Effect of silica colloids on the rheology of viscoelastic gels formed by the surfactant cetyl trimethylammonium tosylate

The effects of the addition of sub-micrometer sized colloidal silica spheres on the linear and nonlinear rheology of semi-dilute solutions of a viscoelastic gel are studied. For a 1.4 wt.% solution of the surfactant CTAT, a peak in the zero shear rate viscosity $\eta_{\circ}$ is observed at approximately equal weight percents of silica and CTAT. This peak shifts to lower silica concentrations on increasing either the CTAT concentration or the surface charge on silica and disappears when the CTAT concentration is increased to 2.6wt%. The increases in $\eta_{\circ}$ and the high frequency plateau modulus G$_{\circ}$ on the introduction of SiO$_{2}$ are explained by considering the increasingly entangled wormlike micelles that are formed due to the enhanced screening of the electrostatic interactions. The observed decrease in the values of G$_{\circ}$ and $\eta_{\circ}$ at higher concentrations of silica particles is explained in terms of the formation of surfactant bilayers due to the adsorption of the positively charged cetyl trimethylammonium to the negatively charged silica.Comment: 28 pages, includes 8 eps and 2 png figures; accepted for publication in Jl. Colloid Interface Sc

A sub-1-V Bandgap Voltage Reference in 32nm FinFET Technology

The bulk CMOS technology is expected to scale down to about 32nm node and likely the successor would be the FinFET. The FinFET is an ultra-thin body multi-gate MOS transistor with among other characteristics a much higher voltage gain compared to a conventional bulk MOS transistor [1]. Bandgap reference circuits cannot be directly ported from bulk CMOS technologies to SOI FinFET technologies, because both conventional diodes cannot be realized in thin SOI layers and also, area-efficient resistors are not readily available in processes with only metal(lic) gates. In this paper, a sub-1V bandgap reference circuit is implemented in a 32nm SOI FinFET technology, with an architecture that significantly reduces the required total resistance value

Oscillatory settling in wormlike-micelle solutions: bursts and a long time scale

We study the dynamics of a spherical steel ball falling freely through a solution of entangled wormlike-micelles. If the sphere diameter is larger than a threshold value, the settling velocity shows repeated short oscillatory bursts separated by long periods of relative quiescence. We propose a model incorporating the interplay of settling-induced flow, viscoelastic stress and, as in M. E. Cates, D. A. Head and A. Ajdari, Phys. Rev. E, 2002, 66, 025202(R) and A. Aradian and M. E. Cates, Phys. Rev. E, 2006, 73, 041508, a slow structural variable for which our experiments offer independent evidence.Comment: To appear in Soft Matte

A Radiation hard bandgap reference circuit in a standard 0.13um CMOS Technology

With ongoing CMOS evolution, the gate-oxide thickness steadily decreases, resulting in an increased radiation tolerance of MOS transistors. Combined with special layout techniques, this yields circuits with a high inherent robustness against X-rays and other ionizing radiation. In bandgap voltage references, the dominant radiation-susceptibility is then no longer associated with the MOS transistors, but is dominated by the diodes. This paper gives an analysis of radiation effects in both MOSdevices and diodes and presents a solution to realize a radiation-hard voltage reference circuit in a standard CMOS technology. A demonstrator circuit was implemented in a standard 0.13 m CMOS technology. Measurements show correct operation with supply voltages in the range from 1.4 V down to 0.85 V, a reference voltage of 405 mV 7.5 mV ( = 6mVchip-to-chip statistical spread), and a reference voltage shift of only 1.5 mV (around 0.8%) under irradiation up to 44 Mrad (Si)

Linear and nonlinear rheology of wormlike micelles

Several surfactant molecules self-assemble in solution to form long, cylindrical, flexible wormlike micelles. These micelles can be entangled with each other leading to viscoelastic phases. The rheological properties of such phases are very interesting and have been the subject of a large number of experimental and theoretical studies in recent years. We shall report on our recent work on the macrorheology, microrheology and nonlinear flow behaviour of dilute aqueous solutions of a surfactant CTAT (Cetyltrimethylammonium Tosilate). This system forms elongated micelles and exhibits strong viscoelasticity at low concentrations ($\sim$ 0.9 wt%) without the addition of electrolytes. Microrheology measurements of $G(\omega)$ have been done using diffusing wave spectroscopy which will be compared with the conventional frequency sweep measurements done using a cone and plate rheometer. The second part of the paper deals with the nonlinear rheology where the measured shear stress $\sigma$ is a nonmonotonic function of the shear rate $\dot{\gamma}$. In stress-controlled experiments, the shear stress shows a plateau for $\dot{\gamma}$ larger than some critical strain rate, similar to the earlier reports on CPyCl/NaSal system. Cates et al have proposed that the plateau is a signature of mechanical instability in the form of shear bands. We have carried out extensive experiments under controlled strain rate conditions, to study the time-dependence of shear stress. The measured time series of shear stress has been analysed in terms of correlation integrals and Lyapunov exponents to show unambiguously that the behaviour is typical of low dimensional dynamical systems.Comment: 15 pages, 10 eps figure

Evaluating a communication technology assessment tool (CTAT): A case of a cloud based communication tool

A primary concern of distributed adaptive development environment (DADE) is that of human communication and knowledge sharing among geographically dispersed developers. Emerging cloudbased communication technologies claim to provide a support for communication and knowledge sharing among developers in a DADE. However, the challenge is how to enable developers to self assess and select appropriate cloud-based communication technologies for their DADE. Based on our recent empirical study, we have developed the construct of a practical communication technologies assessment tool (CTAT). We argue that, CTAT construct, as a part of our large conceptual framework of context aware cloud adaptation (CACA), can be useful to assist developers in the self assessment of appropriate cloud-based communication technologies for their DADE. This paper presents the evaluation of the CTAT by using it for the assessment of the Force.com cloud-based Chatter communication tool. The main objective of this evaluation is to determine to what extent CTAT construct is relevant, valuable and sufficient to achieve its purpose. The results of this evaluation indicate that CTAT seems useful when performing vendor independent assessment of communication technologies in order to make an informed decision about the selection of a communication tool for the DADE

Tunable Brownian Vortex at the Interface

A general kind of Brownian vortexes are demonstrated by applying an external nonconservative force field to a colloidal particle bound by a conservative optical trapping force at a liquid-air interface. As the liquid medium is translated at a constant velocity with the bead trapped at the interface, the drag force near the surface provide enough rotational component to bias the particle's thermal fluctuations in a circulatory motion. The interplay between the thermal fluctuations and the advection of the bead in constituting the vortex motions is studied, inferring that the angular velocity of the circulatory motion offers a comparative measure of the interface fluctuations.Comment: Accepted for publication in Phys. Rev.

Dynamical Behaviour in the Nonlinear Rheology of Surfactant Solutions

Several surfactant molecules self-assemble in solution to form long, flexible wormlike micelles which get entangled with each other, leading to viscoelastic gel phases. We discuss our recent work on the rheology of such a gel formed in the dilute aqueous solutions of a surfactant CTAT. In the linear rheology regime, the storage modulus $G^{\prime}(\omega)$ and loss modulus $G^{\prime\prime}(\omega)$ have been measured over a wide frequency range. In the nonlinear regime, the shear stress $\sigma$ shows a plateau as a function of the shear rate $\dot\gamma$ above a certain cutoff shear rate $\dot\gamma_c$. Under controlled shear rate conditions in the plateau regime, the shear stress and the first normal stress difference show oscillatory time-dependence. The analysis of the measured time series of shear stress and normal stress has been done using several methods incorporating state space reconstruction by embedding of time delay vectors.The analysis shows the existence of a finite correlation dimension and a positive Lyapunov exponent, unambiguously implying that the dynamics of the observed mechanical instability can be described by that of a dynamical system with a strange attractor of dimension varying from 2.4 to 2.9.Comment: 12 pages, includes 7 eps figure

Nonequilibrium Fluctuation Relation for Sheared Micellar Gel in a Jammed State

We show that the shear rate at a fixed shear stress in a micellar gel in a jammed state exhibits large fluctuations, showing positive and negative values, with the mean shear rate being positive. The resulting probability distribution functions (PDF's) of the global power flux to the system vary from Gaussian to non-Gaussian, depending on the driving stress and in all cases show similar symmetry properties as predicted by Gallavotti-Cohen steady state fluctuation relation. The fluctuation relation allows us to determine an effective temperature related to the structural constraints of the jammed state. We have measured the stress dependence of the effective temperature. Further, experiments reveal that the effective temperature and the standard deviation of the shear rate fluctuations increase with the decrease of the system size.Comment: 5 pages 3 figure