Outgassing of icy bodies in the solar system - I. The sublimation of hexagonal water ice through dust layers

Our knowledge about the physical processes determining the activity of comets were mainly influenced by several extremely successful space missions, the predictions of theoretical models and the results of laboratory experiments. However, novel computer models should not be treated in isolation but should be based on experimental results. Therefore, a new experimental setup was constructed to investigate the temperature dependent sublimation properties of hexagonal water ice and the gas diffusion through a dry dust layer covering the ice surface. We show that this experimental setup is capable to reproduce known gas production rates of pure hexagonal water ice. The reduction of the gas production rate due to an additional dust layer on top of the ice surface was measured and compared to the results of another experimental setup in which the gas diffusion through dust layers at room temperature was investigated. We found that the relative permeability of the dust layer is inversely proportional to its thickness, which is also predicted by theoretical models. However, the measured absolute weakening of the gas flow was smaller than predicted by models. This lack of correspondence between model and experiment may be caused by an ill-determination of the boundary condition in the theoretical models, which further demonstrates the necessity of laboratory investigations. Furthermore, the impedance of the dust layer to the ice evaporation was found to be similar to the impedance at room temperature, which means that the temperature profile of the dust layer is not influencing the reduction of the gas production. Finally, we present the results of an extended investigation of the sublimation coefficient, which is an important factor for the description of the sublimation rate of water ice and, thus, an important value for thermophysical modeling of icy bodies in the solar system.Comment: Submitted to Icaru

Nonlinear Structure of the Diffusing Gas-Metal Interface in a Thermonuclear Plasma

This Letter describes the theoretical structure of the plasma diffusion layer that develops from an initially sharp gas-metal interface. The layer dynamics under isothermal and isobaric conditions is considered so that only mass diffusion (mixing) processes can occur. The layer develops a distinctive structure with asymmetric and highly nonlinear features. On the gas side of the layer the diffusion coefficient goes nearly to zero, causing a sharp “front,” or well defined boundary between mix layer and clean gas with similarities to the Marshak thermal waves. Similarity solutions for the nonlinear profiles are found and verified with full ion kinetic code simulations. A criterion for plasma diffusion to significantly affect burn is given.United States. Dept. of Energy (Contract DE-AC52-06NA25396)United States. Dept. of Energy. Office of Science (Contract DE-AC52-07NA27344

Particle Stirring in Turbulent Gas Disks: Including Orbital Oscillations

We describe the diffusion and random velocities of solid particles due to stochastic forcing by turbulent gas. We include the orbital dynamics of Keplerian disks, both in-plane epicycles and vertical oscillations. We obtain a new result for the diffusion of solids. The Schmidt number (ratio of gas to particle diffusivity) is Sc = 1 + (Omega t_stop)^2, in terms of the particle stopping time, t_stop, and the orbital frequency, Omega. The standard result, Sc = 1 + t_stop/t_eddy, in terms of the eddy turnover time, t_eddy, is shown to be incorrect. The main difference is that Sc rises quadratically, not linearly, with stopping time. Consequently, particles larger than ~ 10 cm in protoplanetary disks will suffer less radial diffusion and will settle closer to the midplane. Such a layer of boulders would be more prone to gravitational collapse. Our predictions of RMS speeds, vertical scale height and diffusion coefficients will help interpret numerical simulations. We confirm previous results for the vertical stirring of particles (scale heights and random velocities), and add a correction for arbitrary ratios of eddy to orbital times. The particle layer becomes thinner for t_eddy > 1/Omega, with the strength of turbulent diffusion held fixed. We use two analytic techniques -- the Hinze-Tchen formalism and the Fokker-Planck equation with velocity diffusion -- with identical results when the regimes of validity overlap. We include simple physical arguments for the scaling of our results.Comment: 17 pages, 7 figures, 2 tables, accepted to Icaru

The effects of water and microstructure on the performance of polymer electrolyte fuel cells

n this paper, we present a comprehensive non-isothermal, one-dimensional model of the cathode side of a Polymer Electrolyte Fuel Cell. We explicitly include the catalyst layer, gas diffusion layer and the membrane. The catalyst layer and gas diffusion layer are characterized by several measurable microstructural parameters. We model all three phases of water, with a view to capturing the effect that each has on the performance of the cell. A comparison with experiment is presented, demonstrating excellent agreement, particularly with regard to the effects of water activity in the channels and how it impacts flooding and membrane hydration. We present several results pertaining to the effects of water on the current density (or cell voltage), demonstrating the role of micro-structure, liquid water removal from the channel, water activity, membrane and gas diffusion layer thickness and channel temperature. These results provide an indication of the changes that are required to achieve optimal performance through improved water management and MEA-component design. Moreover, with its level of detail, the model we develop forms an excellent basis for a multi-dimensional model of the entire membrane electrode assembly

Feasibility study of tungsten as a diffusion barrier between nickel-chromium-aluminum and Gamma/Gamma prime - Delta eutectic alloys

Coating systems proposed for potential use on eutectic alloy components in high-temperature gas turbine engines were studied with emphasis on deterioration of such systems by diffusion. A 1-mil thick W sheet was placed between eutectic alloys and a NiCrAl layer. Layered test specimens were aged at 1100 C for as long as long as 500 hours. Without the W barrier, the delta phase of the eutectic deteriorated by diffusion of Nb into the NiCrAl. Insertion of the W barrier stopped the diffusion of Nb from delta. Chromium diffusion from the NiCrAl into the gamma/gamma prime phase of the eutectic was greatly reduced by the barrier. However, the barrier thickness decreased with time; and W diffused into both the NiCrAl and the eutectic. When the delta platelets were alined parallel to the NiCrAl layer, rather than perpendicular, diffusion into the eutectic was reduced