A Total Synthesis of Millingtonine A
- Publication date
- 2012
- Publisher
Abstract
A total synthesis of millingtonine A, a diglycosylated alkaloid, has been accomplished. Millingtonine A possesses a unique racemic tricyclic core structure not known from any other natural or synthetic source until now. The synthesis features a key bond-forming radical Ueno–Stork cyclization to form the heterocyclic core