Freeform Fabrication of Ionomeric Polymer-Metal Composite Actuators

Ionomeric polymer-metal composite (IPMC) actuators are a type of soft electromechanically active material which offers large displacement, rapid motion with only ~1V stimulus. IPMC’s are entering commercial applications in toys (Ashley 2003) and biomedical devices (Soltanpour 2001; Shahinpoor 2002; Shahinpoor, Shahinpoor et al. 2003; Soltanpour and Shahinpoor 2003; Soltanpour and Shahinpoor 2004), but unfortunately they can only actuate by bending, limiting their utility. Freeform fabrication offers a possible means of producing IPMC with novel geometry and/or tightly integrated with mechanisms which can yield linear or more complex motion. We have developed materials and processes which allow us to freeform fabricate complete IPMC actuators and their fabrication substrate which will allow integration within other freeform fabricated devices. We have produced simple IPMC’s using our multiple material freeform fabrication system, and have demonstrated operation in air for more than 40 minutes and 256 bidirectional actuation cycles. The output stress scaled to input power is two orders of magnitude inferior to that of the best reported performance for devices produced in the traditional manner, but only slightly inferior to devices produced in a more similar manner. Possible explanations and paths to improvement are presented. Freeform fabrication of complete electroactive polymer actuators in unusual geometries, with tailored actuation behavior, and integrated with other freeform fabricated active components, will enable advances in biomedical device engineering, biologically inspired robotics, and other fields. This work constitutes the first demonstration of complete, functional, IPMC actuators produced entirely by freeform fabrication.Mechanical Engineerin

Materials science and the sensor revolution

For the past decade, we have been investigating strategies to develop ways to provide chemical sensing platforms capable of long-term deployment in remote locations1-3. This key objective has been driven by the emergence of ubiquitous digital communications and the associated potential for widely deployed wireless sensor networks (WSNs). Understandably, in these early days of WSNs, deployments have been based on very reliable sensors, such as thermistors, accelerometers, flow meters, photodetectors, and digital cameras. Biosensors and chemical sensors (bio/chemo-sensors) are largely missing from this rapidly developing field, despite the obvious value offered by an ability to measure molecular targets at multiple locations in real-time. Interestingly, while this paper is focused on the issues with respect to wide area sensing of the environment, the core challenge is essentially the same for long-term implantable bio/chemo-sensors4, i.e.; how to maintain the integrity of the analytical method at a remote, inaccessible location

Fully Integrated Biochip Platforms for Advanced Healthcare

Recent advances in microelectronics and biosensors are enabling developments of innovative biochips for advanced healthcare by providing fully integrated platforms for continuous monitoring of a large set of human disease biomarkers. Continuous monitoring of several human metabolites can be addressed by using fully integrated and minimally invasive devices located in the sub-cutis, typically in the peritoneal region. This extends the techniques of continuous monitoring of glucose currently being pursued with diabetic patients. However, several issues have to be considered in order to succeed in developing fully integrated and minimally invasive implantable devices. These innovative devices require a high-degree of integration, minimal invasive surgery, long-term biocompatibility, security and privacy in data transmission, high reliability, high reproducibility, high specificity, low detection limit and high sensitivity. Recent advances in the field have already proposed possible solutions for several of these issues. The aim of the present paper is to present a broad spectrum of recent results and to propose future directions of development in order to obtain fully implantable systems for the continuous monitoring of the human metabolism in advanced healthcare applications

Theoretical and Experimental Investigation on the Multiple Shape Memory Ionic Polymer-Metal Composite Actuator

Development of biomimetic actuators has been an essential motivation in the study of smart materials. However, few materials are capable of controlling complex twisting and bending deformations simultaneously or separately using a dynamic control system. The ionic polymer-metal composite (IPMC) is an emerging smart material in actuation and sensing applications, such as biomimetic robotics, advanced medical devices and human affinity applications. Here, we report a Multiple Shape Memory Ionic Polymer-Metal Composite (MSM-IPMC) actuator having multiple-shape memory effect, and is able to perform complex motion by two external inputs, electrical and thermal. Prior to the development of this type of actuator, this capability only could be realized with existing actuator technologies by using multiple actuators or another robotic system. Theoretical and experimental investigation on the MSM-IPMC actuator were performed. To date, the effect of the surface electrode properties change on the actuating of IPMC have not been well studied. To address this problem, we theoretically predict and experimentally investigate the dynamic electro-mechanical response of the IPMC thin-strip actuator. A model of the IPMC actuator is proposed based on the Poisson-Nernst-Planck equations for ion transport and charge dynamics in the polymer membrane, while a physical model for the change of surface resistance of the electrodes of the IPMC due to deformation is also incorporated. By incorporating these two models, a complete, dynamic, physics-based model for IPMC actuators is presented. To verify the model, IPMC samples were prepared and experiments were conducted. The results show that the theoretical model can accurately predict the actuating performance of IPMC actuators over a range of dynamic conditions. Additionally, the charge dynamics inside the polymer during the oscillation of the IPMC are presented. It is also shown that the charge at the boundary mainly affects the induced stress of the IPMC. This study is beneficial for the comprehensive understanding of the surface electrode effect on the performance of IPMC actuators. In our study, we introduce a soft MSM-IPMC actuator having multiple degrees-of-freedom that demonstrates high maneuverability when controlled by two external inputs, electrical and thermal. These multiple inputs allow for complex motions that are routine in nature, but that would be otherwise difficult to obtain with a single actuator. To the best of our knowledge, this MSM-IPMC actuator is the first solitary actuator capable of multiple-input control and the resulting deformability and maneuverability. The shape memory properties of MSM-IPMC were theoretically and experimentally studied. We presented the multiple shape memory properties of Nafion cylinder. A physics based model of the IPMC was proposed. The free energy density theory was utilized to analyze the shape properties of the IPMC. To verify the model, IPMC samples with the Nafion as the base membrane was prepared and experiments were conducted. Simulation of the model was performed and the results were compared with the experimental data. It was successfully demonstrated that the theoretical model can well explain the shape memory properties of the IPMC. The results showed that the reheat glass transition temperature of the IPMC is lower than the programming temperature. It was also found that the back-relaxation of the IPMC decreases as the programming temperature increases. This study may be useful for the better understanding of the shape memory effect of IPMC. Furthermore, we theoretically modeled and experimentally investigated the multiple shape memory effect of MSM-IPMC. We proposed a new physical principle to explain the shape memory behavior. A theoretical model of the multiple shape memory effect of MSM-IPMC was developed. Based on our previous study on the electro-mechanical actuation effect of IPMC, we proposed a comprehensive physics-based model of MSM-IPMC which couples the actuation effect and the multiple shape memory effect. It is the first model that includes these two actuation effects and multiple shape memory effect. Simulation of the model was performed using finite element method. To verify the model, an MSM-IPMC sample was prepared. Experimental tests of MSM-IPMC were conducted. By comparing the simulation results and the experimental results, both results have a good agreement. The multiple shape memory effect and reversibility of three different polymers, namely the Nafion, Aquivion and GEFC with three different ions, which are the hydrogen, lithium and sodium, were also quantitatively tested respectively. Based on the results, it is shown that all the polymers have good multiple shape memory effect and reversibility. The ions have an influence on the broad glass transition range of the polymers. The current study is beneficial for the better understanding of the underlying physics of MSM-IPMC. A biomimetic underwater robot, that was actuated by the MSM-IPMC, was developed. The design of the robot was inspired by the pectoral fish swimming modes, such as stingrays, knifefish and cuttefish. The robot was actuated by two soft fins which were consisted of multiple IPMC samples. Through actuating the IPMCs separately, traveling wave was generated on the soft fin. Experiments were performed for the test of the robot. The deformation and the blocking force of the IPMCs on the fin were measured. A force measurement system in a flow channel was implemented. The thrust force of the robot under different frequencies and traveling wave numbers were recorded. Multiple shape memory effect was performed on the robot. The robot was capable of changing its swimming modes from Gymnotiform to Mobuliform, which has high deformability, maneuverability and agility