Bedrock and soil geochemistry influence the content of chemical elements in wild edible mushrooms (Morchella group) from South Italy (Sicily)

Chemical elements in the samples of wild edible mushrooms of the Morchellagroup collected from different unpolluted Sicilian sites was analyzed by the ICP-MS (method) to detect the content of their minerals and determine whether soil geology and geochemistry can influence the chemical composition in fungi. Results showed that the mushroom samples mainly contained a high concentration of K and P and a wide variety of minor and trace elements (V, Mo, Pb, Ce, Cs, Zr), including heavy metals. Statistical analysis showed that the mushrooms differed in their content of minor and trace elements based on the geological/geographic site of origin. Comparison with other studies showed differences in the content detected in the Sicilian morels with those collected from other geographical sites. Conversely, dif-ferent fungal species collected from similar geological sites in Sicily showed different patterns of accumulation of the elements confirming that bioconcentration in fungi is species- and site-dependent

Evidence for Miocene subduction beneath the Alboran Sea (Western Mediterranean) from 40Ar/39Ar age dating and the geochemistry of volcanic rocks from holes 977A and 978A

Volcanic pebbles in gravels from Sites 977 and 978 in the Alboran Sea (western Mediterranean) were dated (using the 40Ar/ 39Ar single-crystal laser technique) and analyzed for their major- and trace-element compositions (determined by X-ray fluorescence and inductively coupled plasma-mass spectrometry). The samples range from basalts to rhyolites, and belong to the tholeiitic, calc-alkaline, and shoshonitic series. Single-crystal and step-heating laser 40Ar/39Ar analyses of plagioclase, sanidine, biotite, and amphibole phenocrysts from basaltic to rhyolitic samples indicate that eruptions occurred between 6.1 and 12.1 Ma. The age data conform to the stratigraphy and agree with microfossil ages, when available. The major-element and compatible trace-element data of samples with H2O < 4 wt% show systematic variations, consistent with fractionation of the observed phenocryst phases (plagioclase, olivine, clinopyroxene, magnetite, hornblende, quartz, and biotite). The incompatible-element patterns formed by normalizing to primitive mantle for all samples show spiked patterns with peaks generally at mobile elements and troughs at immobile elements, in particular Nb and Ta. The calc-alkaline affinities and the incompatible-element systematics are characteristic of subduction zone volcanism, which indicates that subduction occurred beneath the eastern Alboran from 6 to at least 12 Ma. We propose that the change in chemistry from calc-alkaline and potassic to sodic compositions between 5– 6 Ma reflects detachment of the subducting slab. Uplift of the Strait of Gibraltar, associated with this detachment, could have caused the Messinian Salinity Crises

Ultramafic xenoliths from the Bearpaw Mountains, Montana, USA: evidence for multiple metasomatic events in the lithospheric mantle beneath the Wyoming craton

Ultramafic xenoliths in Eocene minettes of the Bearpaw Mountains volcanic field (Montana, USA), derived from the lower lithosphere of the Wyoming craton, can be divided based on textural criteria into tectonite and cumulate groups. The tectonites consist of strongly depleted spinel lherzolites, harzburgites and dunites. Although their mineralogical compositions are generally similar to those of spinel peridotites in off-craton settings, some contain pyroxenes and spinels that have unusually low Al2O3 contents more akin to those found in cratonic spinel peridotites. Furthermore, the tectonite peridotites have whole-rock major element compositions that tend to be significantly more depleted than non-cratonic mantle spinel peridotites (high MgO, low CaO, Al2O3 and TiO2) and resemble those of cratonic mantle. These compositions could have been generated by up to 30% partial melting of an undepleted mantle source. Petrographic evidence suggests that the mantle beneath the Wyoming craton was re-enriched in three ways: (1) by silicate melts that formed mica websterite and clinopyroxenite veins; (2) by growth of phlogopite from K-rich hydrous fluids; (3) by interaction with aqueous fluids to form orthopyroxene porphyroblasts and orthopyroxenite veins. In contrast to their depleted major element compositions, the tectonite peridotites are mostly light rare earth element (LREE)-enriched and show enrichment in fluid-mobile elements such as Cs, Rb, U and Pb on mantle-normalized diagrams. Lack of enrichment in high field strength elements (HFSE; e.g. Nb, Ta, Zr and Hf) suggests that the tectonite peridotites have been metasomatized by a subduction-related fluid. Clinopyroxenes from the tectonite peridotites have distinct U-shaped REE patterns with strong LREE enrichment. They have 143Nd/144Nd values that range from 0·5121 (close to the host minette values) to 0·5107, similar to those of xenoliths from the nearby Highwood Mountains. Foliated mica websterites also have low 143Nd/144Nd values (0·5113) and extremely high 87Sr/86Sr ratios in their constituent phlogopite, indicating an ancient (probably mid-Proterozoic) enrichment. This enriched mantle lithosphere later contributed to the formation of the high-K Eocene host magmas. The cumulate group ranges from clinopyroxene-rich mica peridotites (including abundant mica wehrlites) to mica clinopyroxenites. Most contain >30% phlogopite. Their mineral compositions are similar to those of phenocrysts in the host minettes. Their whole-rock compositions are generally poorer in MgO but richer in incompatible trace elements than those of the tectonite peridotites. Whole-rock trace element patterns are enriched in large ion lithophile elements (LILE; Rb, Cs, U and Pb) and depleted in HFSE (Nb, Ta Zr and Hf) as in the host minettes, and their Sr–Nd isotopic compositions are also identical to those of the minettes. Their clinopyroxenes are LREE-enriched and formed in equilibrium with a LREE-enriched melt closely resembling the minettes. The cumulates therefore represent a much younger magmatic event, related to crystallization at mantle depths of minette magmas in Eocene times, that caused further metasomatic enrichment of the lithosphere

The power of being positive: Robust state estimation made possible by quantum mechanics

We study the problem of quantum-state tomography under the assumption that the state of the system is close to pure. In this context, an efficient measurements that one typically formulates uniquely identify a pure state from within the set of other pure states. In general such measurements are not robust in the presence of measurement noise and other imperfections, and therefore are less practical for tomography. We argue here that state tomography experiments should instead be done using measurements that can distinguish a pure state from {\em any} other quantum state, of any rank. We show that such nontrivial measurements follows from the physical constraint that the density matrix is positive semidefinite and prove that these measurements yield a robust estimation of the state. We assert that one can implement such tomography relatively simply by measuring only a few random orthonormal bases; our conjecture is supported by numerical evidence. These results are generalized for estimation of states close to bounded-rank.Comment: 6 pages, 2 figures. This submission was combined with arXiv:1510.02736 to produce arXiv:1605.02109, which is published in Phys. Rev.

New electromagnetic conservation laws

The Chevreton superenergy tensor was introduced in 1964 as a counterpart, for electromagnetic fields, of the well-known Bel-Robinson tensor of the gravitational field. We here prove the unnoticed facts that, in the absence of electromagnetic currents, Chevreton's tensor (i) is completely symmetric, and (ii) has a trace-free divergence if Einstein-Maxwell equations hold. It follows that the trace of the Chevreton tensor is a rank-2, symmetric, trace-free, {\em conserved} tensor, which is different from the energy-momentum tensor, and nonetheless can be constructed for any test Maxwell field, or any Einstein-Maxwell spacetime.Comment: 6 page

On the hadron mass decomposition

We argue that the standard decompositions of the hadron mass overlook pressure effects, and hence should be interpreted with great care. Based on the semiclassical picture, we propose a new decomposition that properly accounts for these pressure effects. Because of Lorentz covariance, we stress that the hadron mass decomposition automatically comes along with a stability constraint, which we discuss for the first time. We show also that if a hadron is seen as made of quarks and gluons, one cannot decompose its mass into more than two contributions without running into trouble with the consistency of the physical interpretation. In particular, the so-called quark mass and trace anomaly contributions appear to be purely conventional. Based on the current phenomenological values, we find that in average quarks exert a repulsive force inside nucleons, balanced exactly by the gluon attractive force.Comment: 21 pages, 4 figure

Primary crustal melt compositions: Insights into the controls, mechanisms and timing of generation from kinetics experiments and melt inclusions

We explore the controls, mechanisms and timing of generation of primary melts and their compositions, and show that the novel studies of melt inclusions in migmatites can provide important insights into the processes of crustal anatexis of a particular rock. Partial melting in the source region of granites is dependent on five main processes: (i) supply of heat; (ii) mineral–melt interface reactions associated with the detachment and supply of mineral components to the melt, (iii) diffusion in the melt, (iv) diffusion in minerals, and (v) recrystallization of minerals. As the kinetics of these several processes vary over several orders of magnitude, it is essential to evaluate in Nature which of these processes control the rate of melting, the composition of melts, and the extent to which residue–melt chemical equilibrium is attained under different circumstances. To shed light on these issues, we combine data from experimental and melt inclusion studies. First, data from an extensive experimental program on the kinetics of melting of crustal protoliths and diffusion in granite melt are used to set up the necessary framework that describes how primary melt compositions are established during crustal anatexis. Then, we use this reference frame and compare compositional trends from experiments with the composition of melt inclusions analyzed in particular migmatites. We show that, for the case of El Hoyazo anatectic enclaves in lavas, the composition of glassy melt inclusions provides important information on the nature and mechanisms of anatexis during the prograde suprasolidus history of these rocks, including melting temperatures and reactions, and extent of melt interconnection, melt homogenization and melt–residue equilibrium. Compositional trends in several of the rehomogenized melt inclusions in garnet from migmatites/granulites in anatectic terranes are consistent with diffusion in melt-controlled melting, though trace element compositions of melt inclusions and coexisting minerals are necessary to provide further clues on the nature of anatexis in these particular rocks.This work was supported by the National Science Foundation [grants EAR-9603199, EAR-9618867, EAR-9625517 and EAR-9404658], the Italian Consiglio Nazionale delle Ricerche, the European Commission (grant 01-LECEMA22F through contract No. ERAS-CT-2003-980409; and a H2020 Marie Skłodowska-Curie Actions under grant agreement No. 654606), the Italian Ministry of Education, University and Research (grants PRIN 2007278A22, 2010TT22SC and SIR RBSI14Y7PF), the Università degli Studi di Padova [Progetto di Ateneo CPDA107188/10 and a Piscopia—Marie Curie Fellowship under grant agreement No. 600376], the Australian Research Council (Australian Professorial Fellowship and Discovery Grants Nos. DP0342473 and DP0556700), and the National Research Foundation (South Africa; Incentives For Rated Researchers Program)

Electronic tuneability of a structurally rigid surface intermetallic and Kondo lattice: CePt5_5 / Pt(111)

We present an extensive study of structure, composition, electronic and magnetic properties of Ce--Pt surface intermetallic phases on Pt(111) as a function of their thickness. The sequence of structural phases appearing in low energy electron diffraction (LEED) may invariably be attributed to a single underlying intermetallic atomic lattice. Findings from both microscopic and spectroscopic methods, respectively, prove compatible with CePt$_5$ formation when their characteristic probing depth is adequately taken into account. The intermetallic film thickness serves as an effective tuning parameter which brings about characteristic variations of the Cerium valence and related properties. Soft x-ray absorption (XAS) and magnetic circular dichroism (XMCD) prove well suited to trace the changing Ce valence and to assess relevant aspects of Kondo physics in the CePt$_5$ surface intermetallic. We find characteristic Kondo scales of the order of 10$^2$ K and evidence for considerable magnetic Kondo screening of the local Ce $4f$ moments. CePt$_5$/Pt(111) and related systems therefore appear to be promising candidates for further studies of low-dimensional Kondo lattices at surfaces.Comment: 14 pages, 11 figure

Crosscutting, what is and what is not? A Formal definition based on a Crosscutting Pattern

Crosscutting is usually described in terms of scattering and tangling. However, the distinction between these concepts is vague, which could lead to ambiguous statements. Sometimes, precise definitions are required, e.g. for the formal identification of crosscutting concerns. We propose a conceptual framework for formalizing these concepts based on a crosscutting pattern that shows the mapping between elements at two levels, e.g. concerns and representations of concerns. The definitions of the concepts are formalized in terms of linear algebra, and visualized with matrices and matrix operations. In this way, crosscutting can be clearly distinguished from scattering and tangling. Using linear algebra, we demonstrate that our definition generalizes other definitions of crosscutting as described by Masuhara & Kiczales [21] and Tonella and Ceccato [28]. The framework can be applied across several refinement levels assuring traceability of crosscutting concerns. Usability of the framework is illustrated by means of applying it to several areas such as change impact analysis, identification of crosscutting at early phases of software development and in the area of model driven software development