We derive the Boltzmann equation for scalar fields using the
Schwinger-Keldysh formalism. The focus lies on the derivation of the collision
term. We show that the relevant self-energy diagrams have a factorization
property. The collision term assumes the Boltzmann-like form of scattering
probability times statistical factors for those self-energy diagrams which
correspond to tree level scattering processes. Our proof covers scattering
processes with any number of external particles, which come from self-energy
diagrams with any number of loops.Comment: 17 pages, 4 figure