Operando IR of Catalytic Reactions Under Microwaves at 5.8 GHz

Abstract

A new spectroscopic cell was designed for operando IR observation of heterogeneous catalysis under microwave irradiation. Oxidation of CO on Pt-H-BEA zeolite was performed under conventional and microwave heating at the same space velocity to assess the efficiency of microwave heating, which was confirmed by an infrared in-situ temperature scale. A temperature of 230-240°C was obtained after 2min microwave irradiation. Infrared monitoring evidences a moderate sintering of the platinum particles after microwave irradiation, probably due to hotspots on the metal. Infrared observation indicates a strong perturbation of electron density in the Pt particles by microwave during catalysis