A Two-Path Method for Eliminating the Effects of Self-Absorption on Temperature for Isothermal Flames

It is the purpose of the current note to outline a two-path method for the determination of flame temperatures. The method is valid for isothermal systems and spectral lines with Doppler contour. All errors arising from self-absorption are eliminated. Practical applications are made by determining the ratio of the total intensity observed when the flame is viewed with a cool blackbody as background to the total intensity obtained with a cool mirror as background

Cool Flame Propagation Speeds

Cool flames are studied at reduced-gravity in a closed, unstirred, spherical reactor to minimize complexities associated with natural convection. Under such conditions, transport is controlled by diffusive fluxes and the flames are observed to propagate radially outward from the center of the reactor toward the wall. Intensified video records are obtained and analyzed to determine the flame radius as a function of time for different vessel temperatures (593–623 K) and initial pressures (55.2–81.4 kPa) using an equimolar (Ø = 5) propane-oxygen premixture. Polynomial-fits are applied to the data and differentiated to determine the cool flame propagation speeds. In nearly all cases considered, the flame decelerates monotonically and in some cases, subsequently retreats towards the center of the reactor. The flame speed is also tabulated as a function of the flame stretch rate. Extrapolation of the cool flame speeds to zero stretch is then performed to determine the ‘‘unstretched’’ cool flame propagation speeds

Autoignition of n-decane Droplets in the Low-, Intermediate-, and High-temperature Regimes from a Mixture Fraction Viewpoint

Detailed numerical simulations of isolated n-decane droplets autoignition are presented for different values of the ambient pressure and temperature. The ignition modes considered included single-stage ignition, twostage ignition and cool-flame ignition. The analysis was conducted from a mixture fraction perspective. Two characteristic chemical time scales were identified for two-stage ignition: one for cool-flame ignition, and another for hot-flame ignition. The appearance and subsequent spatial propagation of a cool flame at lean compositions was found to play an important role in the ignition process, since it created the conditions for activating the hightemperature reactions pathway in regions with locally rich composition. Single-stage ignition was characterized by a single chemical time scale, corresponding to hot-flame ignition. Low-temperature reactions were negligible for this case, and spatial diffusion of heat and chemical species mainly affected the duration of the ignition transient, but not the location in mixture fraction space at which ignition first occurs. Finally, ignition of several cool flames of decreasing strength was observed in the cool-flame ignition case, which eventually lead to a plateau in the maximum gas-phase temperature. The first cool flame ignited in a region where the fuel / air mixture was locally lean, whereas ignition of the remaining cool flames occurred at rich mixture compositions.This is the author accepted manuscript. The final version is available from Springer via http://dx.doi.org/10.1007/s10494-016-9710-

Travelling waves in the cool flame regime

Hydrocarbon oxidation develops through a complex network of elementary steps. Depending on the initial thermodynamic conditions, different behaviours are observed ranging from slow combustion to hot ignition [1]. Chain reactions involving radicals, govern all the combustion processes. Most of the time, the operating kinetic mechanism can be approximated by a reduced kinetic scheme which is depending on the initial conditions. In an intermediate range of temperature, cool flames appear as a transition between slow combustion and hot ignition. The existence of cool flames is often associated with knocking is engines

The Cool Flames Experiment: Recent Results at Reduced and Partial Gravity

Cool flames at Earth (1g), Martian (0.38g), Lunar (0.18g) and reduced-gravity (10–2g) have been studied experimentally in a closed, unstirred, static reactor to better understand the role of natural convection and diffusive transport on the induction period(s), flame shape, flame propagation speed, pressure history and temperature profile. Natural convection is known to play an important role in all terrestrial, unstirred, static reactor cool flame and auto-ignition experiments when the Rayleigh number exceeds 600 [2,3,6]. At 1g, typical values of the Ra are 10^4-10^6. In this paper, experimental results from static, unstirred reactor studies conducted at four different gravitational acceleration levels are reported for an equimolar propane-oxygen premixture. At 1g, the effects of natural convection dominate diffusive transport, the cool flame starts near the top of the vessel and subsequently propagates downward through the vessel. The flame is inherently two-dimensional. As the effective gravitational acceleration decreases, the associated Ra decreases linearly, convective transport weakens relative to diffusive fluxes of heat and species. At reduced-gravity, cool flames are observed to propagate radially outward from a centrally-located kernel without distortion owed to convective flow at a velocity that depends on the flame radius

Experimental and modeling study of the autoignition of 1-hexene/iso-octane mixtures at low temperatures

Autoignition delay times have been measured in a rapid compression machine at Lille at temperatures after compression from 630 to 840 K, pressures from 8 to 14 bar, \Phi = 1 and for a iso octane/1 hexene mixture containing 82% iso-octane and 18% 1 hexene. Results have shown that this mixture is strongly more reactive than pure iso-octane, but less reactive than pure 1 hexene. It exhibits a classical low temperature behaviour, with the appearance of cool flame and a negative temperature coefficient region. The composition of the reactive mixture obtained after the cool flame has also been determined. A detailed kinetic model has been obtained by using the system EXGAS, developed in Nancy for the automatic generation of kinetic mechanisms, and an acceptable agreement with the experimental results has been obtained both for autoignition delay times and for the distribution of products. A flow rate analysis reveals that the crossed reactions between species coming from both reactants (like H-abstractions or combinations) are negligible in the main flow consumption of the studied hydrocarbons. The ways of formation of the main primary products observed and the most sensitive rate constants have been identified

Cool-flame Extinction During N-Alkane Droplet Combustion in Microgravity

Recent droplet combustion experiments onboard the International Space Station (ISS) have revealed that large n-alkane droplets can continue to burn quasi-steadily following radiative extinction in a low-temperature regime, characterized by negative-temperaturecoefficient (NTC) chemistry. In this study we report experimental observations of n-heptane, n-octane, and n-decane droplets of varying initial sizes burning in oxygen/nitrogen/carbon dioxide and oxygen/helium/nitrogen environments at 1.0, 0.7, and 0.5 atmospheric pressures. The oxygen concentration in these tests varied in the range of 14% to 25% by volume. Large n-alkane droplets exhibited quasi-steady low-temperature burning and extinction following radiative extinction of the visible flame while smaller droplets burned to completion or disruptively extinguished. A vapor-cloud formed in most cases slightly prior to or following the "cool flame" extinction. Results for droplet burning rates in both the hot-flame and cool-flame regimes as well as droplet extinction diameters at the end of each stage are presented. Time histories of radiant emission from the droplet captured using broadband radiometers are also presented. Remarkably the "cool flame" extinction diameters for all the three n-alkanes follow a trend reminiscent of the ignition delay times observed in previous studies. The similarities and differences among the n-alkanes during "cool flame" combustion are discussed using simplified theoretical models of the phenomeno

Three Stage Cool Flame Droplet Burning Behavior of n-Alkane Droplets at Elevated Pressure Conditions: Hot, Warm and Cool Flame

Transient, isolated n-alkane droplet combustion is simulated at elevated pressure for helium-diluent substituted-air mixtures. We report the presence of unique quasi-steady, three-stage burning behavior of large sphero-symmetric n-alkane droplets at these elevated pressures and helium substituted ambient fractions. Upon initiation of reaction, hot-flame diffusive burning of large droplets is initiated that radiatively extinguishes to establish cool flame burning conditions in nitrogen/oxygen air at atmospheric and elevated pressures. However, at elevated pressure and moderate helium substitution for nitrogen ( X He > 20%), the initiated cool flame burning proceeds through two distinct, quasi-steady-state, cool flame burning conditions. The classical Hot flame ( 1500 K) radiatively extinguishes into a Warm flame burning mode at a moderate maximum reaction zone temperature ( 970 K), followed by a transition to a lower temperature ( 765 K), quasi-steady Cool flame burning condition. The reaction zone (flame) temperatures are associated with distinctly different yields in intermediate reaction products within the reaction zones and surrounding near-field, and the flame-standoff ratios characterizing each burning mode progressively decrease. The presence of all three stages first appears with helium substitution near 20%, and the duration of each stage is observed to be strongly dependent on helium substitutions level between 2060%. For helium substitution greater than 60%, the hot flame extinction is followed by only the lower temperature cool flame burning mode. In addition to the strong coupling between the diffusive loss of both energy and species and the slowly evolving degenerate branching in the low and negative temperature coefficient (NTC) kinetic regimes, the competition between the low-temperature chain branching and intermediate-temperature chain termination reactions control the Warm and Cool flame quasi-steady conditions and transitioning dynamics

Use of fiber like materials to augment the cycle life of thick thermoprotective seal coatings

Some experimental and analytical studies of plasma sprayed ZrO2-Y2O3 thick seal thermoprotective materials over NiCrAlY bond coats with testing to 1040 deg C in a Mach 0.3 burner flame are reviewed. These results indicate the need for material to have both compliance and sufficient strength to function successfully as a thick thermoprotective seal material. Fibrous materials may satisfy many of these requirements. A preliminary analysis simulating the simplified behavior of a 25 mm cylindrical SiO2-fiber material indicated significant radial temperature gradients, a relatively cool interface and generally acceptable stresses over the initial portion of the thermal cycle. Subsequent testing of these fiberlike materials in a Mach 0.3 Jet A/air burner flame confirmed these results

Combustion Characteristics in a Non-Premixed Cool-Flame Regime of n-Heptane in Microgravity

A series of distinct phenomena have recently been observed in single-fuel-droplet combustion tests performed on the International Space Station (ISS). This study attempts to simulate the observed flame behavior numerically using a gaseous n-heptane fuel source in zero gravity and a time-dependent axisymmetric (2D) code, which includes a detailed reaction mechanism (127 species and 1130 reactions), diffusive transport, and a radiation model (for CH4, CO, CO2, H2O, and soot). The calculated combustion characteristics depend strongly on the air velocity around the fuel source. In a near-quiescent air environment (< or = 2 mm/s), with a sufficiently large fuel injection velocity (1 cm/s), a growing spherical diffusion flame extinguishes at 1200 K due to radiative heat losses. This is typically followed by a transition to the low-temperature (cool-flame) regime with a reaction zone (at 700 K) in close proximity to the fuel source. The 'cool flame' regime is formed due to the negative temperature coefficient in the low-temperature chemistry. After a relatively long period (18 s) of the cool flame regime, a flash re-ignition occurs, associated with flame-edge propagation and subsequent extinction of the re-ignited flame. In a low-speed (3 mm/s) airstream (which simulates the slight droplet movement), the diffusion flame is enhanced upstream and experiences a local extinction downstream at 1200 K, followed by steady flame pulsations (0.4 Hz). At higher air velocities (4-10 mm/s), the locally extinguished flame becomes steady state. The present axisymmetric computational approach helps in revealing the non-premixed 'cool flame' structure and 2D flame-flow interactions observed in recent microgravity droplet combustion experiments