Investigation of the dielectric and thermal properties of non-edible cottonseed oil by infusing h-BN nanoparticles

Vegetable oils have emerged as insulating fluids in transformer applications and as a prominent and effective alternative for traditional dielectric fluids. However, most of vegetable oils are edible causing their application on a large scale to be limited. In the present work, a novel non-edible vegetable oil is developed as an insulating fluid. The developed oil is oxidation-inhibited cottonseed oil (CSO) based nanofluids. Tertiary butylhydroquinone was used as antioxidant. The concept of nanofluids was used to overcome the limited dielectric and thermal properties of cottonseed oil. Hexagonal Boron Nitride (h-BN) nanoparticles at low weight fractions (0.01 - 0.1 wt%) were proposed as nanofillers to achieve adequate dielectric strength and improved thermal conductivity. Stability of prepared CSO based nanofluids was analyzed using Ultraviolet-visible (UV-Vis) spectroscopy. Then, the prepared nanofluids were tested for dielectric and thermal properties under a temperature range between 45 °C and 90 °C. The dielectric properties include breakdown strengths under AC and lightning impulse voltages, dielectric constant, dissipation factor, and resistivity, while thermal properties include thermal conductivity and thermogram analysis. The dielectric and thermal properties were significantly improved in CSO based nanofluids. The creation of electric double layer at nanoparticle/oil interface and the lattice vibration of nanoparticles were used to clarify the obtained results. The proposed CSO based h-BN nanofluids open up a great opportunity in both natural ester insulating fluid applications and thermal energy management systems

THERMAL CONDUCTIVITY MODELING OF DIELECTRIC OILS-BASED NANOFLUIDS USING THE FINITE ELEMENT METHOD

The enhancement of the thermal conductivity of dielectric oils has a positive effect on the performance of electrical equipment that uses these oils as a cooling medium. Nanofluids (NFs) have inspired high-voltage engineers to use them as alternative fluids in power transformers due to their impressive heat transfer and insulation compared to traditional dielectric oils. The present study is a numerical simulation by COMSOL Multiphysics of the thermal conductivity of NFs based on dielectric oils used in power transformers, to identify the effect of temperature, the concentration of nanoparticles (NPs), type of insulating fluid and NPs on thermal conductivity. The NFs were modeled inside a cube using the finite element method (FEM) by applying a temperature gradient. Several types of NPs were used (SiC, ZnO, TiO2, and Al2O3) in addition to several volume concentrations (0%, 0.001%, 0.002%, 0.01%, and 0.02%). The results showed a significant improvement in the thermal conductivity of the NFs with increasing concentration since the best results were recorded at an estimated volume concentration of 0.02%, while the lowest results were obtained for samples using a volume concentration estimated at 0.001%. The base fluid (BF) type and NPs play a dominant role in the thermal performance of the NFs, as the vegetable oil-based nanofluid provided the highest thermal conductivity values and silicon carbides (SiC) was the best NPs used in this study. However, a decrease in thermal transfer capacities was observed for all samples with increasing temperature

Development of Vegetable Oil-Based Nano-Lubricants Using Ag, h-BN and MgO Nanoparticles as Lubricant Additives

Because of the harmful impact of petroleum-based lubricant on the environment and human body, vegetable oil-based lubricant with eco-friendly nanoparticles has a great potential to be an alternative lubricant if it possesses proper lubricating properties. In this study, thermal conductivity, viscosity and tribological properties (wear scar diameter and coefficient of friction) of vegetable oil-based nanolubricant, developed from soybean oil and sunflower oil, modified with Ag, h-BN and MgO nanoparticles as lubricant additives, were evaluated. For thermal conductivity evaluation, a line heat source method was used with KD2 Pro-Thermal Property Analyzer. For viscosity evaluation, Haake Mars 40-rheometer was used to evaluate viscosity as a function of share rate and temperature. And for tribological properties evaluation, a fourball tester, named FBT-3 was used to obtain coefficient of friction and a digital image acquisition system, IAS-3 was used to measure wear scar diameter. It is observed that for all the samples, thermal conductivity increased as a function of nanoparticle concentration with increased temperature. The viscosity of all the sample showed a consistent result as a function of nanoparticle concentration and dropped significantly in response to increased temperature. Also, it has been observed that coefficient of friction and wear scar diameter lowered down to a certain nanoparticle concentration and then raised again as a result of increased nanoparticle concentration. These newly developed nanofluids can be promising alternatives to conventional petroleum-based lubricant