Hydrothermal Process for Cellulosic Waste Degradation Into Valuable Chemicals

Pada tulisan ini dibahas tentang sifat-sifat air pada kondisi sub dan super kritik dalam kemampuannyauntuk menguraikan biomasa selulosa. Air dalam kondisi super kritik mempunyai sifat oksidator yang kuat, yangmampu menguraikan biomasa selulosa menjadi molekul yang lebih kecil seperti dalam bentuk gas CO2 , H2 danair. Air pada kondisi sub kritik mempunyai sifat oksidator yang lebih rendah yang mampu menguraikanbiomasa selulosa menjadi molekul yang agak besar seperti glukosa, asam-asam organik dan biofuel. Penguraianbiomasa selulosa dengan proses hydrothermal biasanya menghasilkan gas, cairan dan padatan tar. Denganmengubah-ubah kondisi operasi (temperatur dan tekanan), jenis katalis, dan waktu reaksi, dan juga komposisidari biomasa selulosa maka produk yang akan dihasilkan bisa diperkirakan. Hydrothermal upgrading danliquefaction menggunakan media air pada kondisi subkritik untuk menguraikan biomasa selulosa menjadiproduk bentuk cair yang bisa dipakai sebagai bahan bakar

Crystal growing by electrodeposition from dense gaseous solutions

Single crystals and dendritic formations of silver are grown on platinum electrodes by electrodeposition from a dense gaseous solution of silver nitrate in ammonia. Process is modification of hydrothermal process, and also differs from standard electrodeposition by permitting single crystals to be grown from hydrogen-bonded solvents

Aminated TiO2 nanotube as a Photoelectrochemical Water Splitting photoanode

The present work reports on the enhancement of TiO2 nanotubes photoelectrochemical water splitting rate by decorating the nanostructure with an amine layer in a hydrothermal process using diethylenetriamine (DETA). The aminate coated TiO2 tubes show a stable improvement of the photoresponse in both UV and visible light spectrum and under hydrothermal conditions, 4-fold increase of the photoelectrochemical water splitting rate is observed. From intensity modulated photocurrent spectroscopy (IMPS) measurements significantly faster electron transport times are observed indicating a surface passivating effect of the N-decoration.Comment: In Catalysis Today, Available online 21 July 201

Microwave-assisted and conventional hydrothermal carbonization of lignocellulosic waste material: comparison of the chemical and structural properties of the hydrochars

This study compares the chemical and structural properties of the hydrochars prepared from microwave-assisted and conventional hydrothermal carbonizations of Prosopis africana shell, a waste plant material. The preparation involved heating the raw material in de-ionized water at 200 °C for 5-20 min, and 120-240 min in the microwave and conventional oven respectively. The prepared hydrochars were characterized using the scanning electron microscope, nitrogen sorption measurement, Fourier transform infrared spectroscopy, CHN analyzer, thermogravimetric analysis, and nuclear magnetic resonance. The results showed that the microwave-assisted hydrothermal carbonization process is fast in the carbonization of the Prosopis africana shell as shown by the level of conversion attained within the short time. This study presents new data on the comparison of the hydrochars from microwave-assisted and conventional hydrothermal carbonization processes of the same lignocellulosic material in terms of their properties

Molecular parameters of post impact cooling in the Boltysh impact structure

Impact events have the potential to generate a number of long-term sources of heat that can lead to the initiation of hydrothermal systems when the impact occurs on a water- or ice-rich target. Such hydrothermal systems have been postulated as promising locations to search for evidence of past biological processes on Mars due to the prevalence of impact cratering as a surface process in Mars’s early history. In this study, we have used molecular parameters of the thermal maturity of organic matter combined with palynology and carbon isotope stratigraphy to study the post impact thermal history of crater fill sediments from the Boltysh crater, Ukraine

Prebiotic Organic Microstructures

Micro- and sub-micrometer spheres, tubules and fiber-filament soft structures have been synthesized in our experiments conducted with 3 MeV proton irradiations of a mixture of simple inorganic constituents, CO, N2 and H2O. We analysed the irradiation products, with scanning electron microscopy (SEM) and atomic force microscopy (AFM). These laboratory organic structures produced wide variety of proteinous and non-proteinous amino acids after HCl hydrolysis. The enantiomer analysis for D-, L- alanine confirmed that the amino acids were abiotically synthesized during the laboratory experiment. Considering hydrothermal activity, the presence of CO2 and H2, of a ferromagnesian silicate mineral environment, of an Earth magnetic field which was much less intense during Archean times than nowadays and consequently of a proton excitation source which was much more abundant, we propose that our laboratory organic microstructures might be synthesized during Archean times. We show similarities in morphology and in formation with some terrestrial Archean microstructures and we suggest that some of the observed Archean carbon spherical and filamentous microstructures might be composed of abiogenic organic molecules. We further propose a search for such prebiotic organic signatures on Mars. This article has been posted on Nature precedings on 21 July 2010 [1]. Extinct radionuclides as source of excitation have been replaced by cosmic radiations which were much more intense 3.5 Ga ago because of a much less intense Earth magnetic field. The new version of the article has been presented at the ORIGINS conference in Montpellier in july 2011 [2] and has since been published in Origins of Life and Evolution of Biospheres 42 (4) 307-316, 2012. 
DOI: 10.1007/s11084-012-9290-5 

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Near-seafloor magnetic mapping of off-axis lava flows near the Kairei and Yokoniwa hydrothermal vent fields in the Central Indian Ridge

Abstract The Kairei (KHF) and Yokoniwa hydrothermal fields (YHF) are hosted in mafic as well as ultramafic rocks distributed at an off-axis volcanic knoll of the Central Indian Ridge. Despite intensive investigations, their geological and geophysical background is still debated. Here, we show the results of near-seafloor magnetic anomaly surveys conducted using a submersible. We investigated the bulk magnetization of the hydrothermally altered zone and the surrounding lava flows and evaluated their intensities compared with previously reported values at axial areas of seafloor spreading environments. The KHF is characterized by low coherence between observed and modeled anomalies and low values of magnetization. This result suggests that magnetic minerals within basaltic lava flows were likely altered by hydrothermal fluid circulation. The variation pattern in the observed magnetic anomalies above the lava flows is in phase with that of the modeled magnetic anomalies for the simple assumption that the magnetization direction is parallel to the geomagnetic field. This result suggests that these lava flows preserve normal magnetic polarity corresponding to the Brunhes Chron. The estimated magnetic-anomaly-derived absolute magnetizations show a reasonable correlation with the natural remanent magnetizations of rock samples collected from the seafloor of the same region; their relationship is consistent with previously reported datasets from the Mariana Trough and Mid-Atlantic Ridge. The estimated magnetization intensity reaches 20 A/m in the study area, which is clearly greater than those of previously reported off-axis areas, suggesting that recent volcanic eruption may have occurred in these off-axis areas. The high magnetization distributions are commonly observed at the bottoms of the western slope from the KHF and YHF. This finding provides new insight into the distribution of highly magnetized lava flows in the off-axis areas and indicates the distribution of recent off-axis volcanic activities, which is potentially linked to the sub-seafloor hydrothermal circulation

Employing surfactant-assisted hydrothermal synthesis to control CuGaO2 nanoparticle formation and improved carrier selectivity of perovskite solar cells

Delafossites like CuGaO2 have appeared as promising p-type semiconductor materials for opto-electronic applications mainly due to their high optical transparency and electrical conductivity. However, existing synthetic efforts usually result in particles with large diameter limiting their performance relevant to functional electronic applications. In this article, we report a novel surfactant-assisted hydrothermal synthesis method, which allows the development of ultrafine (~5 nm) monodispersed p-type CuGaO2 nanoparticles (NPs). We show that DMSO can be used as a ligand and dispersing solvent for stabilizing the CuGaO2 NPs. The resulting dispersion is used for the fabrication of dense, compact functional CuGaO2 electronic layer with properties relevant to advanced optoelectronic applications. As a proof of concept, the surfactant-assisted hydrothermal synthesized CuGaO2 is incorporated as a hole transporting layer (HTL) in the inverted p-i-n perovskite solar cell device architecture providing improved hole carrier selectivity and power conversion efficiency compared to conventional PEDOT:PSS HTL based perovskite solar cells

Machine learning-guided synthesis of advanced inorganic materials

Synthesis of advanced inorganic materials with minimum number of trials is of paramount importance towards the acceleration of inorganic materials development. The enormous complexity involved in existing multi-variable synthesis methods leads to high uncertainty, numerous trials and exorbitant cost. Recently, machine learning (ML) has demonstrated tremendous potential for material research. Here, we report the application of ML to optimize and accelerate material synthesis process in two representative multi-variable systems. A classification ML model on chemical vapor deposition-grown MoS2 is established, capable of optimizing the synthesis conditions to achieve higher success rate. While a regression model is constructed on the hydrothermal-synthesized carbon quantum dots, to enhance the process-related properties such as the photoluminescence quantum yield. Progressive adaptive model is further developed, aiming to involve ML at the beginning stage of new material synthesis. Optimization of the experimental outcome with minimized number of trials can be achieved with the effective feedback loops. This work serves as proof of concept revealing the feasibility and remarkable capability of ML to facilitate the synthesis of inorganic materials, and opens up a new window for accelerating material development

The vertical distribution of iron stable isotopes in the North Atlantic near Bermuda

Seawater dissolved iron isotope ratios (δ^(56)Fe) have been measured in the North Atlantic near Bermuda. In a full-depth profile, seawater dissolved δ^(56)Fe is isotopically heavy compared to crustal values throughout the water column (δ^(56)Fe_(IRMM-014) = +0.30‰ to +0.71‰). Iron isotope ratios are relatively homogenous in the upper water column (between +0.30‰ to +0.45‰ above 1500 m), and δ^(56)Fe increases below this to a maximum of +0.71‰ at 2500 m, decreasing again to +0.35‰ at 4200 m. The δ^(56)Fe profile is very different from the iron concentration profile; in the upper water column [Fe] is variable while δ^(56)Fe is relatively constant, and in the deeper water column δ^(56)Fe varies while [Fe] remains relatively constant. The δ^(56)Fe profile is also not well correlated with other hydrographic tracers in the North Atlantic such as temperature, salinity, or the concentrations of oxygen, phosphate, silica, and CFC-11. The dissimilarity between δ^(56)Fe profiles and profiles of [Fe] and other hydrographic tracers shows that Fe isotope ratios provide a unique sort of information about ocean chemistry, and they suggest that Fe isotopes may therefore be a valuable new tool for tracing the global sources, sinks, and biogeochemical cycling of Fe