In the metal casting industry, we often hear about a type of cast iron called white cast iron.
White cast iron is a type of cast iron that does not have graphite, so it has very hard but brittle
mechanical properties. This study was conducted to determine the microstructure before and
after the annealing process, as well as the hardness value of white cast iron. Metallographic
testing and composition testing were carried out using Scanning Electron Microscope - Energy
Dispersive X-Ray Spectroscopy (SEM-EDS), while hardness testing was carried out using the
Rockwell hardness method. The results of SEM raw material testing showed that in white cast
iron there were cementite (Fe₃C) and pearlite phases. While the results of SEM annealing
testing showed that in white cast iron there were cementite (Fe₃C), pearlite, and graphite
phases. The results of EDS raw material testing showed that in white cast iron the cementite
phase contained the element Fe (Ferro) of 84.3% by weight, the element C (Carbon) by 14.67%
by weight, and the element Cr (Chromium) by 0.7% by weight. Then, in the perlite phase, there
is a Fe (Ferro) element of 85.5% by weight, a C (Carbon) element of 13.2% by weight, and a
Si (Silicon) element of 1.2% by weight. The results of the EDS annealing test show that in the cementite phase white cast iron there is a Fe (Ferro) element of 83.8% by weight, a C (Carbon)
element of 14.5% by weight, and a Cr (Chromium) element of 1.6% by weight. In the perlite
phase there is a Fe (Ferro) element of 85.9% by weight, a C (Carbon) element of 12.7% by
weight, and a Si (Silicon) element of 1.4% by weight. Then, in the graphite phase, there is a Fe
(Ferro) element of 31.0% xii by weight, a C (Carbon) element of 38% by weight, a Si (Silicon)
element of 0.2% by weight, and an O (Oxygen) element of 30.8% by weight. The results of the
hardness test showed that the hardness value of the raw material specimen obtained an average
hardness value of 48.3 HRC. While the specimen that had been annealed obtained an average
hardness value of 38.5 HRC. So the annealing heat treatment process can reduce the value of
white cast iron
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