Plasmonic Enhancement of Nanophosphor Upconversion Luminescence in Au Nanohole Arrays
- Publication date
- 2013
- Publisher
Abstract
Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)hexagonal phase NaYF<sub>4</sub> doped with Yb<sup>3+</sup> and Er<sup>3+</sup>. The dimensions of nanohole Au arrays were designed to accept only a single UCNP upon particle filling and with a periodicity to be resonant with the excitation wavelength of the upconversion. Frequency-dependent luminescence enhancements of up to 35-fold and a concomitant shortening of the UCNP luminescence rise time were observed, consistent with simulations of plasmonic enhancement of the UCNP absorption