research article
oaioai:escidoc.org:escidoc:2070847

A “Hard/Soft” Mismatch Enables Catalytic Friedel−Crafts Acylations

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Publication date
2001
Publisher
Doi

    Abstract

    Cationic complexes of Pt(II) and other late transition metals efficiently catalyze Friedel−Crafts acylations of moderately activated arenes by carboxylic acid anhydrides. The nature of the catalytically relevant species formed from (PhCN)<sub>2</sub>PtCl<sub>2</sub> and AgSbF<sub>6</sub> and their interactions with the substrates are studied by NMR and ESI-MS

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    Last time updated on 23/08/2016

    This paper was published in MPG.PuRe.

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