Comparison of organic packing materials for toluene biofiltration

he paper focuses on the operation of a pilot plant with four biofilters operated in parallel for determining the suitability of coconut fiber, peat, compost from the digested sludge of a wastewater treatment plant and pine leaves as packing materials for biofiltration of toluene. Physical characteristics of packing materials such as specific surface area, density, pore size and elemental composition were determined for each packing material. Biological activity and packing capabilities related to toluene removal were determined during the startup and operation of the four biofilters under different conditions of nutrients, watering and inlet air relative humidity supply. Nutrient addition was key in improving removal efficiency (RE) and elimination capacity (EC) of biofilters. Feeding of medium with nutrients increased the RE and the EC by a factor of 2 to 4 than these found when supplying only tap water. Additionally, when extra nitrogen was supplied in the medium, RE and EC increased by a factor of 2. Nutrient addition also lead to a microbial population change from bacterial to fungal biofilters. It was denoted that watering control is necessary to improve fungal biofilters performance in terms of ensuring a proper washout of acidic by-products to avoid fungi inhibition and consequent lowered removal capacities.Peer ReviewedPostprint (published version

Eficiencia de absorción de nutrientes de Gracilaria chilensis y Ulva lactuca en un sistema multitrófico integrado con el abalón rojo Haliotis rufescens

Indexación: Web of Science; Scielo.ABSTRACT. The current study examined the nutrient uptake efficiency of Ulva lactuca and Gracilaria chilensis cultivated in tanks associated with the wastewater of a land-based abalone culture. The experiments evaluated different seaweed stocking densities (1200, 1900, 2600, and 3200 g m-2) and water exchange rates (60, 80, 125, and 250 L h-1). The results show that both U. lactuca and G. chilensis were efficient in capturing and removing all of the inorganic nutrients originating from the abalone cultivation for all of the tested conditions. Furthermore, an annual experiment was performed with U. lactuca, cultivated at a stocking density of 1900 g m-2 and at a water exchanged rate of 125 L h-1, in order to evaluate seasonal changes in the nutrient uptake efficiency, productivity, and growth rate associated with the wastewater of a land-based abalone culture. The results confirmed high uptake efficiency during the entire year, equivalent to a 100% removal of the NH4, NO3, and PO4 produced by the land-based abalone culture. The growth rate and productivity of U. lactuca presented a marked seasonality, increasing from fall until summer and varying from 0.5 ± 0.2% to 2.6 ± 0.2% d-1 and 10 ± 6.1% to 73.6 ± 8.4% g m-2 d-1 for sustainable growth rate and productivity, respectively. We conclude that there is sufficient evidence that demonstrates the high possibility of changing the traditional monoculture system of abalone in Chile, to a sustainable integrated multi-trophic aquaculture system, generating positive environmental externalities, including the use of U. lactuca as a biofiltration unit.Resumen: Se analizó la eficiencia de captación de nutrientes de Ulva lactuca y Gracilaria chilensis, cultivadas en estanques asociados a aguas de desecho proveniente de un cultivo del abalón rojo Haliotis rufescens. Los experimentos consideraron evaluar diferentes densidades de cultivo de algas (1200, 1900, 2600 and 3200 g m-2) y tasas de recambio de agua (60, 80, 125 y 250 L h-1). Los resultados mostraron que tanto U. lactuca como G. chilensis fueron eficientes en la captación de nutrientes inorgánicos provenientes del cultivo de abalón, en todas las condiciones probadas, con remoción total de los nutrientes aportados por el cultivo. De la misma forma se realizó un experimento anual con U. lactuca, siendo cultivada con densidad de 1900 g m-2 y tasa de recambio de agua de 125 L h-1 para evaluar cambios estacionales en la eficiencia de captación de nutrientes, así como en la productividad y tasa de crecimiento de U. lactuca. Los resultados confirmaron una alta eficiencia de captación de U. lactuca durante todo el año, equivalente a la remoción del 100% del NH4, NO3 y PO4 aportado por el cultivo de abalón. La tasa de crecimiento y la productividad de U. lactuca presentó una marcada estacionalidad, incrementando de otoño al verano, variando de 0,5 ± 0,2 a 2,6 ± 0,2% d-1 y 10 ± 6,1 a 73,6 ± 8,4 g m-2 d-1, respectivamente. Se concluye que existen antecedentes suficientes que demuestran que es altamente posible cambiar la actividad tradicional de cultivo de abalón por un sistema integrado multitrófico, alcanzando externalidades ambientales positivas que incluyen U. lactuca como unidad de biofiltración.http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-560X201400030001

CFD modeling of a fixed-bed biofilm reactor coupling hydrodynamics and biokinetics

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Conversion of chemical scrubbers to biotrickling filters for VOCs and H2S treatment at low contact times

The purpose of this work was to evaluate the technical and economical feasibility of converting three chemical scrubbers in series to biotrickling filters (BTFs) for the simultaneous removal of H2S and volatile organic compounds (VOCs). The conversion of the full-scale scrubbers was based on previous conversion protocols. Conversion mainly required replacing the original carrier material and recycle pumps as well as modifying the controls and operation of the reactors. Complete removal of H2S and VOCs on a routine basis was reached at neutral pH in a longer period of time compared to previous conversions reported. Biotrickling filters operated at a gas contact time of about 1.4 s per reactor and at pH controlled between 6.5 and 6.8. Inlet average concentrations below 10 ppmv of H2S and below 5 ppmv for VOCs were often completely removed. The first and second bioreactors played a primary role in H2S removal. Year-round operation of the biotrickling filters proved the ability of the system to handle progressive load increases of H2S and VOCs. However, fast, sudden load changes often lead to reduced removal efficiencies. Odor analyses showed average removal efficiencies above 80 %. Gas chromatography-mass spectrometry of selected samples showed that outlet odor concentration was due to limited removal of VOCs. The conversion showed was economically viable taking into account the theoretical consumption of chemicals needed for the absorption and oxidation of both H2S and VOCs.Peer ReviewedPostprint (published version

Distribution of heavy metals in vegetative biofiltration columns

This study investigated the distribution of heavy metals in vegetative biofiltration columns irrigated by synthetic greywater. Twelve species of ornamental plants (three plants from each species) were planted in the same designed 36 biofiltration columns. Samples of effluent water, soils, roots, shoots and leaves were collected and analyzed. It was observed that before irrigation, the distribution of copper was in soils (0%), roots (42%), leaves (37%) and shoots (21%). After irrigation, this distribution changed to soils (29%), roots (39%), leaves (17%) and shoots (15%). It was found that lead concentrations decreased in soils from (84% to 7%), but increased in plants (from 16% to 93%) following irrigation with greywater. In contrast, the distribution of zinc changed from leaves (46%), roots (22%) and soils (16%) before irrigation to 89% in leaves and soils and 11% in shoots following irrigation. The chromium distribution before and after irrigation was found to be almost unchanged in soils, shoots and effluent water, but it increased in roots (19.4% to 26.9%) and decreased in leaves (11.4% to 5.8%). The outcomes of this study demonstrated that heavy metals mostly accumulate in soils and roots, and it is necessary to investigate their potential detrimental effects on the receiving environment

Assessing Biofiltration without Ozonation for Removal of Trihalomethane Precursors in Drinking Water at the Beaver Water District Drinking Water Treatment Plant

Biofiltration without pre-ozonation has the capability to remove natural organic matter (NOM) fractions that serve as precursors of disinfection byproducts (DBPs), which include the four regulated trihalomethanes (THMs) and dichloroacetonitrile (DCAN). Rapid small-scale column tests (RSSCTs) and Pilot Plant filters operated at empty-bed contact times (EBCTs) of 4, 8, and 16 minutes were used to evaluate the performance of nutrient-amended (free ammonia and phosphorus) biofiltration for THM and DCAN precursor removal, as measured using formation potential (FP) tests. NOM surrogates – which include dissolved organic carbon (DOC), specific ultraviolet absorbance (SUVA254) and fluorescence-PARAFAC components – were measured weekly throughout the 30-week study to assess their suitability to track DBP precursor removal. RSSCTs containing DOC-exhausted granular activated carbon (GAC) removed up to 25% of the DOC with removal increasing (=0.01) with EBCT between 4 and 16 mins. During the 11-week period of active nitrification in the RSSCTs, average removals of total THMFP and DCANFP were 21% and 44%, respectively. However, statistically similar removals (=0.01) were observed at 8 and 16 mins EBCT, indicating that EBCTs in excess of 8 mins would not be helpful unless additional pretreatment steps such as pre-ozonation or a higher chlorine dioxide dose were added prior to the biofilters to increase the amount of biodegradable NOM. Relative to the RSSCTs, the Pilot filters achieved higher average removals of DOC, SUVA254, TTHMFP and DCANFP because their GAC media was not exhausted with respect to DOC and thus NOM was sorbed by physical-chemical mechanisms. Weak linear correlations observed between NOM surrogates and TTHMFP (R2 \u3c 0.27) during the active nitrification period in the RSSCTs indicate that these surrogates are not useful for monitoring THM precursor removal in nutrient-enhanced biofilters and therefore DBPFP tests are required to assess biofiltration performance

A comparative study of the characteristics and physical behaviour of different packing materials commonly used in biofiltration

In this study, the characteristics and physical behaviour of 8 different packing materials were compared. The materials were selected according to previous works in the field of biofiltration including organic and inorganic or synthetic materials. Results pre-selected those more acceptable support materials for the main function they have to perform in the biological system: high surface contact, rugosity to immobilize the biomass, low pressure drop, nutrients supply, water retentivity or a commitment among them. Otherwise, pressure drop have been described by means of the respective mathematic expressions in order to include phenomena in the classical biofiltration models.Peer ReviewedPostprint (author's final draft

Evaluation on Biofilter in Recirculating Integrated Multi-Trophic Aquaculture

Integrated multi-trophic aquaculture pays more attention as a bio-integrated food production system that serves as a model of sustainable aquaculture, minimizes waste discharge, increases diversity and yields multiple products. The objectives of this research were to analyze the efficiency of total ammonia nitrogen biofiltration and its effect on carrying capacity of fish rearing units. Pilot-scale bioreactor was designed with eight run-raceways (two meters of each) that assembled in series. Race 1-3 were used to stock silky worm (Tubifex sp) as detrivorous converter, then race 4-8 were used to plant three species of leaf-vegetable as photoautotrophic converters, i.e; spinach (Ipomoea reptana), green mustard (Brassica juncea) and basil (Ocimum basilicum). The three plants were placed in randomized block design based on water flow direction. Mass balance of nutrient analysis, was applied to figure out the efficiency of bio-filtration and its effect on carrying capacity of rearing units. The result of the experiment showed that 86.5 % of total ammonia nitrogen removal was achieved in 32 days of culturing period. This efficiency able to support the carrying capacity of the fish tank up to 25.95 kg/lpm with maximum density was 62.69 kg/m3 of fish biomass productio