Synthesis, X-ray structures, and photoluminescence of heterometal trinuclear Hg(II)-Pt(I) and tetranuclear Hg(II)-Pd(I) complexes

Abstract

通讯作者地址: Huang, RB (通讯作者), Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China 2. Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China 电子邮件地址: [email protected] heterometallic trinuclear complex with monovalent platinum consisting of a [Pt2Hg] cluster bridged by two mu(3)-Cl atoms and another tetranuclear complex with monovalent palladium owning the structural core of open cubane-like [Hg2Pd2Cl2I2] framework were synthesized by self-assembly reactions. (C) 2008 Elsevier B.V. All rights reserved.National Natural Science Foundation of China 20571062 20721001 National Basic Research Program of China 2007CB81530