60,367 research outputs found
Viscosity and viscosity anomalies of model silicates and magmas: a numerical investigation
We present results for transport properties (diffusion and viscosity) using
computer simulations. Focus is made on a densified binary sodium disilicate
2SiO-NaO (NS2) liquid and on multicomponent magmatic liquids (MORB,
basalt). In the NS2 liquid, results show that a certain number of anomalies
appear when the system is densified: the usual diffusivity maxima/minima is
found for the network-forming ions (Si,O) whereas the sodium atom displays
three distinct r\'egimes for diffusion. Some of these features can be
correlated with the obtained viscosity anomaly under pressure, the latter being
be fairly well reproduced from the simulated diffusion constant. In model
magmas (MORB liquid), we find a plateau followed by a continuous increase of
the viscosity with pressure. Finally, having computed both diffusion and
viscosity independently, we can discuss the validity of the Eyring equation for
viscosity which relates diffusion and viscosity. It is shown that it can be
considered as valid in melts with a high viscosity. On the overall, these
results highlight the difficulty of establishing a firm relationship between
dynamics, structure and thermodynamics in complex liquids.Comment: 13 pages, 8 figure
In-plane structure and ordering at liquid sodium surfaces and interfaces from ab initio molecular dynamics
Atoms at liquid metal surfaces are known to form layers parallel to the
surface. We analyze the two-dimensional arrangement of atoms within such layers
at the surface of liquid sodium, using ab initio molecular dynamics (MD)
simulations based on density functional theory. Nearest neighbor distributions
at the surface indicate mostly 5-fold coordination, though there are noticeable
fractions of 4-fold and 6-fold coordinated atoms. Bond angle distributions
suggest a movement toward the angles corresponding to a six-fold coordinated
hexagonal arrangement of the atoms as the temperature is decreased towards the
solidification point. We rationalize these results with a distorted hexagonal
order at the surface, showing a mixture of regions of five and six-fold
coordination. The liquid surface results are compared with classical MD
simulations of the liquid surface, with similar effects appearing, and with ab
initio MD simulations for a model solid-liquid interface, where a pronounced
shift towards hexagonal ordering is observed as the temperature is lowered
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A Multifunctional Cosolvent Pair Reveals Molecular Principles of Biomass Deconstruction
Structural properties of various sodium thiogermanate glasses through DFT-based molecular dynamics simulations
We present a study of the structural properties of (x)NaS-(1-x)GeS
glasses through DFT-based molecular dynamics simulations, at different sodium
concentrations (). We computed the radial pair correlation functions
as well as the total and partial structure factors. We also analyzed the
evolution of the corner- and edge-sharing intertetrahedral links with the
sodium concentration and show that the sodium ions exclusively destroy the
former. With the increase of the sodium concentration the ``standard'' FSDP
disappears and a new pre-peak appears in the structure factor which can be
traced back in the Na-Na partial structure factor. This self organization of
the sodium ions is coherent with Na-rich zones that we find at high modifier
concentration.Comment: 9 pages, 7 figures; to be published in Phys. Rev.
Structural properties of various sodium thiogermanate glasses through DFT-based molecular dynamics simulations
We present a study of the structural properties of (x)NaS-(1-x)GeS
glasses through DFT-based molecular dynamics simulations, at different sodium
concentrations (). We computed the radial pair correlation functions
as well as the total and partial structure factors. We also analyzed the
evolution of the corner- and edge-sharing intertetrahedral links with the
sodium concentration and show that the sodium ions exclusively destroy the
former. With the increase of the sodium concentration the ``standard'' FSDP
disappears and a new pre-peak appears in the structure factor which can be
traced back in the Na-Na partial structure factor. This self organization of
the sodium ions is coherent with Na-rich zones that we find at high modifier
concentration.Comment: 9 pages, 7 figures; to be published in Phys. Rev.
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