Non-metallic brush seals for gas turbine bearings

A non-metallic brush seal has been developed as an oil seal for use in turbomachinary. Traditionally labyrinth-type seals with larger clearances have been used in such applications. Labyrinth seals have higher leakage rates and can undergo excessive wear in case of rotor instability. Brush seals reduce leakage by up to an order of magnitude and provide compliance against rotor instabilities. Brush seals are compact and are much less prone to degradation associated with oil sealing. This paper describes the benefits and development of the nonmetallic brush seals for oil sealing application

Factors Influencing Reinforcement of NR and EPDM Rubbers with Short Aramid Fibers

Among short fiber reinforced composites, those with rubbery matrices have gained great importance due to the advantages they have in processing and low cost, coupled with high strength. These composites combine the elastic behavior of rubbers with strength and stiffness of fibers. Reinforcement with short fibers offers additional features such as design flexibility, high modulus, tear strength, etc. The degree of reinforcement depends on parameters such as: the nature of the rubber matrix, the type of fibers, the concentration and orientation of fibers, fiber to rubber adhesion (generation of a strong interface), fiber length and aspect ratio of the fibers. In this research aramid fibers have been chosen because of their significantly higher modulus and strength, compared to other commercial fibers. Compounds based on NR and EPDM are prepared. Short aramid fibers with different kinds of surface treatments, standard finish and RFL-coating result in different rubber-fiber interfaces. The reinforcing effect of these short aramid fibers is characterized by mechanical and viscoelastic experiments, and by studying the fracture surfaces with microscopic techniques

Hazards protection for space suits and spacecraft

A flexible multi-layered covering article for protection against the hazards of exposure to the environment of outer space is disclosed. The covering includes an outer layer section comprising an outermost lamina of woven expanded tetrafluoroethylene yarns (Gore Tex) for protecting against abrasion and tearing, an underlying weave of meta-aramid yarns (Nomex) and para-aramid yarns (Kevlar) for particle impart protection, and electrostatic charge dissipation and control system incorporated therein, and a chemical contaminants control barrier applied as a coating. A middle section includes a succession of thermal insulating layers of polymeric thermoplastic or thermoforming material, each of which is coated with a metal deposit of high infra-red emissivity and low solar radiation absorption characteristics and separated from adjacent insulating layers by a low thermal conductance material. The covering further includes a radiation attenuating layer of a tungsten-loaded polymeric elastomer binder for protecting against bremsstrahlung radiation and an inner layer of rip-stop polyester material for abrasion protection. A chloroprene coating may be supplied the polyester-material for added micrometeroid protection. Securing means of low heat conductance material secures the multi-layers together as a laminar composite

Extrapancreatic actions of incretin-based therapies on bone in diabetes mellitus

Diabetes mellitus is correlated with modifications in bone microarchitectural and mechanical strength, leading to increased bone fragility. The incretin hormones, with a classical effect to increase insulin secretion following food ingestion, are now postulated to have important direct effects on bone. As such, glucose-dependent insulinotropic polypeptide (GIP) has dual actions on bone cells; enhancing bone�forming activity of osteoblasts and suppressing bone resorption by osteoclasts. The sister incretin of GIP, glucagon-like peptide-1 (GLP-1), is also suspected to directly influence bone health in a beneficial manner, although mechanism are less clear at present. The physiological actions of incretins are attenuated by dipeptidyl peptidase (DPP-4) activity and it is speculated that introduction of DPP-4 inhibitor may also positively affect quality of the skeleton. As such, this thesis evaluates the potential beneficial effects of a DPP-4 resistant GIP analogue, namely [D-Ala2 ]GIP, on osteoblastic-derived, SaOS-2 cells, and also preliminary in vivo studies on the impact of genetic deficiencies of GIPRs and GLP-1Rs on bone mineral density and content. Further studies characterised the beneficial effects of incretin-based therapies on metabolic control, bone microstructure and bone mechanical integrity in animal models of pharmacologically-, genetically- and environmentally-induced diabetes. GIP and related stable analogue increased bone-forming biomarkers in SaOS-2 cells and importantly, [D-Ala2 ]GIP was shown to be more potent than native GIP. Knockout mouse studies revealed that both GIPR and GLP-1R signaling are important for optimum bone mass. All diabetic mouse models displayed reduced bone mass, altered bone micromorphology and impairment of bone mechanical strength, similar to the human situation, confirming their appropriateness. The incretin-based therapeutics, [D-Ala2 ]GIP and Liraglutide, in streptozotocin-diabetic significantly increased bone matrix properties, indicating recovery of bone strength at the tissue level. The beneficial effects of administration of [D-Ala2 ]GIP�oxyntomodulin on bone health in db/db mice were more prominent as the Oxm analogue did not only improve bone strength at tissue level, but also at whole-bone level. These modifications were independent of metabolic status. Twice-daily Exendin-4 therapy improved glycaemic control and increased work required to resist bone fracture in high-fat fed mice. It was also established that Sitagliptin had neutral effects on bone microstructure and mechanical strength in high-fat mice. In summary, these data demonstrate the negative impact of diabetes mellitus on normal skeleton development and bone quality. Moreover, this thesis highlights the growing potential of incretin-based therapies for ameliorating bone defects and improving the increased fragility fracture risk associated with diabete

Tests for Trends in Binary Response

Tests for trend in binary response are especially important when analyzing animal experiments where the response in various dose--groups is of interest. Among the nonparametric tests the approach of Cochran and Armitage is the one which is most commonly used. This test (CA-test) is actually a test for a linear trend. The result of this test is highly dependent on the quantification of the dose. Varying score assignments can lead to totally different results. As an alternative isotonic regression is proposed. The result of this approach is independent of any monotonic transformation of the dose. The p--value related with the isotonic regression can be obtained either from considering all possible combinations of the total number of events in the dose--groups or by analyzing a random sample of all permutations. Both tests are compared within a simulation--study and on data from an experiment considering whether a certain type of fibre, para--aramid, is carcinogenic. The result of the commonly used CA--test is highly dependent on the event rate in the lowest and highest dose--group. Based on our analyses we recommend to use the isotonic regression instead of the test proposed by Cochran and Armitage

PBO Fibres: from saliling design towards architectural performance

p. 3013-3023PBO fibres, also called "high-performance" polymer fibres, are a group of materials known as "rigid rods". Through this work it is pretended to make some considerations about the use of these new generation fibres. Poly (p-phenylene-2.6-benzobisoxazole)(PBO) is rigid-rod isotropic crystal polymer. PBO fibre is a high performance fibre developed by TOYOBO (Japan) PBO fibre is quite flexible and has very soft handling, in spite of its extremely high mechanical properties. Over the past ten years Future Fibres Company has pioneered the use of PBO for yacht rigging and has proven it to provide remarkable performance and longevity. Their method of producing these PBO cables delivers the lightest, smallest cables available on the market today. The PBO cable is formed by combining the incredible properties of PBO (poly(p-phenylene-2,6- benzobisoxazole)) fibre with the simple yet undeniably reliable process of continuous winding. A PBO cable is dry fibre tightly compacted and does not rely on a resin matrix that, if impacted, can be compromised. The cover of the cable is a vital component and whilst PBO is an excellent material for yacht rigging purposes, due to its extreme strength, low elongation and general robustness it must be protected from sunlight and seawater. Future Fibres has perfected its cover design that comprises a consolidating film, environmental protection layer and a customizable braided cover that can be tailored to suit any specific application. PBO has great potential to be used in construction or rehabilitation applications. At the same time the fibres, following further testing, would open up several design opportunities for high quality architectural projects.Gough, CE.; Pobo Blasco, M.; Ruiz Checa, JR. (2009). PBO Fibres: from saliling design towards architectural performance. Editorial Universitat Politècnica de València. http://hdl.handle.net/10251/670

Interfaces and interfacial effects in glass reinforced thermoplastics - Keynote Presentation

Optimization of the fibre-matrix interphase region is critical to achieving the required performance level in thermoplastic matrix composites. Due to its initial location on the fibre surface, the sizing layer is an important component in the formation and properties of the composite interphase. Consequently, any attempt to understand the science of the composite interphase must encompass an understanding of the science of sizing. In this paper the role of sizings from fibre manufacture through to performance of composite parts is reviewed. In particular the role of organosilane coupling agents and how the formation of a polysiloxane interphase is influenced by the surface properties of the fibre is examined. The influence of the sizing film former in terms of its level of interaction with the silane coupling agent is also examined. The importance of residual stresses in thermoplastic composites in the values obtained for the apparent adhesion levels in these systems is highlighted. These residual stresses are shown to play a significant role in determining the level of interfacial strength in thermoplastic composites and in particular in polyolefin matrices. By applying some of the available models for this phenomenon this analysis is extended to explore the effect of the anisotropic fibre microstructure of carbon, aramid and natural fibres on the apparent interfacial strength in thermoplastic composites

Comparison of flexural properties of aramid-reinforced pultrusions having varied matrices, pretreatments and postcures

Aramid-reinforced composite materials of equal fiber volume and varied polymer thermoset matrices were pultruded and flexurally tested to failure. The objective was to improve the flexural properties of aramid-reinforced pultrusions. Pultrusions of both sized and unsized aramid fiber with four different resin systems were compared to determine the effects of sizing compounds and postcuring on flexural strength, fiber wettability, and fiber-to-resin interface bonding. Improvements in flexural strength resulting from pretreatments with the sizing solutions used were marginal. The most significant improvements in flexural properties resulted from postcuring. Flexural strengths ranged from a low of 39,647 psi (273MPa) to a high of 80,390 psi (554 MPa), an overall increase of 103 percent. The fact that postcuring improved the flexural properties of the pultrusions of the four resin systems indicates that a full cure did not occur in any of the resin systems during the pultrusion process. The increased flexural strengths of the polyester and vinyl ester pultrusions were the most surprising. The four resin systems examined were Interplastic Corporation VE 8300 vinyl ester, Ashland Chemical Company Aropol 7430 Polyester, and Shell Chemical Company Epon 9302 and Epon 9310 epoxides

Tire Tread Reinforcement with Short Aramid Fibers

Tensile testing on short fiber reinforced composites is helping to identify the advantages and disadvantages of different rubber compound

Blade Sharpness and its Effect on the Testing of Body Armours

Factors such as edge sharpness and tip sharpness have been identified by Horsfall,1 as keyvariables in the testing of stab and slash resistant armours. This paper evaluates the influenceof blade sharpness on the mechanics of penetration and its relationship with a variety ofmaterials used for body armour systems. The differences in performance between blunt andsharp blades are compared by dynamic tests using an instrumented drop tower, measuringpeak loads and energy to penetration. Variance in the initial impact forces required topenetrate body armour between blunt and sharp blades is shown. However, the total energyto penetration for both sharp and blunt knives was found to be similar for a specific bodyarmour system. Dynamic tests were also used to evaluate the effect of wear on bladeperformance by the comparison of the initial loads for puncture and depth of penetration onaramid and metallic armour systems. The effect of sharpness on the reproducibility of testresults is also investigated and discussed. Various test methods are described for themeasurement of sharpness for both stab and slash and compared. The recent development ofa new non-destructive proof test method to measure tip and edge sharpness is also described