Magmatic record of India-Asia collision

This work was financially co-supported by Chinese Academy of Sciences (XDB03010301) and other Chinese funding agencies (Project 973: 2011CB403102 and 2015CB452604; NSFC projects: 41225006, 41273044, and 41472061).New geochronological and geochemical data on magmatic activity from the India-Asia collision zone enables recognition of a distinct magmatic flare-up event that we ascribe to slab breakoff. This tie-point in the collisional record can be used to back-date to the time of initial impingement of the Indian continent with the Asian margin. Continental arc magmatism in southern Tibet during 80-40 Ma migrated from south to north and then back to south with significant mantle input at 70-43 Ma. A pronounced flare up in magmatic intensity (including ignimbrite and mafic rock) at ca. 52-51 Ma corresponds to a sudden decrease in the India-Asia convergence rate. Geological and geochemical data are consistent with mantle input controlled by slab rollback from ca. 70 Ma and slab breakoff at ca. 53 Ma. We propose that the slowdown of the Indian plate at ca. 51 Ma is largely the consequence of slab breakoff of the subducting Neo-Tethyan oceanic lithosphere, rather than the onset of the India-Asia collision as traditionally interpreted, implying that the initial India-Asia collision commenced earlier, likely at ca. 55 Ma.Peer reviewe

The thermal history of the Western Irish onshore

We present here a low-temperature thermochronological study that combines the apatite fission-track and (U + Th)/He dating methods with a pseudo-vertical sampling approach to generate continuous and well-constrained temperature–time histories from the onshore Irish Atlantic margin. The apatite fission-track and (U + Th)/He ages range from the Late Jurassic to Early Cretaceous and the mean track lengths are relatively short. Thermal histories derived from inverse modelling show that following post-orogenic exhumation the sample profiles cooled to c. 75 °C. A rapid cooling event to surface temperatures occurred during the Late Jurassic to Early Cretaceous and was diachronous from north to south. It was most probably caused by c. 2.5 km of rift-shoulder related exhumation and can be temporally linked to the main stage of Mesozoic rifting in the offshore basins. A slow phase of reheating during the Late Cretaceous and Early Cenozoic is attributed to the deposition of a thick sedimentary sequence that resulted in c. 1.5 km of burial. Our data imply a final pulse of exhumation in Neogene times, probably related to compression of the margin. However, it is possible that an Early Cenozoic cooling event, compatible with our data but not seen in our inverse models, accounts for part of the Cenozoic exhumation

Characterization of the aerosol produced by infrared femtosecond laser ablation of polyacrylamide gels for the sensitive inductively coupled plasma mass spectrometry detection of selenoproteins

A 2D high repetition rate femtosecondlaserablation strategy (2-mm wide lane) previously developed for the detection of selenoproteins in gel electrophoresis by inductively coupled plasma mass spectrometry was found to increase signal sensitivity by a factor of 40 compared to conventional nanosecond ablation (0.12-mm wide lane) [G. Ballihaut, F. Claverie, C. Pécheyran, S. Mounicou, R. Grimaud and R. Lobinski, Sensitive Detection of Selenoproteins in Gel Electrophoresis by High Repetition Rate FemtosecondLaserAblation-Inductively Coupled Plasma Mass Spectrometry, Anal. Chem. 79 (2007) 6874–6880]. Such improvement couldn't be explained solely by the difference of amount of material ablated, and then, was attributed to the aerosol properties. In order to validate this hypothesis, the characterization of the aerosolproduced by nanosecond and high repetition rate femtosecondlaserablation of polyacrylamidegels was investigated. Our 2D high repetition rate femtosecondlaserablation strategy of 2-mm wide lane was found to produce aerosols of similar particle size distribution compared to nanosecond laserablation of 0.12-mm wide lane, with 38% mass of particles < 1 µm. However, at high repetition rate, when the ablated surface was reduced, the particle size distribution was shifted toward thinner particle diameter (up to 77% for a 0.12-mm wide lane at 285 µm depth). Meanwhile, scanning electron microscopy was employed to visualize the morphology of the aerosol. In the case of larger ablation, the fine particles ejected from the sample were found to form agglomerates due to higher ablation rate and then higher collision probability. Additionally, investigations of the plasma temperature changes during the ablation demonstrated that the introduction of such amount of polyacrylamidegel particles had very limited impact on the ICP source (ΔT~ 25 ± 5 K). This suggests that the cohesion forces between the thin particles composing these large aggregates were weak enough to have negligible impact on the ICPMS detection

Three-dimensional reconstruction of the tissue-specific multielemental distribution within Ceriodaphnia dubia via multimodal registration using laser ablation ICP-mass spectrometry and X-ray spectroscopic techniques

In this work, the three-dimensional elemental, distribution profile within the freshwater crustacean Ceriodaphnia dubia was constructed at a spatial resolution down to S mu m via a data, fusion approach employing state-of-the-art laser ablation inductively coupled plasma-time-of-flight mass spectrometry (LAICP-TOFMS) and laboratory-based absorption microcomputed tomography (mu-CT). C. dubia was exposed to elevated Cu, Ni, and Zn concentrations, chemically fixed, dehydrated, stained, and embedded, prior to mu-CT analysis. Subsequently, the sample was cut into 5 pm thin sections that were subjected to LA-ICPTOFMS imaging. Multimodal image registration was performed to spatially align the 2D LA-ICP-TOFMS images relative to the Corresponding slices of the 3D mu-CT reconstruction. Mass channels corresponding to the isotopes of a single element were merged to improve the signal-to-noise ratios within the elemental images. In order to aid the visual interpretation of the data, LA-ICP-TOEMS data wete projected onto the mu-CT voxels representing tissue. Additionally, the image resolution and elemental sensitivity were compared to those obtained with synchrotron radiation based 3D confocal mu-X-ray fluorescence imaging upon a chemically fixed and air-dried C. dubia specimen

Indosinian high-strain deformation for the Yunkaidashan tectonic belt, south China : Kinematics and 40Ar/39Ar geochronological constraints

Structural and 40Ar/39Ar data from the Yunkaidashan Belt document kinematic and tectonothermal characteristics of early Mesozoic Indosinian orogenesis in the southern part of the South China Block. The Yunkaidashan Belt is tectonically divided from east to west into the Wuchuang-Sihui shear zone, Xinyi-Gaozhou block, and the Fengshan-Qinxi shear zone. Indosinian structural elements ascribed to the Indosinian orogeny include D2 and D3 deformation. The early D2 phase is characterized by folding and thrusting with associated foliation and lineation development, related to NW-SE transpression under amphibolite- to greenschist-facies conditions. This event is heterogeneously overprinted by D3 deformation characterized by a gentle-dipping S-3 foliation, subhorizontally to shallowly plunging L3 lineation, some reactived-D2 folds and low-angle normal faults. The D3 fabrics suggest a sinistral transtensional regime under greenschist-facies metamorphism. The timing of the D2 and D3 events have been constrained to the early to middle Triassic (similar to 248-220 Ma) and late Triassic (similar to 220-200 Ma) respectively on the basis of 40Ar/39Ar geochronology and regional geological relations. The change from oblique thrusting (D2) to sinistral transtension (D3) may reflect oblique convergence and crustal thickening followed by relaxation of the overthickened crust. In combination with the regional relations from Xuefengshan to Yunkaidashan and on to Wuyishan, the early phase of the Indosinian orogeny constituted a large-scale positive flower structure and is related to the intracontinental convergence during the assembly of Pangea in which the less competent South China Orogen was squeezed between the more competent North China and Indosinian Blocks.Peer reviewe

Indigenous demosponge spicules in a Late Devonian stromatoporoid basal skeleton from the Frasnian of Belgium

This paper records the first example of a demosponge spicule framework in a single specimen of a Devonian stromatoporoid from the Frasnian of southern Belgium. The small sample (2.5 × 2 cm) is a component in a brecciated carbonate from a carbonate mound in La Boverie Quarry 30 km east of Dinant. Because of the small size of the sample, generic identification is not confirmed, but the stromatoporoid basal skeleton is similar to the genus Stromatopora. The spicules are arranged in the calcified skeleton, but not in the gallery space, and are recrystallized as multi-crystalline calcite. The spicules fall into two size ranges: 10-20 μm diameter and 500-2000 μm long for the large ones and between 5-15 μm diameter and 50-100 μm length for the small ones. In tangential section, the spicules are circular, they have a simple structure, and no axial canal has been preserved. The large spicules are always monaxons, straight or slightly curved styles or strongyles. The spicules most closely resemble halichondrid/axinellid demosponge spicules and are important rare evidence of the existence of spicules in Palaeozoic stromatoporoids, reinforcing the interpretation that stromatoporoids were sponges. The basal skeleton may have had an aragonitic spherulitic mineralogy. Furthermore, the spicules indicate that this stromatoporoid sample is a demosponge. © 2014 Lethaia Foundation. Published by John Wiley & Sons Ltd

Trace element homogeneity from micron- to atomic scale: Implication for the suitability of the zircon GJ-1 as a trace element reference material

The quality of a chemical reference material relies on the fact that the composition of the material is homogeneous across all scales. A series of different techniques have been used to evaluate the trace element homogeneity of the GJ-1 reference zircon from the micron- to atomic scale. Cathodoluminescence imaging was conducted along with quantitative crystallographic orientation analysis and trace element analysis using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). The nanometre-scale homogeneity was evaluated by analysing five mineral tips using atom probe tomography, which provides atomic scale three dimensional chemical reconstructions with unprecedented spatial resolution. Results show that the GJ-1 reference zircon is homogeneous at all scales, both structurally and chemically. Crystallographic orientation data confirms that this gem quality zircon has no detectable internal crystallographic orientation changes such as crystal-plastic deformation features or cracks. No mineral inclusions were found. Atom probe tomography shows that there is a lack of any chemical clustering or other modes of spatially defined elemental accumulation or depletion for the most abundant trace elements such as Y, Yb and Hf. This finding is supported by LA-ICPMS data revealing homogeneity within the analytical precision. Trace elements of significant abundance include P, Yb, Y, U and Hf, with contents of 30 ± 6, 65 ± 2, 238 ± 5, 284 ± 14 and 6681 ± 57 ppm, respectively. Hence, the GJ-1 zircon used as a reference zircon for UPb and Hf-isotopic studies is also a suitable zircon reference material for trace element analyses