332,047 research outputs found
Spectral phase conjugation with cross-phase modulation compensation
Spectral phase conjugation with short pump pulses in a third-order nonlinear material is analyzed in depth. It is shown that if signal amplification is considered, the conversion efficiency can be significantly higher than previously considered, while the spectral phase conjugation operation remains accurate. A novel method of compensating for cross-phase modulation, the main parasitic effect, is also proposed. The validity of our theory and the performance of the spectral phase conjugation scheme are studied numerically
Complex conjugation supermap of unitary quantum maps and its universal implementation protocol
A complex conjugation of unitary quantum map is a second-order map (supermap)
that maps a unitary operator to its complex conjugate . First, we
present a deterministic quantum protocol that universally implements the
complex conjugation supermap when we are given a blackbox quantum circuit,
guaranteed to implement some unitary operation, whose only known description is
its dimension. We then discuss the complex conjugation supermap in the context
of entanglement theory and derive a conjugation-based expression of the
-concurrence. Finally, we present a physical process involving identical
fermions from which the complex conjugation protocol is derived as a simulation
of the process using qudits.Comment: ver.5: published version, 5 pages, 2 figures, double-colum
Conjugation in Semigroups
The action of any group on itself by conjugation and the corresponding
conjugacy relation play an important role in group theory. There have been
several attempts to extend the notion of conjugacy to semigroups. In this
paper, we present a new definition of conjugacy that can be applied to an
arbitrary semigroup and it does not reduce to the universal relation in
semigroups with a zero. We compare the new notion of conjugacy with existing
definitions, characterize the conjugacy in various semigroups of
transformations on a set, and count the number of conjugacy classes in these
semigroups when the set is infinite.Comment: 41 pages, 14 figure
[n]cycloparaphenylenes with charges
Oligophenylenes (polyphenylenes) are constituted by an array of conjugated benzenes where inter-ring electron delocalization tends to extend over the whole chain (linear conjugation) being intrinsically limited, among other factors, by terminal effects. Alternatively, cyclic conjugation is envisaged as the unlimited free-boundary versionofconjugation which will impact the structure of molecules in rather unknown ways. The cyclic version of oligophenylenes, cycloparaphenylenes ([n]CPPs with n the number of phenyl rings) were first synthesized in 2008 by Beztozzi and Jasti.1 Today the whole [n]CPP series from [5]CPP to [18]CPP has been prepared. [n]CPPs represent ideal models to investigate new insights of the electronic structure of molecules and cyclic conjugation when electrons or charges circulate in a closed circuit without boundaries. Radical cations and dications of [n]CPP from n=5 to n=12 have been prepared and studied by Raman spectroscopy.2 Small [n]CPP dications own their stability to the closed-shell electronic configuration imposed by cyclic conjugation. However, in large [n]CPP dications cyclic conjugation is minimal and these divalent species form open-shell biradicals. The Raman spectra reflect the effect of cyclic conjugation in competition with cyclic strain and biradicaloid aromatic stabilization. Cyclic conjugation provokes the existence of a turning point or V-shape behavior of the frequencies of the G bands as a function of n. In this communication we will show the vibrational spectroscopic fingerprint of this rare form of conjugation.
[1] R. Jasti, J. Bhattacharjee, J. B. Neaton, C. R. Bertozzi, “Synthesis, Characterization, and Theory of [9]-, [12]-, and [18]Cycloparaphenylene: Carbon Nanohoop Structures”, J. Am. Chem. Soc. 130 (2008), 17646–17647.
[2] M. P. Alvarez, P. M. Burrezo, M. Kertesz, T. Iwamoto, S. Yamago, J. Xia, R. Jasti, J. T. L. Navarrete, M. Taravillo, V. G. Baonza, J. Casado, “Properties of Sizeable [n]CycloParaPhenylenes As Molecular Models of Single-Wall Carbon Nanotubes By Raman Spectroscopy: Structural and Electron-Transfer Responses Under Mechanical Stress”, Angew. Chem. Int. Ed. 53, (2014), 7033−7037.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech
Quaternionic Hyperbolic Fenchel-Nielsen Coordinates
Let be the isometry group of the quaternionic hyperbolic plane
. An element in is `hyperbolic' if it
fixes exactly two points on the boundary of . We
classify pairs of hyperbolic elements in up to conjugation.
A hyperbolic element of is called `loxodromic' if it has no real
eigenvalue. We show that the set of conjugation orbits of irreducible
loxodromic pairs is a -bundle over a topological
space that is locally a semi-analytic subspace of . We use
the above classification to show that conjugation orbits of `geometric'
representations of a closed surface group (of genus ) into
can be determined by a system of real parameters.
Further, we consider the groups and . These
groups also act by the orientation-preserving isometries of the four and five
dimensional real hyperbolic spaces respectively. We classify conjugation orbits
of pairs of hyperbolic elements in these groups. These classifications
determine conjugation orbits of `geometric' surface group representations into
these groups.Comment: major structural revision. Restructured the exposition. Introduction
re-writte
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