Influence of ceramic (feldspathic) surface treatments on the micro-shear bond strength of composite resin

Objective: To test the null hypothesis that surface treatment has no influence on the micro-shear bond strength between orthodontic composite resin cement and ceramics (feldspathic porcelain). Materials and Methods: Circular specimens of feldspathic porcelain were fabricated and randomly divided into six groups: (1) no treatment; (2) treatment with a mixture of acidic primer and silane agent for 20 seconds; (3) etching with 9.5% hydrofluoric acid; (4) etching with 9.5% hydrofluoric acid and coating with a mixture of acidic primer and silane agent for 20 seconds; (5) airborne-particle abrasion with 50-μm aluminum oxide; and (6) airborne-particle abrasion and coating with a mixture of acidic primer and silane agent for 20 seconds. The porcelain disks were then bonded to resin cylinders with composite resin cement. A micro-shear bond test was carried out to measure the bond strength. Moreover, each ceramic surface was observed morphologically by scanning electron microscopy. One-way analysis of covariance was used to compare the groups for differences in micro-shear bond strength. Results: The mean micro-shear bond strength varied as a function of surface treatment. It ranged from 3.7 to 20.8 MPa. The highest values for micro-shear bond strength were found when the surface was acid-etched with hydrofluoric acid and coated with silane. On the other hand, the control group (no treatment) had significantly lower micro-shear bond strength than all the other groups. Conclusion: The null hypothesis that the surface treatment has no influence on the micro-shear bond strength of orthodontic composite resin was rejected. The bond strength between ceramics and orthodontic resin cement is affected by the ceramic surface treatment. The bond failure was of the adhesive type, except with the hydrofluoric acid + silane group, where it was a cohesive bond failure

Analysis of damage and fracture mechanisms in ductile metals under non-proportional loading paths

The paper discusses biaxial experiments and corresponding numerical simulations to analyze the effect of non-proportional loading paths on damage and fracture behavior of ductile metals. Newly developed specimens are taken from thin metal sheets and are tested under different biaxial loading conditions covering a wide range of stress states. In this context, an anisotropic continuum damage model is presented based on yield and damage conditions as well as on evolution laws for plastic and damage strain rates. Different branches of the damage criteria are taken into account corresponding to various damage and failure processes on the micro-level depending on stress triaxiality and Lode parameter. Experiments with biaxially loaded specimens have been performed. Results for proportional and corresponding non-proportional loading histories are discussed. During the experiments strain fields in critical regions of the specimens are analyzed by digital image correlation (DIC) technique while the fracture surfaces are examined by scanning electron microscopy (SEM). Numerical simulations of the experiments have been performed and numerical results are compared with experimental data. In addition, based on the numerical analyses stress distributions in critical parts of specimens are detected. The results demonstrate the efficiency of the new specimen’s geometries covering a wide range of stress states in the shear/tension and shear/compression regime as well as the effect of loading history on damage and fracture behavior in ductile metal sheets

Modeling of ductile damage using numerical analyses on the micro-scale

The presentation deals with a continuum damage model which has been generalized to take into account the effect of stress state on damage criteria as well as on evolution equations of damage strains. It is based on the introduction of damaged and corresponding undamaged configurations. Plastic behavior is modeled by a yield criterion and a flow rule formulated in the effective stress space (undamaged configurations). In a similar way, damage behavior is governed by a damage criterion and a damage rule considering the damaged configurations. Different branches of the damage criterion are considered corresponding to various damage mechanisms depending on stress intensity, stress triaxiality and the Lode parameter. Experiments with carefully designed specimens are performed and the test results are used to identify basic material parameters. However, it is not possible to determine all parameters based on these tension and shear tests. To be able to get more insight in the complex damage behavior under different loading conditions, additional series of micro-mechanical numerical analyses of void containing unit cells have been performed. These finite element calculations on the micro-level cover a wide range of stress triaxialities and Lode parameters in the tension, shear and compression domain. The numerical results are used to show general trends, to develop equations for the stress-statedependent damage criteria, to propose evolution equations of damage strains, and to identify parameters of the continuum model

Deformation modes and geometries in the EPICA-DML ice core, Antarctica

Combination of physical-properties methods (crystal-orientation-fabrics, grain-elongation-data, line-scan stratigraphy-documentation) reveal evidences for five deformation geometry regimes:1. Random c-axes distributions and crystal elongation directions (~2020 m depth). Here bed-parallel simple shear deforms the ice causing folding and inclination of stratigraphic layers.5. A last change of geometries is observed at ~2370 m depth, with a locally very restricted (~10 m) backslide to girdle fabric, isoclinal z-folding and borehole closure. Below that an inclined single maximum fabric reoccurs.Simple shear can easily produce the observed small-scale folding of layers which however may belong to disturbances on a larger scale with possible overturning and thus age reversal of layers. Below ~2020 m the EDML climate record has to be interpreted with great care

Studies on the growth of voids in amorphous glassy polymers

Numerical studies are presented of the localized deformations around voids in amorphous glassy polymers. This problem is relevant for polymer-rubber blends once cavitation has taken place inside the rubber particles. The studies are based on detailed finite element analyses of axisymmetric or planar cell models, featuring large local strains and recent material models that describe time-dependent yield, followed by intrinsic softening and subsequent strain hardening due to molecular orientation. The results show that plasticity around the void occurs by a combination of two types of shear bands, which we refer to as wing and dog-ear bands, respectively. Growth of the void occurs by propagation of the shear bands, which is driven by orientational hardening. Also discussed is the evolution of the local hydrostatic stress distribution between voids during growth, in view of possible craze initiation.

Residual stress, phase, microstructure and mechanical property studies of ultrafine bainitic steel through laser shock peening

The aimed study proposes laser shock peening without a coating of high strength ultrafine bainitic steel to mitigating the fatigue failures for automotive and structural engineering applications. Laser pulse density of 2500 pulses/cm2 (75% overlapping) was optimised based on the induced residual stresses for employing the wide range of characterisations. The roughness and topographic results showed that surface roughening was controlled by tuning the laser pulse density. The High-Resolution X-ray Diffraction analysis confirmed the lattice misorientation resulting peak shift and the trend towards martensite phase transformations. The electron microscopic micro/nanostructure analyses revealed the grain refinement features such as nano-twins, micro shear bands and shear cells. The work hardening depth analysis indicates the significant enhancement in the mechanical properties. Completely reversed (R = −1) high-cycle fatigue tests extended the lifespan by an average of five times than the untreated. Also, it has potential to repair the structural components effectively.<br/

Microstructure mapping: a new method for imaging deformation-induced microstructural features of ice on the grain scale

This work presents a method of mapping deformation-related sublimation patterns, formed on the surface of ice specimens, at microscopic resolution (3-4 gm pixel(-1)). The method is based on the systematic sublimation of a microtomed piece of ice, prepared either as a thick or a thin section. The mapping system consists of an optical microscope, a CCD video camera and a computer-controlled xy-stage. About 1500 images are needed to build a high-resolution mosaic map of a 4.5 x 9 cm section. Mosaics and single images are used to derive a variety of statistical data about air inclusions (air bubbles and air clathrate hydrates), texture (grain size, shape and orientation) and deformation-related features (subgrain boundaries, slip bands, subgrain islands and loops, pinned and bulged grain boundaries). The most common sublimation patterns are described, and their relevance for the deformation of polar ice is briefly discussed