Effects of Gravity and Non-Perpendicularity during Powder-Fed Directed Energy Deposition of Ni-Based Alloy 718 through Two Types of Coaxial Nozzle

The consequences of gravity and the nozzle inclination angle in the powder-fed Directed Energy Deposition (DED) process were examined in this study. We also sought to define guidelines and manufacturing strategies, depending on the DED system configuration and the nozzle type. To do so, two nozzle types were used: a continuous coaxial nozzle with a slit of 0.5 mm and a four-stream discrete coaxial nozzle. Although the main effects of the configurations and the nozzles are well-known, their effects on the clad characteristics and the deposition strategy are as yet unclear. In this paper, measurements of a single clad and the effects of different deposition strategies on cladding applications and inclined walls are presented, and the consequences for manufacturing processes are discussed. Based on a complete study of a single clad, working vertically, five different tilted deposition strategies were applied: three to a single clad and two to an inclined wall. The results for both the single clad and the inclined wall reflect a pattern of changes to height, width, area, and efficiency, at both small and large nozzle angles and deposition strategies. The inclined wall presents a maximum horizontal displacement that can be reached per layer, without geometrical distortions. The amount of material per layer has to be adapted to this limitation.This research was funded by the European Commission through the project "PARADDISE: a Productive, Affordable and Reliable solution for large scale manufacturing of metallic components by combining laser-based Additive and Subtractive processes with high Efficiency” (Grant Agreement 723440), an initiative of the Public–Private Partnership “Photonics and Factories of the Future”. This research was also funded by European Institute of Innovation & Technology (EIT), through the project "DEDALUS: Directed Energy Deposition machines with integrated process ALgorithms Under dedicated monitoring and control System” (ID 20094), and by the vice-counseling of technology, innovation and competitiveness of the Basque Government (Eusko Jaurlaritza), under the ELKARTEK Program, PROCODA project, grant number KK-2019/00004

Study of the trace metal ion influence on the turnover of soil organic matter in cultivated contaminated soils

The role of metals in the behaviour of soil organic matter (SOM) is not well documented. Therefore, we investigated the influence of metals (Pb, Zn, Cu and Cd) on the dynamic of SOM in contaminated soils where maize (C4 plant) replaced C3 cultures. Three pseudogley brown leached soil profiles under maize with a decreasing gradient in metals concentrations were sampled. On size fractions, stable carbon isotopic ratio (d13C), metals, organic carbon and nitrogen concentrations were measured in function of depth. The determined sequence for the amount of C4 organic matter in the bulk fractions: M3 (0.9) > M2 (0.4) > M1 (0.3) is in agreement with a significant influence of metals on the SOM turnover. New C4 SOM, mainly present in the labile coarser fractions and less contaminated by metals than the stabilised C3 SOM of the clay fraction, is more easily degraded by microorganism

Stochastic linear scaling for metals and non metals

Total energy electronic structure calculations, based on density functional theory or on the more empirical tight binding approach, are generally believed to scale as the cube of the number of electrons. By using the localisaton property of the high temperature density matrix we present exact deterministic algorithms that scale linearly in one dimension and quadratically in all others. We also introduce a stochastic algorithm that scales linearly with system size. These results hold for metallic and non metallic systems and are substantiated by numerical calculations on model systems.Comment: 9 pages, 2 figure

Theory for the electromigration wind force in dilute alloys

A multiple scattering formulation for the electromigration wind force on atoms in dilute alloys is developed. The theory describes electromigration via a vacancy mechanism. The method is used to calculate the wind valence for electromigration in various host metals having a close-packed lattice structure, namely aluminum, the noble metals copper, silver and gold and the $4d$ transition metals. The self-electromigration results for aluminum and the noble metals compare well with experimental data. For the $4d$ metals small wind valences are found, which make these metals attractive candidates for the experimental study of the direct valence.Comment: 18 pages LaTeX, epsfig, 8 figures. to appear in Phys. Rev. B 56 of 15/11/199

Self-organized pseudo-graphene on grain boundaries in topological band insulators

Semi-metals are characterized by nodal band structures that give rise to exotic electronic properties. The stability of Dirac semi-metals, such as graphene in two spatial dimensions (2D), requires the presence of lattice symmetries, while akin to the surface states of topological band insulators, Weyl semi-metals in three spatial dimensions (3D) are protected by band topology. Here we show that in the bulk of topological band insulators, self-organized topologically protected semi-metals can emerge along a grain boundary, a ubiquitous extended lattice defect in any crystalline material. In addition to experimentally accessible electronic transport measurements, these states exhibit valley anomaly in 2D influencing edge spin transport, whereas in 3D they appear as graphene-like states that may exhibit an odd-integer quantum Hall effect. The general mechanism underlying these novel semi-metals -- the hybridization of spinon modes bound to the grain boundary -- suggests that topological semi-metals can emerge in any topological material where lattice dislocations bind localized topological modes.Comment: 14 pages, 6 figures. Improved discussion compared to the earlier versio

Duplex and superduplex stainless steels: microstructure and properties evolution by surface modification processes

The paper presents an overview of diffusion surface treatments, especially nitriding processes, applied to duplex and superduplex stainless steels in the last five years. Research has been done mainly to investigate different nitriding processes in order to optimize parameters for the most appropriate procedure. The scope has been to improve mechanical and wear resistance without prejudice to the corrosion properties of the duplex and superduplex stainless steels. Our investigation also aimed to understand the effect of the nitriding layer on the precipitation of secondary phases after any heating step.Peer ReviewedPostprint (published version

A Budget and Accounting of Metals at z~0: Results from the COS-Halos Survey

We present a budget and accounting of metals in and around star-forming galaxies at $z\sim 0$. We combine empirically derived star formation histories with updated supernova and AGB yields and rates to estimate the total mass of metals produced by galaxies with present-day stellar mass of $10^{9.3}$--$10^{11.6} M_{\odot}$. On the accounting side of the ledger, we show that a surprisingly constant 20--25% mass fraction of produced metals remain in galaxies' stars, interstellar gas and interstellar dust, with little dependence of this fraction on the galaxy stellar mass (omitting those metals immediately locked up in remnants). Thus, the bulk of metals are outside of galaxies, produced in the progenitors of today's $L^*$ galaxies. The COS-Halos survey is uniquely able to measure the mass of metals in the circumgalactic medium (to impact parameters of $< 150$ kpc) of low-redshift $\sim L^*$ galaxies. Using these data, we map the distribution of CGM metals as traced by both the highly ionized OVI ion and a suite of low-ionization species; combined with constraints on circumgalactic dust and hotter X-ray emitting gas out to similar impact parameters, we show that $\sim 40$% of metals produced by $M_{\star}\sim 10^{10}M_{\odot}$ galaxies can be easily accounted for out to 150 kpc. With the current data, we cannot rule out a constant mass of metals within this fixed physical radius. This census provides a crucial boundary condition for the eventual fate of metals in galaxy evolution models.Comment: 19 pages, 12 figures, 2 tables. ApJ, in pres