We report on non-destructive scattering and diffraction of He, He<sub>2</sub>, and He<sub>3</sub> from a plane ruled reflection grating. At grazing incidence the normal component of the particle’s wave-vector is sufficiently small to allow for quantum reflection at the attractive Casimir-van der Waals particle–surface interaction potential. Quantum reflection occurs tens of nanometers in front of the surface, before the dimers and trimers reach the region where the surface-induced forces would inevitably cause breakup of the fragile bonds. The reflected particles are identified via their mass-dependent diffraction angles and by mass spectrometry. The intensity distributions of the observed diffraction patterns are discussed in terms of the grating’s blaze angle
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