Three-coordinate iron(II) expanded ring N-heterocyclic carbene complexes

A sterically demanding seven-membered expanded ring N-heterocyclic carbene (NHC) ligand allows access to rare examples of three-coordinate iron(II)-NHC complexes incorporating only halide coligands of the general formula [Fe(NHC)X 2 ] (NHC = 7-DiPP; X = Br (1) Cl (2)). Reducing the steric influence of the ancillary NHC ligand through modulation of the N-aryl substituents leads to either four- or three-coordinate complexes of the general formula [Fe(NHC)Br 2 (THF)] (3) or [Fe(NHC)Br 2 ] (4) (NHC = 7-Mes), dependent upon the solvent of recrystallization. The further reduction of NHC steric influence results in four-coordinate geometries at iron in the form of the dimeric species [Fe(NHC)Br(μ-Br)] 2 (5) or [Fe(NHC)Br 2 (THF)] (6) (NHC = SDiPP), again dependent upon the solvent of recrystallization. Compounds 1-6 have been analyzed by 1 H NMR spectroscopy, X-ray crystallography, elemental microanalysis, Mössbauer spectroscopy (for 1 and 3-5), and Evans method magnetic susceptibility. In addition to these measurements the three-coordinate species 1 and 4 have been further analyzed by SQUID magnetometry and CASSCF calculations, which show significant magnetic anisotropy that is extremely sensitive to the coordination geometry

Spectral characteristics for a spherically confined -1/r + br^2 potential

We consider the analytical properties of the eigenspectrum generated by a class of central potentials given by V(r) = -a/r + br^2, b>0. In particular, scaling, monotonicity, and energy bounds are discussed. The potential $V(r)$ is considered both in all space, and under the condition of spherical confinement inside an impenetrable spherical boundary of radius R. With the aid of the asymptotic iteration method, several exact analytic results are obtained which exhibit the parametric dependence of energy on a, b, and R, under certain constraints. More general spectral characteristics are identified by use of a combination of analytical properties and accurate numerical calculations of the energies, obtained by both the generalized pseudo-spectral method, and the asymptotic iteration method. The experimental significance of the results for both the free and confined potential V(r) cases are discussed.Comment: 16 pages, 4 figure

Physical Structure of Small Wolf-Rayet Ring Nebulae

We have selected the seven most well-defined WR ring nebulae in the LMC (Br 2, Br 10, Br 13, Br 40a, Br 48, Br 52, and Br 100) to study their physical nature and evolutionary stages. New CCD imaging and echelle observations have been obtained for five of these nebulae; previous photographic imaging and echelle observations are available for the remaining two nebulae. Using the nebular dynamics and abundances, we find that the Br 13 nebula is a circumstellar bubble, and that the Br 2 nebula may represent a circumstellar bubble merging with a fossil main-sequence interstellar bubble. The nebulae around Br 10, Br 52, and Br 100 all show influence of the ambient interstellar medium. Their regular expansion patterns suggest that they still contain significant amounts of circumstellar material. Their nebular abundances would be extremely interesting, as their central stars are WC5 and WN3-4 stars whose nebular abundances have not been derived previously. Intriguing and tantalizing implications are obtained from comparisons of the LMC WR ring nebulae with ring nebulae around Galactic WR stars, Galactic LBVs, LMC LBVs, and LMC BSGs; however, these implications may be limited by small-number statistics. A SNR candidate close to Br 2 is diagnosed by its large expansion velocity and nonthermal radio emission. There is no indication that Br 2's ring nebula interacts dynamically with this SNR candidate.Comment: 20 pages, Latex (aaspp4.sty), 2 figures, accepted by the Astronomical Journal (March 99 issue