Synthetic Studies Directed toward Dideoxy Lomaiviticinone Lead to Unexpected 1,2-Oxazepine and Isoxazole Formation
Abstract
In the course of studies directed toward the synthesis of dideoxy lomaiviticinone, 3-(nitromethyl)cyclohexenones <b>2a</b> (X = H) and <b>2b</b> (X = I) were prepared. The corresponding enolates were reacted with naphthazarin (<b>1</b>) and unexpectedly afforded 1,2-oxazepine <b>3</b> and isoxazole <b>4</b>, respectively. Rationale for their formation is proposed- Text
- Journal contribution
- Biophysics
- Biochemistry
- Medicine
- Pharmacology
- Sociology
- Inorganic Chemistry
- Infectious Diseases
- Space Science
- Dideoxy Lomaiviticinone
- nitromethyl
- Isoxazole FormationIn
- naphthazarin
- enolate
- dideoxy lomaiviticinone
- Rationale
- synthesis
- 2 b
- formation
- Oxazepine
- Unexpected
- isoxazole
- Synthetic Studies
- oxazepine
Similar works
This paper was published in FigShare.
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