Technology advancement of the electrochemical CO2 concentrating process

Two multicell, liquid-cooled, advanced electrochemical depolarized carbon dioxide concentrator modules were fabricated. The cells utilized advanced, lightweight, plated anode current collectors, internal liquid cooling and lightweight cell frames. Both were designed to meet the carbon dioxide removal requirements of one-person, i.e., 1.0 kg/d (2.2 lb/d)

Silicon containing electroconductive polymers and structures made therefrom

An electropolymerized film comprised of polymers and copolymers of a monomer is formed on the surface of an anode. The finished structures have superior electrical and mechanical properties for use in applications such as electrostatic dissipation and for the reduction of the radar cross section of advanced aircraft

Further studies of single-sided charge-sharing CZT strip detectors

We report progress in the study of a thick CZT strip detector module designed to perform gamma-ray spectroscopy and 3-D imaging. We report preliminary performance measurements of 7.5 mm thick single-sided charge-sharing strip detector prototype devices. This design features both row and column contacts on the anode surface. This electron-only approach addresses problems associated with poor hole transport in CZT that limit the thickness and energy range of double-sided strip detectors. This work includes laboratory and simulation studies aimed at developing compact, efficient, detector modules for 0.05 to 1 MeV gamma measurements while minimizing the number and complexity of the electronic readout channels. This is particularly important in space-based coded aperture and Compton telescope instruments that require large area, large volume detector arrays. Such arrays will be required for the NASA Black Hole Finder Probe (BHFP)and Advanced Compton Telescope (ACT). This new design requires an anode pattern with contacts whose dimensions and spacing are roughly the size of the ionization charge cloud. The first prototype devices have 125 μm anode contacts on 225 μm pitch. Our results demonstrate the principle of operation but suggest that even finer anode contact feature sizes will be necessary to achieve the desired performance

Position Resolution in LaBr3 and LaCl3 Scintillators Using Position-Sensitive Photomultiplier Tubes

Advanced scintillator materials such as LaBr3:Ce and LaCl3:Ce hold great promise for future hard X-ray and gamma-ray astrophysics missions due to their high density, high light output, good linearity, and fast decay times. Of particular importance for future space-based imaging instruments, such as coded-aperture telescopes, is the precise spatial location of individual gamma-ray interactions. We have investigated the position and energy resolution achievable within monolithic (5 cm × 5 cm × 1 cm) LaBr3:Ce and LaCl3:Ce crystals using position-sensitive light readout devices, including a position-sensitive photomultiplier tube and a multi-anode photomultiplier tube. We present the results of these tests and discuss the applicability of such advanced scintillators to future high-energy imaging astrophysics missions

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Department of Energy Engineering (Battery Science and Technology)The continuous throng in demand for high energy density rechargeable batteries innovatively drives technological development in cell design as well as electrochemically active materials. In that perspective metal-free batteries consisting of a flowing seawater as a cathode active material were introduced. However, the electrochemical performance of the seawater battery was restrained by NASICON (Na3Zr2Si2PO12) ceramic solid electrolyte. Here, we demonstrate a new class of fibrous nanomat hard-carbon (FNHC) anode/1D (one-dimensional) bucky paper (1DBP) cathode hybrid electrode architecture in seawater battery based on 1D building block-interweaved hetero-nanomat frameworks. Differently from conventional slurry-cast electrodes, exquisitely designed hybrid hetero-nanomat electrodes are fabricated through concurrent dual electrospraying and electrospinning for the anode, vacuum-assisted infiltration for the cathode. HC nanoparticles are closely embedded in the spatially reinforced polymeric nanofiber/CNT hetero-nanomat skeletons that play a crucial role in constructing 3D-bicontinuous ion/electron transport pathways and allow to eliminate heavy metallic aluminum foil current collectors. Eventually the FNHC/1DBP seawater full cell, driven by aforementioned physicochemical uniqueness, shows exceptional improvement in electrochemical performance (Energy density = 693 Wh kg-1), (Power density = 3341 W kg-1) removing strong stereotype of ceramic solid electrolyte, which beyond those achievable with innovative next generation battery technologies.ope

Continued Studies of Single-Sided Charge-Sharing CZT Strip Detectors

In this paper, we report progress in the study of thick single-sided charge-sharing cadmium zinc telluride (CZT) strip detector modules designed to perform gammaray spectroscopy and 3-D imaging. We report on continuing laboratory and simulation measurements of prototype detectors with 11×11 unit cells (15×15×7.5mm3 ). We report preliminary measurements of the 3-D spatial resolution. Our studies are aimed at developing compact, efficient, detector modules for 0.05 to 1 MeV gamma measurements while minimizing the number and complexity of the electronic readout channels. This is particularly important in space-based coded aperture and Compton telescope instruments that require large area, large volume detector arrays. Such arrays will be required for the NASA’s Black Hole Finder Probe (BHFP) and Advanced Compton Telescope (ACT). This design requires an anode pattern with contacts whose dimensions and spacing are roughly the size of the ionization charge cloud. The first prototype devices have 125µm anode contacts on 225µm pitch. Our studies conclude that finer pitch contacts will be required to improve imaging efficiency

Modifications of the X-ray source and monitor at the X-ray Calibration Facility

In order to test the instruments aboard the Advanced X-ray Astrophysics Facility (AXAF) some modifications will need to be made in the X-ray Calibration Facility at Marshall. Several of these modifications involve the X-ray source and the monitor. The source was redesigned to increase the spectral purity of the beam and decrease its polarization by minimizing the number of bremsstrahlung photons in the beam. This was accomplished by utilizing an annular electron gun which allowed the beam to take off antiparallel to the direction at which electrons are incident on the anode. Two other features of the source are the conical anode which decreases the effective spot size and a rotatable anode and filter wheel which allow the operator to change targets without breaking vacuum. The monitor is an important part of the facility because it is used to determine the X-ray flux at the target. A commercially available solid-state detector, Si(Li), should be used along with appropriate proportional counters for monitoring. This detector will be particularly useful when energy or wavelength dispersive instruments are tested because of its good resolution

Compensation methods to support cooperative applications: A case study in automated verification of schema requirements for an advanced transaction model

Compensation plays an important role in advanced transaction models, cooperative work and workflow systems. A schema designer is typically required to supply for each transaction another transaction to semantically undo the effects of . Little attention has been paid to the verification of the desirable properties of such operations, however. This paper demonstrates the use of a higher-order logic theorem prover for verifying that compensating transactions return a database to its original state. It is shown how an OODB schema is translated to the language of the theorem prover so that proofs can be performed on the compensating transactions

2D Hydrogenated graphene-like borophene as a high capacity anode material for improved Li/Na ion batteries: A first principles study

Fast-growing electronics industry and future energy storage needs have encouraged the design of rechargeable batteries with higher storage capacities, and longer life times. In this regard, two-dimensional (2D) materials, specifically boron and carbon nanosheets, have garnered enthusiasm due to their fascinating electronic, optical, mechanical and chemical properties. Recently, a hydrogen boride (HB) nanosheet was successfully fabricated showing remarkable stability and superior physical properties. Motivated by this experimental study, we used first principle electronic structure calculations to study the feasibility of this nanosheet to serve as an anode material for Li/Na/Ca/Mg/Al ion batteries. Most active adsorption sites for single adatoms were evaluated and next adatoms were gradually inserted into the anode surface accordingly. The charge transfer, electronic density of sates, storage capacity, structural stability, open-circuit potential and diffusion energy barriers were explored. Our theoretical study predicts that HB shows outstanding electrode properties for Li and Na ion batteries. The intercalation of both Li and Na adatoms into the HB monolayer can lead to a high identical storage capacity of 1133.8 mAh/g which is promising compared to the capacities of the traditional anode materials; such as graphite (372 mAh/g) and TiO2 (200 mAh/g), and other 2D materials; such as germanene (369 mAh/g), stanene (226 mAh/g), and phosphorene (432.8 mAh/g) nanosheets. These results may open a new horizon for the design of rechargeable batteries with higher storage capacitates