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oaioai:strathprints.strath.ac.uk:19126

Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs. Si-O bond cleavage

Authors
Publication date
1 January 2009
Publisher
Doi

    Abstract

    A new application of zincate [(THF) Li(TMP)(Bu-t) Zn(Bu-t)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DIZn) of trimethyl(phenoxy) silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures

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