Investigation on some factors affecting crack formation in high resistance aluminum alloys

Aluminum alloys having good mechanical properties are Al-Zn-Mg alloys (7xxx) and Al-Cu-Li alloys (Weldalite®). These alloys may be subjected to stress corrosion cracking. In order to overcome this problem the Al 7050 alloy has been developed and it is widely used for aerospace applications. Despite that, some components made of this alloy cracked during the manufacturing process including machining and chemical anodization. In a previous work cracked Al 7050 components have been analyzed in order to identify possible causes of crack formation. In this work the susceptibility of this alloy to intergranular corrosion has been analysed and compared with that of other high resistance aluminum alloys

Formation of Ti–Zr–Cu–Ni bulk metallic glasses

Formation of bulk metallic glass in quaternary Ti–Zr–Cu–Ni alloys by relatively slow cooling from the melt is reported. Thick strips of metallic glass were obtained by the method of metal mold casting. The glass forming ability of the quaternary alloys exceeds that of binary or ternary alloys containing the same elements due to the complexity of the system. The best glass forming alloys such as Ti34Zr11Cu47Ni8 can be cast to at least 4-mm-thick amorphous strips. The critical cooling rate for glass formation is of the order of 250 K/s or less, at least two orders of magnitude lower than that of the best ternary alloys. The glass transition, crystallization, and melting behavior of the alloys were studied by differential scanning calorimetry. The amorphous alloys exhibit a significant undercooled liquid region between the glass transition and first crystallization event. The glass forming ability of these alloys, as determined by the critical cooling rate, exceeds what is expected based on the reduced glass transition temperature. It is also found that the glass forming ability for alloys of similar reduced glass transition temperature can differ by two orders of magnitude as defined by critical cooling rates. The origins of the difference in glass forming ability of the alloys are discussed. It is found that when large composition redistribution accompanies crystallization, glass formation is enhanced. The excellent glass forming ability of alloys such as Ti34Zr11Cu47Ni8 is a result of simultaneously minimizing the nucleation rate of the competing crystalline phases. The ternary/quaternary Laves phase (MgZn2 type) shows the greatest ease of nucleation and plays a key role in determining the optimum compositions for glass formation

Japanese irogane alloys and patination – a study of production and application

Japanese metalworkers use a wide range of irogane alloys (shakudo, shibuichi), which are colored with a single patination solution (niiro). This approach allows different alloys to be combined in one piece and patinated, producing a multi-colored piece of metalwork. At present the production of irogane alloys and their patination is an unreliable process. This study aims to develop reliable alloy production and a safe, easy-to use and repeatable patination process using standard ingredients available from chemical suppliers. The study has examined the production of shakudo and shibuichi alloys, characterizing the alloys produced by casting into cloth molds in hot water, into steel molds, and produced using continuous casting. The influence of traditional polishing methods was assessed using surface texture (Sa) measurements. Traditional rokusho, an ingredient of the niiro solution, was analyzed by XRF and XRD. Niiro patinated surfaces on a range of alloys were examined using XRD and L*a*b* color measurements.</p

Ferrimagnetism and antiferromagnetism in half-metallic Heusler alloys

Half-metallic Heusler alloys are among the most promising materials for future applications in spintronic devices. Although most Heusler alloys are ferromagnets, ferrimagnetic or antiferromagnetic (also called fully-compensated ferrimagnetic) alloys would be more desirable for applications due to the lower external fields. Ferrimagnetism can be either found in perfect Heusler compounds or achieved through the creation of defects in ferromagnetic Heusler alloys.Comment: To be considered for the proceedings of the International Conference on Nanoscale Magnetism (ICNM 07

Reliable irogane alloys and niiro patination—further study of production and application to jewelry

Japanese metalworkers use a wide range of irogane alloys (shakudo, shibuichi), which are colored with a single patination solution (niiro eki). This approach allows different alloys to be combined in one piece and patinated, producing a multi-colored piece of metalwork. At present the niiro patination process is unreliable. In this study we develop a deeper understanding of the effect of patination solution ingredients on color. We have tested a synthetic niiro solution, comparing the color results with traditional niiro solution patination. Surface products have been analyzed to determine how they are influenced by both the niiro solution and cleaning procedures during patination. A large range of shibuichi and shakudo alloys have been produced to determine the full color pallette. This work also explores the use of alternative processes for the patination of irogane alloys, examining the effect of laser marking and anodizing on irogane alloys

Lightweight magnesium-lithium alloys show promise

Evaluation tests show that magnesium-lithium alloys are lighter and more ductile than other magnesium alloys. They are being used for packaging, housings, containers, where light weight is more important than strength

Microstructure and plastic properties of mg-Li alloys smelted in vacuum induction furnaces after hot working

The paper analyses the characteristics of plasticity and microstructure of magnesium alloys with lithium meant for hot plastic working with different lithium content. The alloys were prepared in conditions of vacuum smelting. Achieved ingots were subject to hot extrusion. Tests on Gleeble simulator were conducted to assess the susceptibility of tested alloys to plastic forming in conditions of hot plastic working. For tested alloy the activation energy was marked for hot plastic deformation and plasticity characteristics in function of Zener-Hollomon parameter. After the analysis of the influence of temperature on the deformability of tested alloys it was stated that the alloy containing 8% Li (LAZ831) has better susceptibility to plastic treatment than alloy containing 4% Li (LAZ431), but higher than in case of classic magnesium alloys-AZ31.Web of Science6231432142