Silyl Migrations in d‑Xylose Derivatives: Total Synthesis of a Marine Quinoline Alkaloid

Anuchit Phanumartwiwath (1883533); Thomas W. Hornsby (1883539); Joazaizulfazli Jamalis (1883536); Christopher D. Bailey (1350954); Christine L. Willis (225856)

Silyl Migrations in d‑Xylose Derivatives: Total Synthesis of a Marine Quinoline Alkaloid

Authors: Anuchit Phanumartwiwath (1883533)
Thomas W. Hornsby (1883539)
Joazaizulfazli Jamalis (1883536)
Christopher D. Bailey (1350954)
Christine L. Willis (225856)
Publication date: 2013
Publisher
Doi

Abstract

A versatile method for the synthesis of orthogonally protected d-xylose 1-thioethers is described using unusual silyl group migrations which were pivotal in the synthesis of 4,8-dimethyl-6-<i>O</i>-(2′,4′-di-<i>O</i>-methyl-β-d-xylopyranosyl)hydroxyquinoline confirming the structure and absolute configuration of the natural product

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Last time updated on 12/02/2018

This paper was published in FigShare.

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