes might be excited.Comment: 8 pages, 7 figures, 3 tables. Accepted for pubblication in MNRA
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