Processing and electrical characterization of a unidirectional CFRP composite filled with double walled carbon nanotubes

Carbon nanotubes represent new emergent multifunctional materials that have potential applications for structural and electrically conductive composites. In the current paper we present a suitable technique for the integration of Double Walled Carbon Nanotubes (DWCNTs) in a unidirectional Carbon Fiber Reinforced Polymer (CFRP) with high volume content of carbon fiber. We showed that the electrical conductivity of the laminates versus temperature follows a non-linear variation which can be well described by the Fluctuation-Induced Tunneling Conduction (FITC) model. The parameters of this model for CFRP/ DWCNTs and CFRP without DWCNTs were determined using best fit curves of the experimental data. This study has shown that DWCNTs have strong influence in the conductivity through laminate thickness. However, there are no significant effects on the electrical conductivity measured in the other two principle directions of the composite laminate. Furthermore, it was found that electron conduction mechanism of carbon fibers is dominated by the FITC

Study of the response of CFRP composite laminates to a laser-induced shock

Laser-induced shock yields to a local tensile stress within a sample. This high strain rate stress can be used to verify the bond strength between two layers. This method has been applied to Carbon Fibre Reinforced Polymer (CFRP) composite laminates, involved in aeronautic or defense industry. Experiments have been carried out on high power laser facility in the nanosecond regime. A velocimetry interferometer has been used to record the material velocity at the back surface of the samples. This study provides a comprehensive approach of the response of CFRP laminates of different thicknesses to a shock load normal to the fibres direction. The stress waves generation and propagation within the laminate and the induced delamination are key issues of this work. The main result is the ability of the technique to evaluate the out-of-plane strength of these laminate

Fracture mechanisms and failure analysis of carbon fibre/toughened epoxy composites subjected to compressive loading

This study investigates the failure mechanisms of unidirectional (UD) HTS40/977-2 toughened resin composites subjected to longitudinal compressive loading. A possible sequence of failure initiation and propagation was proposed based on SEM and optical microscopy observations of failed specimens. The micrographs revealed that the misaligned fibres failed in two points upon reaching maximum micro-bending deformation and two planes of fracture were created to form a kink band. Therefore, fibre microbuckling and fibre kinking models were implemented to predict the compressive strength of LID HTS40/977-2 composite laminate. The analysis identified several parameters that were responsible for the microbuckling and kinking failure mechanisms. The effects of these parameters on the compressive strength of the LID HTS40/977-2 composite systems were discussed. The predicted compressive strength using a newly developed combined modes model showed a very good agreement to the measured value (c) 2009 Elsevier Ltd. All rights reserve

Extrapancreatic actions of incretin-based therapies on bone in diabetes mellitus

Diabetes mellitus is correlated with modifications in bone microarchitectural and mechanical strength, leading to increased bone fragility. The incretin hormones, with a classical effect to increase insulin secretion following food ingestion, are now postulated to have important direct effects on bone. As such, glucose-dependent insulinotropic polypeptide (GIP) has dual actions on bone cells; enhancing bone�forming activity of osteoblasts and suppressing bone resorption by osteoclasts. The sister incretin of GIP, glucagon-like peptide-1 (GLP-1), is also suspected to directly influence bone health in a beneficial manner, although mechanism are less clear at present. The physiological actions of incretins are attenuated by dipeptidyl peptidase (DPP-4) activity and it is speculated that introduction of DPP-4 inhibitor may also positively affect quality of the skeleton. As such, this thesis evaluates the potential beneficial effects of a DPP-4 resistant GIP analogue, namely [D-Ala2 ]GIP, on osteoblastic-derived, SaOS-2 cells, and also preliminary in vivo studies on the impact of genetic deficiencies of GIPRs and GLP-1Rs on bone mineral density and content. Further studies characterised the beneficial effects of incretin-based therapies on metabolic control, bone microstructure and bone mechanical integrity in animal models of pharmacologically-, genetically- and environmentally-induced diabetes. GIP and related stable analogue increased bone-forming biomarkers in SaOS-2 cells and importantly, [D-Ala2 ]GIP was shown to be more potent than native GIP. Knockout mouse studies revealed that both GIPR and GLP-1R signaling are important for optimum bone mass. All diabetic mouse models displayed reduced bone mass, altered bone micromorphology and impairment of bone mechanical strength, similar to the human situation, confirming their appropriateness. The incretin-based therapeutics, [D-Ala2 ]GIP and Liraglutide, in streptozotocin-diabetic significantly increased bone matrix properties, indicating recovery of bone strength at the tissue level. The beneficial effects of administration of [D-Ala2 ]GIP�oxyntomodulin on bone health in db/db mice were more prominent as the Oxm analogue did not only improve bone strength at tissue level, but also at whole-bone level. These modifications were independent of metabolic status. Twice-daily Exendin-4 therapy improved glycaemic control and increased work required to resist bone fracture in high-fat fed mice. It was also established that Sitagliptin had neutral effects on bone microstructure and mechanical strength in high-fat mice. In summary, these data demonstrate the negative impact of diabetes mellitus on normal skeleton development and bone quality. Moreover, this thesis highlights the growing potential of incretin-based therapies for ameliorating bone defects and improving the increased fragility fracture risk associated with diabete

Seismic strengthening of beam-column joints with multidirectional CFRP laminates

An experimental program was carried out to analyse the potentialities of a technique based on the use of multidirectional CFRP laminates (MDL-CFRP) for the seismic repair and strengthening of reinforced concrete (RC) beam-column joints. This experimental program comprises cyclic tests on three full-scale RC joints, representative of interior beam-column connections in buildings. The joints were initially submitted to a cyclic test inducing a damage pattern representative of a seismic event. Subsequently, they were repaired and strengthened with MDL-CFRP. The strengthened joints were then tested for the same loading history of the original ones up to their failure. The adopted strengthening technique uses the MDL-CFRP that are simultaneously glued and anchored to the concrete surfaces. This technique is called Mechanically Fastened and Externally Bonded Reinforcement (MF-EBR). In the present study, the effectiveness of two different strengthening configurations was investigated. The tests are described and the main results are presented and analyzed

Abrasive water jet drilling of advanced sustainable bio-fibre-reinforced polymer/hybrid composites : a comprehensive analysis of machining-induced damage responses

This paper aims at investigating the effects of variable traverse speeds on machining-induced damage of fibre-reinforced composites, using the abrasive water jet (AWJ) drilling. Three different types of epoxy-based composites laminates fabricated by vacuum bagging technique containing unidirectional (UD) flax, hybrid carbon-flax and carbon fibre-reinforced composite were used. The drilling parameters used were traverse speeds of 20, 40, 60 and 80 mm/min, constant water jet pressure of 300 MPa and a hole diameter of 10 mm. The results obtained depict that the traverse speed had a significant effect with respect to both surface roughness and delamination drilling-induced damage responses. Evidently, an increase in water jet traverse speed caused an increase in both damage responses of the three samples. Significantly, the CFRP composite sample recorded the lowest surface roughness damage response, followed by C-FFRP, while FFRP exhibited the highest. However, samples of FFRP and hybrid C-FFRP recorded lowest and highest delamination damage responses, respectively. The discrepancy in both damage responses, as further validated with micrographs of colour video microscopy (CVM), scanning electron microscopy (SEM) and X-ray micro-computed tomography (X-ray μCT), is attributed to the different mechanical properties of the reinforced fibres, fibre orientation/ply stacking and hybridisation of the samples.Peer reviewe

The influence of service temperature on bond between FRP reinforcement and concrete

The interest in fibre reinforced polymer (FRP) reinforcement in construction has considerably increased and especially the application of FRP as externally bonded reinforcement (FRP EBR) has become more and more established. The use of FRP EBR has been adopted world-wide as a very attractive technique for structural strengthening and rehabilitation. At Ghent university, the fire behaviour of slabs and beams strengthened with advanced composites, including the use of fire protection systems, has been investigated. In addition, the behaviour of the FRP-concrete interface at increased temperatures has been considered, as elevated temperatures may occur during service conditions, especially for outdoor applications. According to fib Bulletin 14, the glass transition temperature of the adhesive used to bond the FRP should equal 20°C in excess of the maximum ambient temperature at normal service conditions, and should be at least 45°C. When reaching the glass transition temperature, the properties of the adhesive decrease to a large extend and bond interaction between the concrete and the external FRP reinforcement may be completely lost. To study the bond behaviour at elevated temperatures, a joint test program between the Universities of Ghent and Lecce has been executed, comprising a series of 20 bond tests performed at the Magnel Laboratory for Concrete Research. The present paper will discuss the experimental work and the main test results obtained

Shock adhesion test for composite bonded assembly using a high pulsed power generator

In a context of the rising use of composite assemblies in aeronautic or defense fields, the assessment of their strength is a key issue. The method developed in this study attempts to provide solutions. A shock adhesion test based on short compressive loads, obtained by a high pulsed power generator, is proposed as a proof test to ensure the quality of composite bonded assemblies. A calibrated load induces a local tensile stress able to damage the bond interface. The high pulsed power source is the GEnerateur de Pression Isentropique device (Isentropic Pressure Generator), used to generate the required stresses, with a 450 ns pulse duration to test assemblies above the mm thickness range. The understanding of the mechanisms of wave propagation and tensile stress generation within these multilayer assemblies are scientific challenges. The ability of the technique to induce a tensile stress able to disbond the laminates and the assemblies is demonstrated. This paper details the response of carbon epoxy laminates and their bonded assemblies to a shock loading near the damage threshold