7,433 research outputs found
Graphite based Schottky diodes formed on Si, GaAs and 4H-SiC substrates
We demonstrate the formation of semimetal graphite/semiconductor Schottky
barriers where the semiconductor is either silicon (Si), gallium arsenide
(GaAs) or 4H-silicon carbide (4H-SiC). Near room temperature, the forward-bias
diode characteristics are well described by thermionic emission, and the
extracted barrier heights, which are confirmed by capacitance voltage
measurements, roughly follow the Schottky-Mott relation. Since the outermost
layer of the graphite electrode is a single graphene sheet, we expect that
graphene/semiconductor barriers will manifest similar behavior.Comment: 5 pages, 3 figures, 1 tabl
Mechanism of Ambipolar Field-Effect Carrier Injections in One-Dimensional Mott Insulators
To clarify the mechanism of recently reported, ambipolar carrier injections
into quasi-one-dimensional Mott insulators on which field-effect transistors
are fabricated, we employ the one-dimensional Hubbard model attached to a
tight-binding model for source and drain electrodes. To take account of the
formation of Schottky barriers, we add scalar and vector potentials, which
satisfy the Poisson equation with boundary values depending on the drain
voltage, the gate bias, and the work-function difference. The current-voltage
characteristics are obtained by solving the time-dependent Schr\"odinger
equation in the unrestricted Hartree-Fock approximation. Its validity is
discussed with the help of the Lanczos method applied to small systems. We find
generally ambipolar carrier injections in Mott insulators even if the work
function of the crystal is quite different from that of the electrodes. They
result from balancing the correlation effect with the barrier effect. For the
gate-bias polarity with higher Schottky barriers, the correlation effect is
weakened accordingly, owing to collective transport in the one-dimensional
correlated electron systems.Comment: 21 pages, 10 figures, to appear in J. Phys. Soc. Jp
Controlling the Schottky barrier at MoS2|metal contacts by inserting a BN monolayer
Making a metal contact to the two-dimensional semiconductor MoS2 without
creating a Schottky barrier is a challenge. Using density functional
calculations we show that, although the Schottky barrier for electrons obeys
the Schottky-Mott rule for high work function ( eV) metals, the
Fermi level is pinned at 0.1-0.3 eV below the conduction band edge of MoS2 for
low work function metals, due to the metal-MoS2 interaction. Inserting a boron
nitride (BN) monolayer between the metal and the MoS2 disrupts this
interaction, and restores the MoS2 electronic structure. Moreover, a BN layer
decreases the metal work function of Co and Ni by eV, and enables a
line-up of the Fermi level with the MoS2 conduction band. Surface modification
by adsorbing a single BN layer is a practical method to attain vanishing
Schottky barrier heights.Comment: 5 pages, 5 figure
Toward a better understanding of the doping mechanism involved in Mo(tfd-COCF doped PBDTTT-c
In this study, we aim to improve our understanding of the doping mechanism
involved in the polymer PBDTTT-c doped with(Mo(tfd-COCF3)3. We follow the
evolution of the hole density with dopant concentration to highlight the limits
of organic semiconductor doping. To enable the use of doping to enhance the
performance of organic electronic devices, doping efficiency must be understood
and improved. We report here a study using complementary optical and electrical
characterization techniques, which sheds some light on the origin of this
limited doping efficiency at high dopant concentration. Two doping mechanisms
are considered, the direct charge transfer (DCT) and the charge transfer
complex (CTC). We discuss the validity of the model involved as well as its
impact on the doping efficiency.Comment: Accepted manuscript, J. Appl. Phy
Space–charge theory applied to the grain boundary impedance of proton conducting BaZr0.9Y0.1O3−δ.
The specific grain interior and grain boundary conductivities, obtained from impedance spectroscopy and the brick layer model, are reported for BaZr0.9Y0.1O3−δ as a function of pO2 and temperature. pO2-dependencies were indicative of dominating ionic and p-type electronic conduction for the grain interior under reducing and oxidizing conditions, respectively, while the grain boundaries showed an additional n-type electronic contribution under reducing conditions. Transmission electron microscopy revealed enrichment of Y in the grain boundary region. These findings indicate the existence of space–charge layers in the grain boundaries. A grain boundary core–space–charge layer model is therefore applied to interpret the data. Using a Mott–Schottky approximation, a Schottky barrier height of 0.5–0.6 V and an effective grain boundary width of 8–10 nm (=2× space–charge layer thickness) is obtained at 250 °C in wet oxygen. Finite-element modelling of the complex impedance over a grain boundary with a space–charge layer depletion of protons yields a distorted semicircle as observed in the impedance spectra
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