Acquisition of acid vapor and aerosol concentration data for use in dry deposition studies in the South Coast Air Basin

An atmospheric monitoring network was operated throughout the South Coast Air Basin in the greater Los Angeles area during the year 1986. The primary objective of this study was to measure the spatial and temporal concentration distributions of atmospheric gas phase and particulate phase acids and bases in support of the California Air Resources Board's dry deposition research program. Gaseous pollutants measured include HNO_3, HCl, HF, HBr, formic acid, acetic acid and ammonia. The chemical composition of the airborne particulate matter complex was examined in three size ranges: fine particles (less than 2.2 μm aerodynamic diameter, AD), PM_(10) (less than 10 μm AD) and total particles (no size discrimination). Upwind of the air basin at San Nicolas Island, gas phase acids concentrations are very low: averaging 0.3 μg m^(-3) (0.1 ppb) for HNO_3, 0.8 μg m^(-3) for HCl, 0.13 μg m^(-3) for HF, and 2.6 μg m^(-3) for formic acid. Annual average HN03 concentrations ranged from 3.1 μg m^(-3) (1.2 ppb) near the Southern California coast to 6.9 μg m^(-3) (2.7 ppb) at an inland site in the San Gabriel Mountains. HCl concentrations within the South Coast Air Basin averaged from 0.8 μg m^(-3) to 1.8 μg m^(-3) during the year 1986. Long-term average HF concentrations within the air basin are very low, in the range from 0.14 to 0.22 μg m^(-3) between monitoring sites. Long-term average formic acid concentrations are lowest near the coastline (5.0 μg m^(-3) at Hawthorne), with the highest average concentrations (10.7 μg m^(-3)) observed inland at Upland. Ammonia concentrations at low elevation within the South Coast Air Basin average from 2.1 μg m^(-3) to 4.4 μg m^(-3) at all sites except Rubidoux. Rubidoux is located directly downwind of a large ammonia source created by dairy farming and other agricultural activities in the Chino area. Ammonia concentrations at Rubidoux average 30 μg m^(-3) during 1986, a factor of approximately 10 higher than elsewhere in the air basin. Annual average PM_(10) mass concentrations within the South Coast Air Basin ranged from 47.0 μg m^(-3) along the coast to 87.4 μg m^(-3) at Rubidoux, the farthest inland monitoring site. Five major aerosol components (carbonaceous material, NO_3^-, SO_4^-, NH_4^+ and soil-related material) accounted for greater than 80% of the annual average PM_(10) mass concentration at all on-land monitoring stations. A peak 24-h average PM_(10) mass concentration of 299 μg m^(-3) was observed at Rubidoux during 1986. That value is a factor of 2 higher than the federal 24-h average PM_(10) concentration standard, and a factor of 6 higher than the State of California PM_(10) standard. More than 40% of the PM_(10) aerosol mass measured at Rubidoux during that peak day event consisted of aerosol nitrates plus ammonium ion. Reaction of gaseous nitric acid to form aerosol nitrates was a major contributor to the high PM_(10) concentrations observed in the Rubidoux area near Riverside, California

Predicting the Path to Recovery from Hurricane Katrina through the Lens of Hurricane Andrew and the Rodney King Riots

Hurricane Katrina caused the greatest damage of any hurricane in American history. We look at the rebuilding effort in New Orleans through the lens of two other disasters that occurred in 1992: Hurricane Andrew in Miami and the Rodney King riots in Los Angeles. The rebuilding effort in New Orleans shares similarities with both events, combining the impact of a hurricane on infrastructure and private businesses, and the prospect of an uneven recovery biased against racial minorities and the economically disadvantaged. Using the experience of the King riots, our concern is that the rebuilding effort will be modest at best in poorer areas and slow to develop. There is the prospect of long lasting negative effects on income in poor neighborhoods. In wealthier areas, the pecuniary incentive for private business and citizens to rebuild is stronger, and in some cases the rebuilding effort can cause net income gains in response to a natural disaster of the scale of Hurricane Andrew. Based on these events, we recommend targeting a disproportionate amount of federal transfers towards poorer areas to stimulate growth.riots, hurricane, Rodney King, Katrina, disasters

Advanced InSAR atmospheric correction: MERIS/MODIS combination and stacked water vapour models

A major source of error for repeat-pass Interferometric Synthetic Aperture Radar (InSAR) is the phase delay in radio signal propagation through the atmosphere (especially the part due to tropospheric water vapour). Based on experience with the Global Positioning System (GPS)/Moderate Resolution Imaging Spectroradiometer (MODIS) integrated model and the Medium Resolution Imaging Spectrometer (MERIS) correction model, two new advanced InSAR water vapour correction models are demonstrated using both MERIS and MODIS data: (1) the MERIS/MODIS combination correction model (MMCC); and (2) the MERIS/MODIS stacked correction model (MMSC). The applications of both the MMCC and MMSC models to ENVISAT Advanced Synthetic Aperture Radar (ASAR) data over the Southern California Integrated GPS Network (SCIGN) region showed a significant reduction in water vapour effects on ASAR interferograms, with the root mean square (RMS) differences between GPS- and InSAR-derived range changes in the line-of-sight (LOS) direction decreasing from ,10mm before correction to ,5mm after correction, which is similar to the GPS/MODIS integrated and MERIS correction models. It is expected that these two advanced water vapour correction models can expand the application of MERIS and MODIS data for InSAR atmospheric correction. A simple but effective approach has been developed to destripe Terra MODIS images contaminated by radiometric calibration errors. Another two limiting factors on the MMCC and MMSC models have also been investigated in this paper: (1) the impact of the time difference between MODIS and SAR data; and (2) the frequency of cloud-free conditions at the global scale

Sediment management for Southern California mountains, coastal plains and shoreline

The Environmental Quality Laboratory at Caltech and the Shore Processes Laboratory at Scripps Institution of Oceanography have jointly undertaken a study of regional sediment balance problems in coastal southern California (see map in Figure 1). The overall objective in this study is to define specific alternatives in sediment management that may be implemented to alleviate a) existing sediment imbalance problems (e.g. inland debris disposal, local shoreline erosion) and b) probable future problems that have not yet manifested themselves. These alternatives will be identified through a consideration of economic, legal, and institutional issues as well as an analysis of governing physical processes and engineering constraints. The first part of this study (Phase I), which is currently under way, involves a compilation and analysis of all available data in an effort to obtain an accurate definition of the inland/coastal regional sediment balance under natural conditions, and specific quantitative effects man-made controls have on the overall natural process. During FY77, substantial progress was made at EQL and SPL in achieving the objectives of the initial Planning and Assessment Phase of the CIT/SIO Sediment Management Project. Financial support came from Los Angeles County, U.S. Geological Survey, Orange County, U.S. Army Corps of Engineers, and discretionary funding provided by a grant from the Ford Foundation. The current timetable for completion of this phase is Fall 1978. This report briefly describes the project status, including general administration, special activities, and research work as of January 1978

Water-soluble organic aerosol in the Los Angeles Basin and outflow regions: Airborne and ground measurements during the 2010 CalNex field campaign

A particle-into-liquid sampler coupled to a total organic carbon analyzer (PILS-TOC) quantified particulate water-soluble organic carbon (WSOC) mass concentrations during the May 2010 deployment of the Center for Interdisciplinary Remotely Piloted Aircraft Studies (CIRPAS) Twin Otter in the CalNex field study. WSOC data collected during 16 flights provide the first spatiotemporal maps of WSOC in the San Joaquin Valley, Los Angeles Basin, and outflow regions of the Basin. WSOC was consistently higher in concentration within the Los Angeles Basin, where sea breeze transport and Basin topography strongly influence the spatial distribution of WSOC. The highest WSOC levels were associated with fire plumes, highlighting the importance of both primary and secondary sources for WSOC in the region. Residual pollution layers enriched with WSOC are observed aloft up to an altitude of 3.2 km and the highest WSOC levels for each flight were typically observed above 500 m. Simultaneous ground WSOC measurements during aircraft overpasses in Pasadena and Riverside typically exhibit lower levels, especially when relative humidity (RH) was higher aloft suggestive of the influence of aerosol-phase water. This points to the underestimation of the radiative effects of WSOC when using only surface measurements. Reduced aerosol-phase water in the eastern desert outflow region likely promotes the re-partitioning of WSOC to the gas phase and suppression of processes to produce these species (partitioning, multiphase chemistry, photolytic production); as a result, WSOC is reduced relative to sulfate (but not as much as nitrate) as aerosol is advected from the Basin to the outflows

California coast nearshore processes study

There are no author-identified significant results in this report

PRICE RELATIONSHIPS AMONG NORTH AMERICAN FRESH TOMATO MARKETS: A COMPARISON BETWEEN MEXICAN AND U.S. MARKETS

Tomato trade between the U.S. and Mexican has grown significantly during the past decade, and market structure suggests increased market integration. This study examines fresh tomato price relationships between two major North American shipping points (Sinaloa, and Florida) and several major terminal markets in the U.S. and Mexico to infer whether business strategies vary by supply region or the geography of consumer markets. The results show some evidence of inefficient pricing behavior among some markets, and suggest that Mexican shipping point prices are less integrated with Mexico's own terminal markets than the closest U.S. market, Los Angeles. Moreover, perfectly competitive price behavior is less likely in a terminal market (Chicago) where Sinaloa and Florida compete during winter months. These results are the basis of discussion on the role of strategic behavior and trade policy influence in these markets.International Relations/Trade,