Information Systems Skills Differences between High-Wage and Low-Wage Regions: Implications for Global Sourcing

Developing Information Systems (IS) skills for a company’s workforce has always been challenging, but global sourcing growth has caused the determination of needed IS skills to be more complex. The increased use of outsourcing to an IS service provider and from high-wage regions to low-wage regions has affected what IS skills are required globally and how to distribute the workforce to meet these needs. To understand what skills are needed in locations that seek and those that provide outsourcing, we surveyed IS service provider managers in global locations. Results from 126 reporting units provide empirical evidence that provider units in low-wage regions value technical skills more than those in high-wage regions. Despite the emphasis on commodity skills in low-wage areas, high- and low-wage providers value project management skills. Low-wage regions note global and virtual teamwork more than high-wage regions do. The mix of skills and the variation by region have implications for domestic and offshore sourcing. Service providers can vary their staffing models in global regions which has consequences for recruiting, corporate training, and curriculum

Improved H_2 Storage in Zeolitic Imidazolate Frameworks Using Li^+, Na^+, and K^+ Dopants, with an Emphasis on Delivery H_2 Uptake

We use grand canonical Monte Carlo simulations with first principles based force fields to show that alkali metal (Li^+, Na^+, and K^+)-doped zeolitic imidazolate frameworks (ZIFs) lead to significant improvement of H_2 uptake at room temperature. For example, at 298 K and 100 bar, Li-ZIF-70 totally binds to 3.08 wt % H_2, Na-ZIF-70 to 2.19 wt % H_2, and K-ZIF-70 to 1.62 wt % H_2, much higher than 0.74 wt % H_2 for pristine ZIF-70. Thus, the dopant effect follows the order of Li-ZIF > Na-ZIF > K-ZIF, which correlates with the H_2 binding energies to the dopants. Moreover, the total H_2 uptake is higher at lower temperatures: 243 K > 273 K > 298 K. On the other hand, delivery H_2 uptake, which is the difference between the total adsorption at the charging pressure (say 100 bar) and the discharging pressure (say 5 bar), is the important factor for practical on-board hydrogen storage in vehicles. We show that delivery H_2 uptake leads to Na-ZIF-70 (1.37 wt %) > K-ZIF-70 (1.25 wt %) > Li-ZIF-70 (1.07 wt %) > ZIF-70 (0.68 wt %), which is different from the trend from the total and excess uptake. Moreover, the delivery uptake increases with increasing temperatures (i.e., 298 K > 273 K > 243 K)! To achieve high delivery H_2 uptake at room temperature, the large free volume of ZIFs is required. We find that higher H_2 binding energy needs not always lead to higher delivery H_2 uptake

Development of an in-field tree imaging system : a thesis presented in partial fulfilment of the requirements for the degree of Master of Technology at Massey University

Quality inventory information is essential for optimal resource utilisation in the forestry industry. In-field tree imaging is a method which has been proposed to improve the preharvest inventor assessment of standing trees. It involves the application of digital imaging technology to this task. The method described generates a three dimensional model of each tree through the capture of two orthogonal images from ground level. The images are captured and analysed using the "TreeScan" in-field tree imaging system. This thesis describes the design, development, and evaluation of the TreeScan system. The thesis can also be used as a technical reference for the system and as such contains appropriate technical and design detail. The TreeScan system consists of a portable computer, a custom designed high resolution scanner with integral microcontroller, a calibration rod, and custom designed processing software. Images of trees are captured using the scanner which contains a CCD line scan camera and a precision scanning mechanism. Captured images are analysed on the portable computer using customised image processing software to estimate real world tree dimensions and shape. The TreeScan system provides quantitative estimates of five tree parameters; height, sweep, stem diameter, branch diameter, and feature separation such as internodal distance. In addition to these estimates a three dimensional model is generated which can be further processed to determine the optimal stem breakdown into logs

Zeolitic Imidazolate Frameworks as H_2 Adsorbents: Ab Initio Based Grand Canonical Monte Carlo Simulation

We report the H_2 uptake behavior of 10 zeolitic−imidazolate frameworks (ZIFs), based on grand canonical Monte Carlo (GCMC) simulations. The force fields (FFs) describing the interactions between H_2 and ZIF in the GCMC were based on ab initio quantum mechanical (QM) calculations (MP2) aimed at correctly describing London dispersion (van der Waals attraction). Thus these predictions of H_2 uptake are based on first principles (non empirical) and hence applicable to new framework materials for which there is no empirical data. For each of these 10 ZIFs we report the total and excess H_2 adsorption isotherms up to 100 bar at both 77 and 300 K. We report the hydrogen adsorption sites in the ZIFs and the relationships between H_2 uptake amount, isosteric heat of adsorption (Q_(st)), surface area, and free volume. Our simulation shows that various ZIFs lead to a variety of H_2 adsorption behaviors in contrast to the metal−organic frameworks (MOFs). This is because ZIFs leads to greater diversity in the adsorption sites (depending on both organic linkers and zeolite topologies) than in MOFs. In particular, the ZIFs uptake larger amounts of H_2 at low pressure because of the high H_2 adsorption energy, and ZIFs have a variety of H_2 adsorption sites. For example, ZIF-11 has an initial Q_(st) value of ~15 kJ/mol, which is higher than observed for MOFs. Moreover, the preferential H_2 adsorption site in ZIFs is onto the organic linker, not nearby the metallic joint as is the case for MOFs