oaioai:eprints.hud.ac.uk:15205

Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

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Publication date
2 October 2012
Publisher
Royal Society of Chemistry
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    Abstract

    A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3’-diamino-2,2’- bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone grou

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    Last time updated on 13/12/2012

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