Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes

Xu-Qiong Xiao; Xupeng Liu; Qiong Lu; Zhifang Li; Guoqiao Lai; Mitsuo Kira

oai:doaj.org/article:a5a839acf7bf48ca902e16d64f3becc3

Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes

Authors: Xu-Qiong Xiao
Xupeng Liu
Qiong Lu
Zhifang Li
Guoqiao Lai
Mitsuo Kira
Publication date: 1 October 2016
Publisher: 'MDPI AG'
Doi

Abstract

The reactions of isolable dialkylsilylene 1 with aromatic acyl chlorides afforded aroylsilanes 3a–3c exclusively. Aroylsilanes 3a–3c were characterized by 1H-, 13C-, and 29Si-NMR spectroscopy, high-resolution mass spectrometry (HRMS), and single-crystal molecular structure analysis. The reaction mechanisms are discussed in comparison with related reaction of 1 with chloroalkanes and chlorosilanes

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Last time updated on 13/10/2017

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