Microstructure and shape-memory characteristics of Ni56Mn25-xCoxGa19 (x=4, 8) high-temperature shape-memory alloys

Abstract

Natural Science Foundation of China [50771086]; Program for New Century Excellent Talents in University [NCET-09-0676]; Program for New Century Excellent Talents in Fujian Province University (NCETFJ); Fujian Provincial Department of Science and TechnologNiMnCoGa alloys were studied as candidate of high-temperature shape-memory alloys with Mn substituted by Co. The results show that the hot workability and room-temperature ductility of NiMnGa alloys can be greatly improved by forming ductile gamma phase through Co addition. When the amount of gamma phase is about 19%, the tensile stress and strain are 491 MPa and 8.2%, respectively. When the amount of gamma phase increased to about 43%, the tensile stress and strain are 729.3 MPa and 14.1%, respectively. The reversible strain due to shape-memory effect is 2.1% under a prestrain of 5.3% for x = 4, and the shape-memory ability almost disappears for x = 8 due to large amount of gamma phase, which seriously hampers the reorientation of martensitic variants and/or detwinning. (C) 2010 Elsevier Ltd. All rights reserved