707 research outputs found
Polypyrrole-Fe2O3 nanohybrid materials for electrochemical storage
We report on the synthesis and electrochemical characterization of nanohybrid polypyrrole (PPy) (PPy/Fe2O3) materials for electrochemical storage applications. We have shown that the incorporation of nanoparticles inside the PPy notably increases the charge storage capability in comparison to the “pure” conducting polymer. Incorporation of large anions, i.e., paratoluenesulfonate, allows a further improvement in the capacity. These charge storage modifications have been attributed to the morphology of the composite in which the particle sizes and the specific surface area are modified with the incorporation of nanoparticles. High capacity and stability have been obtained in PC/NEt4BF4 (at 20 mV/s), i.e., 47 mAh/g, with only a 3% charge loss after one thousand cyles. The kinetics of charge–discharge is also improved by the hybrid nanocomposite morphology modifications, which increase the rate of insertion–expulsion of counter anions in the bulk of the film. A room temperature ionic liquid such as imidazolium trifluoromethanesulfonimide seems to be a promising electrolyte because it further increases the capacity up to 53 mAh/g with a high stability during charge–discharge processes
New Materials and New Configurations for Advanced Electrochemical Capacitors
Today, electrochemical capacitors (ECs) have the potential to emerge as a promising energy storage technology. The weakness of EC systems is certainly the limited energy density, which restricts applications to power delivery over only few seconds. As a consequence, many research efforts are focused on designing new materials to improve energy and power
densities. These are reviewed below
Endogenous N-nitroso compounds, and their precursors, present in bacon, do not initiate or promote aberrant crypt foci in the colon of rats
Processed meat intake is associated with increased risk of colorectal cancer. This association may be explained by the endogenous formation of N-nitroso compounds (NOC). The hypothesis that meat intake can increase fecal NOC levels and colon carcinogenesis was tested in 175 Fischer 344 rats. Initiation was assessed by the number of aberrant crypt foci (ACF) in the colon of rats 45 days after the start of a high-fat bacon-based diet. Promotion was assessed by the multiplicity of ACF (crypts per ACF) in rats given experimental diets for 100 days starting 7 days after an azoxymethane injection. Three promotion studies were done, each in 5 groups of 10 rats, whose diets contained 7%, 14%, or 28% fat. Tested meats were bacon, pork, chicken, and beef. Fecal and dietary NOC were assayed by thermal energy analysis. Results show that feces from rats fed bacon-based diets contained 10-20 times more NOC than feces from control rats fed a casein-based diet (all p < 0.0001 in 4 studies). In bacon-fed rats, the amount of NOC input (diet) and output (feces) was similar. Rats fed a diet based on beef, pork, or chicken meat had less fecal NOC than controls (most p < 0.01). No ACF were detected in the colon of bacon-fed uninitiated rats. After azoxymethane injection, unprocessed but cooked meat-based diets did not change the number of ACF or the ACF multiplicity compared with control rats. In contrast, the bacon-based diet consistently reduced the number of large ACF per rat and the ACF multiplicity in the three promotion studies by 12%, 17%, and 20% (all p < 0.01). Results suggest that NOC from dietary bacon would not enhance colon carcinogenesis in rats
Ab initio evaluation of the charge-ordering in
We report {\it ab initio} calculations of the charge ordering in
using large configurations interaction methods on
embedded fragments. Our major result is that the electrons of the
bridging oxygen of the rungs present a very strong magnetic character and
should thus be explicitly considered in any relevant effective model. The most
striking consequence of this result is that the spin and charge ordering differ
substantially, as differ the experimental results depending on whether they are
sensitive to the spin or charge density.Comment: 4 page
The Metric-FF Planning System: Translating "Ignoring Delete Lists" to Numeric State Variables
Planning with numeric state variables has been a challenge for many years,
and was a part of the 3rd International Planning Competition (IPC-3). Currently
one of the most popular and successful algorithmic techniques in STRIPS
planning is to guide search by a heuristic function, where the heuristic is
based on relaxing the planning task by ignoring the delete lists of the
available actions. We present a natural extension of ``ignoring delete lists''
to numeric state variables, preserving the relevant theoretical properties of
the STRIPS relaxation under the condition that the numeric task at hand is
``monotonic''. We then identify a subset of the numeric IPC-3 competition
language, ``linear tasks'', where monotonicity can be achieved by
pre-processing. Based on that, we extend the algorithms used in the heuristic
planning system FF to linear tasks. The resulting system Metric-FF is,
according to the IPC-3 results which we discuss, one of the two currently most
efficient numeric planners
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