6 research outputs found

    Irreducible Cartesian tensor analysis of harmonic scattering from chiral fluids

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    Symmetry principles of several distinct kinds are revealingly engaged in an analysis focussing on third harmonic scattering, a current focus of research on nonlinear optics in chiral media. Analysis in terms of irreducible Cartesian tensors elucidates the detailed electrodynamical origin, and character of the corresponding material properties. Considerations of fundamental charge, parity and time reversal (CPT) symmetry reveal the conditions for an interplay of transition multipoles to elicit a chiral response using circularly polarised pump radiation, and the symmetry of quantised angular momentum underpins the associated selection rules and angular distribution. The intrinsic structural symmetry of chiral scatterers determines their capacity to exhibit differential response. Exploiting permutational index symmetry in the response tensors enables quantitative assessment of the boundary values for experimentally measurable properties including circular intensity differentials

    Symmetries, Conserved Properties, Tensor Representations, and Irreducible Forms in Molecular Quantum Electrodynamics

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    In the wide realm of applications of quantum electrodynamics, a non-covariant formulation of theory is particularly well suited to describing the interactions of light with molecular matter. The robust framework upon which this formulation is built, fully accounting for the intrinsically quantum nature of both light and the molecular states, enables powerful symmetry principles to be applied. With their origins in the fundamental transformation properties of the electromagnetic field, the application of these principles can readily resolve issues concerning the validity of mechanisms, as well as facilitate the identification of conditions for widely ranging forms of linear and nonlinear optics. Considerations of temporal, structural, and tensorial symmetry offer significant additional advantages in correctly registering chiral forms of interaction. More generally, the implementation of symmetry principles can considerably simplify analysis by reducing the number of independent quantities necessary to relate to experimental results to a minimum. In this account, a variety of such principles are drawn out with reference to applications, including recent advances. Connections are established with parity, duality, angular momentum, continuity equations, conservation laws, chirality, and spectroscopic selection rules. Particular attention is paid to the optical interactions of molecules as they are commonly studied, in fluids and randomly organised media

    Irreducible spherical representation of some fourth-rank tensors

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    New Trends in Quantum Electrodynamics

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    Quantum electrodynamics is one of the most successful physical theories, and its predictions agree with experimental results with exceptional accuracy. Nowadays, after several decades since its introduction, quantum electrodynamics is still a very active research field from both the theoretical and experimental points of view. The aim of this Special Issue is to present recent relevant advances in quantum electrodynamics, both theoretical and experimental, and related aspects in quantum field theory and quantum optics
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